Polymer compositions and coating solutions
In a first aspect, a polymer composition includes a first polymer derived from a soluble polymer composition having an imide group and a T g reducing compound having an amine group. The first polymer has a glass transition temperature that is lower than a second polymer derived from the same soluble polymer composition, but without a T g reducing compound having an amine group. In a second aspect, a coating solution includes a soluble polymer having an imide group and a T g reducing compound having an amine moiety that can be an amine or a first masked amine that can be converted to an amine, wherein the first masked amine can be chemically converted, thermally converted, photo-converted or dissociated.
1. A polymer composition comprising a first polymer derived from:
a soluble polymer composition comprising an imide group; and
a T g reducing compound comprising an amine group, wherein:
the first polymer has a glass transition temperature that is lower than a second polymer derived from the same soluble polymer composition, but without a T g reducing compound comprising an amine group; and
the T g reducing compound comprises an amine moiety comprising a first masked amine that can be converted to form an amine, wherein the first masked amine can be thermally converted or dissociated and is selected from the group consisting of carbamates, amides, sulfonamides, ammonium salts made from acids and silyl derivatives.
2. The polymer composition of claim 1 , wherein the soluble polymer composition comprising an imide group is selected from the group consisting of polyimides, poly(amide-imides), poly(ether-imides), poly(ester-imides), copolymers comprising amide, ester or ether groups, and mixtures thereof.
3. A polymer film comprising the polymer composition of claim 1 .
4. A metal-clad laminate comprising the polymer film of claim 3 and a metal layer.
5. An article comprising the polymer film of claim 3 and an inorganic substrate, wherein the inorganic substrate comprises a material comprising a ceramic, a glass, a glass-ceramic or a mixture thereof, wherein the material comprises:
a metal selected from the group consisting of silicon, aluminum, titanium, zirconium, tantalum, niobium and mixtures thereof; and
oxygen.
6. The article of claim 5 , further comprising a hard coat layer adhered to the polymer film layer on a side opposite the inorganic substrate.
7. An impact-resistant article comprising the article of claim 5 .
8. A penetration-resistant article comprising the article of claim 5 .
9. A sound-reducing article comprising the article of claim 5 .
10. A coating solution comprising:
a soluble polymer comprising an imide group; and
a T g reducing compound comprising: an amine moiety comprising a first masked amine that can be converted to an amine, wherein the first masked amine:
can be thermally converted or dissociated; and
is selected from the group consisting of carbamates, amides, sulfonamides, ammonium salts made from acids and silyl derivatives.
11. The coating solution of claim 10 , wherein the T g reducing compound is selected from a single multi-amino-functional precursor, a combination of multiple amino-functional precursors, or a mixture thereof.
12. The coating solution of claim 10 , wherein the soluble polymer is selected from the group consisting of polyimides, poly(amide-imides), poly(ether-imides), poly(ester-imides), copolymers comprising amide, ester or ether groups, and mixtures thereof.