Tufted carpet including polyethyleneterephthalate bulked continuous filament
A polyethylene terephthalate bulked continuous filament is manufactured by steps of melt-spinning, multi-step stretching a polyethylene terephthalate chip and a master batch chip for coloring, passing through a texturing nozzle, cooling, and winding and has an elastic modulus of 1.00E+07 to 5.00E+09Pa at a temperature range of 10° C. to 200° C., the filament being manufactured by steps of melt-spinning a polyethylene terephthalate chip and a master batch chip for coloring, multi-step stretching, passing through a texturing nozzle, cooling, and winding.
1 . A polyethylene terephthalate bulked continuous filament made from a polyethylene terephthalate chip and a polyethylene terephthalate master batch chip for coloring comprising inorganic dyes or organic dyes,
wherein the polyethylene terephthalate master batch is produced and has a lower weight average molecular weight compared to the polyethylene terephthalate chip,
wherein the master batch chip for coloring is produced by injecting the inorganic dyes or organic dyes with a base polyethylene terephthalate chip and extruding the inorganic dyes or organic dyes and the base chip,
wherein the polyethylene terephthalate bulked continuous filament has an elastic modulus in a dynamic mechanical analysis (DMA) of between 1.0E+07 and 5.0E+09 Pa in a temperature range of 10° C. to 200° C.,
wherein a weight average molecular weight of the polyethylene terephthalate bulked continuous filament is 50,000 to 70,000, a molecular weight distribution (PDI) of the polyethylene terephthalate bulked continuous filament is 1.6 to 2.0,
wherein a diethylene glycol (DEG) content of the polyethylene terephthalate bulked continuous filament is equal to or less than 1.2 wt %, and
wherein a diameter of the polyethylene terephthalate bulked continuous filament is 6 to 20 dpf.
2 . The polyethylene terephthalate bulked continuous filament of claim 1 , wherein the polyethylene terephthalate master batch chip comprises about 150 ppm or less of terephthalic acid, monohydroxyethyl terephthatate, and bis (2-hydroxyethyl terephthalate).
3 . The polyethylene terephthalate bulked continuous filament of claim 1 , wherein the polyethylene terephthalate master batch has a weight average molecular weight of 30,000 to 70,000.
4 . The polyethylene terephthalate bulked continuous filament of claim 1 , wherein a content of low molecular weight substances having a weight average molecular weight of 8,000 or less in a polymer of the polyethylene terephthalate master batch chip for coloring is 10 wt % or less.
5 . The polyethylene terephthalate bulked continuous filament of claim 1 , wherein a content of low molecular weight substances having a weight average molecular weight of 8,000 or less in a polymer of the polyethylene terephthalate master batch chip for coloring is 5 wt % or less.
6 . The polyethylene terephthalate bulked continuous filament of claim 1 , wherein the polyethylene terephthalate master batch chip is prepared by solid phase polymerization.
7 . The polyethylene terephthalate bulked continuous filament of claim 6 , wherein the solid phase polymerization is carried out under vacuum conditions at 110 to 170° C. for 4 to 6 hours, and the temperature is raised from 235 to 255° C. for 4 to 6 hours.
8 . The polyethylene terephthalate bulked continuous filament of claim 1 , wherein the master batch chip for coloring includes carbon black as a dye in an amount of 1 to 40 wt % based on a total weight of the polyethylene terephthalate master batch chip for coloring.
9 . The polyethylene terephthalate bulked continuous filament of claim 1 , which is prepared by a method comprising melt-spinning the polyethyleneterephthalate chip and the coloring polyethylene terephthalate master batch chip together.
10 . The polyethylene terephthalate bulked continuous filament of claim 9 , wherein the method further comprises cooling the yarn with air at a speed of 0.2 to 1.0 m/sec.
11 . The polyethylene terephthalate bulked continuous filament of claim 10 , wherein the method further comprises oiling with a neat type emulsion or a water-soluble emulsion.
12 . The polyethylene terephthalate bulked continuous filament of claim 11 , wherein the method further comprises a step of feeding the filament to a stretching roller at a speed of 300 to 1,200 m/min.
13 . The polyethylene terephthalate bulked continuous filament of claim 11 , wherein the polyethylene terephthalate bulked continuous filament has an elastic modulus in a dynamic mechanical analysis (DMA) of between 2.0E+07 and 6.0E+08 Pa in a temperature range of 10° C. to 200° C.
14 . A tufted carpet, comprising:
a pile layer including the polyethylene terephthalate bulked continuous filament of claim 1 ; and
at least one backing layer,
wherein an elastic recovery rate, which is a height of the pile layer after thermoforming to a height of the pile layer before thermoforming, is equal to or greater than 35%.
15 . The tufted carpet of claim 14 , wherein the bulked continuous filament has a fineness of 700 to 1500 denier.
16 . The tufted carpet of claim 14 , wherein the pile layer weighs 180 gsm to 700 gsm.
17 . The tufted carpet of claim 14 , wherein the elastic recovery rate is equal to or greater than 45%.
18 . The tufted carpet of claim 14 , wherein the at least one backing layer is made of polyester or polyolefin and has a spunbond or fabric shape of 90 to 150 gsm.
19 . A polyethylene terephthalate bulked continuous filament made from a polyethylene terephthalate chip and a polyethylene terephthalate master batch chip for coloring comprising inorganic dyes or organic dyes,
wherein the colored polyethylene terephthalate bulked continuous filament has an elastic modulus in a dynamic mechanical analysis (DMA) of between 1.0E+07 and 5.0E+09 Pa in a temperature range of 10° C. to 200° C.,
wherein the polyethylene terephthalate comprises units derived from ethylene glycol and terephthalic acid and one or more ester-forming components selected from the group consisting of 1,3-propanediol, 1,4-butanediol, 1,6-hexanediol, isophthalic acid, hexahydroterephthalic acid, stilbene dicarboxylic acid, bibenzoic acid, adipic acid, sebacic acid, and azelaic acid,
wherein a weight average molecular weight of the polyethylene terephthalate bulked continuous filament is 50,000 to 70,000,
wherein a molecular weight distribution (PDI) of the polyethylene terephthalate bulked continuous filament is 1.6 to 2.0,
wherein a diethylene glycol (DEG) content of the polyethylene terephthalate bulked continuous filament is equal to or less than 1.2 wt %, and
wherein a diameter of the polyethylene terephthalate bulked continuous filament is 6 to 20 dpf.