Biodegradable magnesium alloy without rare earth elements, preparation method and use thereof
The present application provides a biodegradable magnesium alloy without rare earth elements. The magnesium alloy comprises the following elements in percentage by mass: Zn 1.0-5.0%; Mn 0.1-1.0%; Ca 0.1-1.0%; Sr 0.1-1.0%; Sn 0.1-3.0%; Zr 0.1-0.8%; and Mg balance. The impurity in the magnesium alloy does not contain rare earth elements. The present application also provides a method for preparing the above biodegradable magnesium alloy and use in the preparation of medical devices. In the present application, Mg is used as the main components and mixed with a specific proportion of Zn, Ca and Mn to prepare the alloy. The biodegradable magnesium alloy of the present application has a controllable degradation rate and strong mechanical strength, and there are no harmful elements to a human body, and the degradation of the alloy in the human body will not affect human body.
1 . A method for preparing a biodegradable magnesium alloy without rare earth elements, wherein the biodegradable magnesium alloy without rare earth elements comprises the following elements in percentage by mass:
Zn
1.0-5.0%;
Mn
0.1-1.0%;
Ca
0.1-1.0%;
Sr
0.1-1.0%;
Sn
0.1-3.0%;
Zr
0.1-0.8%; and
Mg
balance[[;]],
wherein, the magnesium alloy has an average grain size of 5-10 μm, and an average density of crack distribution on the surface of the magnesium alloy is less than or equal to 20 cracks/mm 2 ,
the method specifically comprising the steps of:
1) melting-casting: in a closed container, fully adding each metal powder into a melting ladle according to the required proportion, controlling the temperature to melt at 700-800° C., blowing argon and stirring, casting and cooling;
2) heat treatment: heating the alloy obtained by casting, controlling the temperature at 200-250° C., annealing for 1-5 min, and cooling;
3) hot extrusion: putting the heat-treated alloy into a hot extrusion mold, controlling the temperature at 250-300° C., controlling the extrusion rate at 2-5 mm/s, and setting the extrusion ratio to 10-15:1; and
4) rolling and forming: rolling at a temperature of 320-350° C., controlling the speed at 20-30 m/min, and controlling the reduction of each rolling at 50-80%, to obtain a formed biodegradable magnesium alloy, and the magnesium alloy has a tensile strength and a yield strength greater than 250 MPa, which are measured according to GB-T228-2002, the magnesium alloy has a degradation rate of 1.35 mm/Y or less.
2 . The method for preparing a biodegradable magnesium alloy without rare earth elements of claim 1 , wherein, after the rolling is completed, a further heat treatment process can be carried out according to requirements.
3 . The method for preparing a biodegradable magnesium alloy without rare earth elements of claim 1 , wherein, preheating is carried out before rolling, and the preheating time does not exceed 10 minutes.
4 . The method for preparing a biodegradable magnesium alloy without rare earth elements of claim 1 , wherein passes for the rolling are no more than 10 times.
5 . The method for preparing a biodegradable magnesium alloy without rare earth elements of claim 1 , wherein, in an optional embodiment, during the melting-casting, the blowing argon and stirring is blowing argon gas through a gas port at the bottom of the melting ladle.