IP Library › Granted Patent US 12,508,214
Granted Patent B2
US 12,508,214 · App. 18/251,037 · Granted Dec 30, 2025

Personal care rinse off composition with composite opacifier particles

Inventors: Luqing Qi (Midland, MI); Ying O'Connor (Coatesville, PA); Yuanqiao Rao (Berwyn, PA); David L. Malotky (Midland, MI); Eric Wasserman (Collegeville, PA); Fanwen Zeng (Audubon, PA); Junsi Gu (Malvern, PA); Stephanie A. Bloxom (Midland, MI)
Assignees: Dow Global Technologies LLC; Rohm and Haas Company
A61K8/29A61Q5/02A61Q19/10
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Quick Facts
Patent No.
US 12,508,214
App. No.
18/251,037
Granted
Dec 30, 2025
Kind
B2
Abstract

An aqueous personal care rinse off composition is provided, comprising: a dermatologically acceptable aqueous vehicle; a dermatologically acceptable cleaning surfactant; and a plurality of composite opacifier particles, wherein the composite opacifier particles comprise metal oxide particles that are partially or completely encapsulated by a wax; wherein the metal oxide particles are selected from the group consisting of zinc oxide, titanium oxide and mixtures thereof; wherein the metal oxide particles have a z average particle size of >100 nm as measured by dynamic light scattering; wherein the wax has a melting point temperature of 50 to 110° C.; and wherein the composite opacifier particles have a z average particle size of >100 nm to 2,000 nm as measured by dynamic light scattering.

Claims (18)

1 . An aqueous personal care rinse off composition, comprising:

70 to 85 wt %, based on weight of the aqueous personal care rinse off composition, of a dermatologically acceptable aqueous vehicle, wherein the dermatologically acceptable aqueous vehicle is water;

7 to 20 wt %, based on weight of the aqueous personal care rinse off composition, of a dermatologically acceptable cleaning surfactant; and

0.75 to 3.0 wt %, based on weight of the aqueous personal care rinse off composition, of a plurality of composite opacifier particles, wherein the composite opacifier particles comprise metal oxide particles that are partially or completely encapsulated by a wax; wherein the metal oxide particles are selected from the group consisting of zinc oxide, titanium oxide and mixtures thereof; wherein the metal oxide particles have a z average particle size of 175 to 275 as measured by dynamic light scattering; wherein the wax has a melting point temperature of 45 to 110° C.; and wherein the composite opacifier particles have a z average particle size of 300 nm to 500 nm as measured by dynamic light scattering.

2 . The aqueous personal care rinse off composition of claim 1 , wherein the aqueous personal care rinse off composition is selected from the group consisting of a shampoo, a conditioning shampoo, a body wash formulation, an exfoliating body wash formulation, a facial wash formulation, an exfoliating facial wash formulation, a liquid hand soap formulation, a sulfate-free cleansing formulation and a mild cleansing formulation.

3 . The aqueous personal care rinse off composition of claim 2 , wherein the dermatologically acceptable cleaning surfactant is selected from the group consisting of alkyl polyglucosides, glycinates, betaines, taurates, glutamates, sarcosinates, isethionates, sulfoacetates, alaninates, amphoacetates, sulfates, sulfonates, succinates, fatty alkanolamides and mixtures thereof.

4 . The aqueous personal care rinse off composition of claim 3 , wherein the metal oxide particles are titanium dioxide particles.

5 . The aqueous personal care rinse off composition of claim 4 , further comprising a rheology modifier.

6 . The aqueous personal care rinse off composition of claim 5 , wherein the wax is a natural wax.

7 . The aqueous personal care rinse off composition of claim 6 , wherein the natural wax is from the group consisting of carnauba wax, Candelilla wax, bayberry wax, castor wax, coco butter, esparto wax, Japan wax, jojoba wax, laurel wax, ouricury wax, palm wax, rice bran wax, soy wax, sunflower wax, shea butter, tallow tree wax and mixtures thereof.

8 . The aqueous personal care rinse off composition of claim 7 , wherein the natural wax is carnauba wax.

9 . A method of cleaning at least one of mammalian skin and hair, comprising:

(a) applying an aqueous personal care rinse off composition according to claim 1 to the skin or hair of a mammal; and

(b) rinsing the aqueous personal care rinse off composition from the skin or hair with a rinse water.

10 . The aqueous personal care rinse off composition of claim 7 , wherein the wax has a melting point temperature of 75 to 90° C.

11 . The aqueous personal care rinse off composition of claim 7 , wherein the wax has a melting point temperature of 80 to 90° C.

12 . The aqueous personal care rinse off composition of claim 11 , wherein the dermatologically acceptable cleaning surfactant includes a mixture of sodium laureth sulfate and trimethylglycine.

13 . The aqueous personal care rinse off composition of claim 12 , wherein the dermatologically acceptable cleaning surfactant is a mixture of sodium laureth sulfate and trimethylglycine.

Assignments (4)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 19, 2025
From: O'CONNOR, YING; ZENG, FANWEN; GU, JUNSI
To: ROHM AND HAAS COMPANY
Reel/Frame 072961/0371 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 19, 2025
From: WASSERMAN, ERIC
To: UNION CARBIDE CORPORATION
Reel/Frame 072961/0523 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 19, 2025
From: UNION CARBIDE CORPORATION
To: DOW GLOBAL TECHNOLOGIES LLC
Reel/Frame 072961/0526 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 19, 2025
From: QI, LUQING; MALOTKY, DAVID L.; BLOXOM, STEPHANIE A.; RAO, YUANQIAO
To: DOW GLOBAL TECHNOLOGIES LLC
Reel/Frame 072961/0592 →
Continuity (2)
Provisional Application 63122072 · Dec 7, 2020
Related Publication 20230404875A1 · Dec 21, 2023
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