Method of preparing a melt for the production of man-made mineral fibres
The invention relates to a method of preparing a mineral melt in a cupola furnace that uses at least one plasma torch to provide heat energy to the furnace. The plasma torch uses nitrogen, carbon monoxide, carbon dioxide, or a mixture thereof as the carrier gas. The invention also relates to a cupola furnace for the preparation of the mineral melt, and the use of a plasma torch in a cupola furnace to reduce the amount of NO x and/or hydrogen in the furnace off-gas.
1 . A process for preparing a mineral melt in a cupola furnace, said process comprising supplying mineral material to the cupola furnace, and providing heating energy to the cupola furnace, said cupola furnace having a base, such that said mineral material is melted to form a mineral melt that collects in the base of the cupola furnace, and wherein the process produces off-gas,
wherein:
the cupola furnace comprises at least two temperature zones, including a hot zone at the base of the cupola furnace and an oxidation zone above the hot zone;
(i) the cupola furnace is equipped with at least one tuyere providing a source of oxygen in the oxidation zone;
(ii) the cupola furnace comprises at least one plasma torch that uses as carrier gas nitrogen, carbon monoxide, carbon dioxide, or a mixture thereof, and provides plasma heating in the hot zone;
(iii) greater than 50% of the heating energy provided to the cupola furnace is provided by the at least one plasma torch;
(iv) the temperature in the oxidation zone is below 1,400° C.;
(v) the temperature in the hot zone is greater than the temperature in the oxidation zone;
(vi) water is substantially excluded from any zone of the cupola furnace where the temperature is above 750° C.
2 . The process as claimed in claim 1 , wherein greater than 60% of the heating energy provided to the cupola furnace is provided by the at least one plasma torch.
3 . The process as claimed in claim 1 , wherein the temperature in the oxidation zone is below 1,300° C.
4 . The process as claimed in claim 1 , wherein heating is provided in the hot zone solely by the at least one plasma torch.
5 . The process as claimed claim 1 , wherein the temperature in the hot zone is above 800° C.
6 . The process as claimed in claim 1 , wherein the carrier gas enthalpy is from 2.0 to 6.0 kWh/Nm 3 .
7 . The process as claimed in claim 1 , wherein the melt has the following composition expressed as oxides, by weight %:
SiO 2
35-50
Al 2 O 3
12-30
TiO 2
up to 2
Fe 2 O 3
2-12
CaO
5-30
MgO
0-15
Na 2 O
0-15
K 2 O
0-15
P 2 O 5
0-3
MnO
0-3
B 2 O 3
0-3.
8 . The process as claimed in claim 1 , wherein the cupola furnace produces off-gas comprising NO x in an amount of less than 400 ppm.
9 . The process as claimed in claim 1 , wherein the carrier gas is nitrogen.
10 . The process as claimed in claim 1 , wherein the carrier gas comprises at least one component of the off-gas.
11 . The process as claimed in claim 10 , wherein the at least one component of the off-gas undergoes off-gas cleaning prior to its use as carrier gas.
12 . The process as claimed in claim 10 , wherein the carrier gas consists of the at least one component of the off-gas.
13 . The process as claimed in claim 1 , wherein greater than 70% the heating energy provided to the cupola furnace is provided by the at least one plasma torch.
14 . The process as claimed in claim 1 , wherein the temperature in the oxidation zone is below 1,200° C.
15 . The process as claimed claim 1 , wherein the temperature in the hot zone is above 900° C.
16 . The process as claimed in claim 1 , wherein the carrier gas enthalpy is from 3.0 to 5.0 kWh/Nm 3 .
17 . The process as claimed in claim 1 , wherein the cupola furnace produces off-gas comprising hydrogen in an amount of less than 20,000 ppm.
18 . A process for manufacturing man-made vitreous fibre (MMVF) comprising the steps of:
(i) forming a melt using a process as defined in claim 1 ;
(ii) fiberizing the melt by means of an internal or external spinning process; and
(iii) collecting the formed fibres.