BATTERY SEPARATORS COMPRISING RIBS
Battery separators comprising ribs are generally described. In some embodiments, the ribs have one or more features that enhance the performance of the battery separator.
1 . A battery separator, comprising:
a porous layer; and
a plurality of ribs disposed on the porous layer, wherein:
the ribs comprise a polymer,
the ribs comprise a filler, and
the plurality of ribs forms a discrete component of the battery separator.
2 . A battery separator, comprising:
a porous layer; and
a plurality of ribs disposed on the porous layer, wherein:
the ribs exhibit a mass loss of less than or equal to 2% upon exposure to a temperature of 160° C. for 13 minutes, and
the plurality of ribs forms a discrete component of the battery separator.
3 . A battery separator, comprising:
a porous layer; and
a plurality of ribs disposed on the porous layer, wherein:
the ribs are porous, and
the plurality of ribs forms a discrete component of the battery separator.
4 . A method for fabricating a battery separator, comprising:
passing a fluid comprising a polymer through a screen comprising a plurality of orifices onto a porous layer; and
cooling the fluid to form ribs comprising the polymer disposed on the porous layer.
5 . A battery separator or method as in any preceding claim, wherein the ribs comprise a polymer.
6 . A battery separator or method as in any preceding claim, wherein the ribs comprise two or more polymers.
7 . A battery separator or method as in any preceding claim, wherein the polymer(s) comprise a homopolymer, a copolymer, and/or a terpolymer.
8 . A battery separator or method as in any preceding claim, wherein the polymer(s) comprise a polymer that is amorphous.
9 . A battery separator or method as in any preceding claim, wherein the polymer(s) comprise a poly(acrylate), a poly(styrene)-poly(acrylate) copolymer, a poly(ester), and/or a poly(alpha olefin).
10 . A battery separator or method as in any preceding claim, wherein the polymer(s) comprise a polymer having a degree of polymerization of greater than or equal to 500 and less than or equal to 10000.
11 . A battery separator or method as in any preceding claim, wherein the polymer(s) make up greater than or equal to 10 wt % and less than or equal to 90 wt % of the ribs.
12 . A battery separator or method as in any preceding claim, wherein the ribs comprise a plasticizer.
13 . A battery separator or method as in any preceding claim, wherein the ribs comprise two or more plasticizers.
14 . A battery separator or method as in any preceding claim, wherein the plasticizer(s) comprise a non-volatile, organic compound.
15 . A battery separator or method as in any preceding claim, wherein the plasticizer(s) comprise a sulfate of an alkylsulfite acid, an ester of an alkylsulfite acid, an alcohol, a phenol, a diester of an ortho-phthalic acid, and/or an epoxy ester of an unsaturated fatty acid.
16 . A battery separator or method as in any preceding claim, wherein the diester of the ortho-phthalic acid is a reaction product of a phthalic anhydride.
17 . A battery separator or method as in any preceding claim, wherein the diester of the ortho-phthalic acid is a reaction product of an oxo alcohol.
18 . A battery separator or method as in any preceding claim, wherein the oxo alcohol comprises greater than or equal to 4 and less than or equal to 13 carbon atoms.
19 . A battery separator or method as in any preceding claim, wherein the epoxy ester of the unsaturated fatty acid is plant-derived.
20 . A battery separator or method as in any preceding claim, wherein the epoxy ester of the unsaturated fatty acid comprises an epoxidized butyl ester of an unsaturated fatty acid and/or an epoxidized n-hexyl ester of an unsaturated fatty acid.
21 . A battery separator or method as in any preceding claim, wherein the plasticizer(s) make up greater than or equal to 10 wt % and less than or equal to 60 wt % of the ribs.
22 . A battery separator or method as in any preceding claim, wherein the ribs comprise a filler.
23 . A battery separator or method as in any preceding claim, wherein the ribs comprise two or more fillers.
24 . A battery separator or method as in any preceding claim, wherein the filler(s) comprise a filler that is chemically inert.
25 . A battery separator or method as in any preceding claim, wherein the filler(s) comprise a filler that has a surface area of greater than or equal to 20 m 2 /g and less than or equal to 950 m 2 /g.
26 . A battery separator or method as in any preceding claim, wherein the filler(s) comprise a filler that has a pore volume of greater than or equal to 0.2 cm 3 /g.
27 . A battery separator or method as in any preceding claim, wherein the filler(s) comprise a filler that has an average diameter of greater than or equal to 0.01 micron and less than or equal to 75 microns.
28 . A battery separator or method as in any preceding claim, wherein the filler(s) make up greater than or equal to 1 wt % and less than or equal to 90 wt % of the ribs.
29 . A battery separator or method as in any preceding claim, wherein, upon exposure to a leaching solution, less than or equal to 30 ppm of iron is leached from the ribs.
30 . A battery separator or method as in any preceding claim, wherein an average spacing between the ribs is greater than or equal to 2 mm and less than or equal to 25 mm.
31 . A battery separator or method as in any preceding claim, wherein an average spacing between the ribs is greater than or equal to 0.1 mm and less than or equal to 12.5 mm.
32 . A battery separator or method as in any preceding claim, wherein an average width of the ribs is greater than or equal to 0.5 mm and less than or equal to 5 mm.
33 . A battery separator or method as in any preceding claim, wherein an average width of the ribs is greater than or equal to 0.05 mm and less than or equal to 2.5 mm.
34 . A battery separator or method as in any preceding claim, wherein the ribs have an average height of greater than or equal to 0.1 mm and less than or equal to 3 mm.
35 . A battery separator or method as in any preceding claim, wherein the plurality of ribs comprises ribs having a cross-section in a plane parallel to the porous layer that is circular.
36 . A battery separator or method as in any preceding claim, wherein the plurality of ribs comprises ribs having a cross-section in a plane parallel to the porous layer that is oval.
37 . A battery separator or method as in any preceding claim, wherein the plurality of ribs comprises ribs having a cross-section in a plane parallel to the porous layer that is diamond-shaped.
38 . A battery separator or method as in any preceding claim, wherein the plurality of ribs comprises ribs having a cross-section in a plane parallel to the porous layer that has a line segment shape.
39 . A battery separator or method as in any preceding claim, wherein the plurality of ribs comprises continuous ribs.
40 . A battery separator or method as in any preceding claim, wherein the plurality of ribs comprises discontinuous ribs.
41 . A battery separator or method as in any preceding claim, wherein the ribs form a pattern that has hexagonal symmetry.
42 . A battery separator or method as in any preceding claim, wherein the ribs comprise a waved structure.
43 . A battery separator or method as in any preceding claim, wherein the ribs comprise a sinusoidal structure.
44 . A battery separator or method as in any preceding claim, wherein a porosity of the ribs is greater than or equal to 0% and less than or equal to 90%.
45 . A battery separator or method as in any preceding claim, wherein the battery separator comprises two or more porous layers.
46 . A battery separator or method as in any preceding claim, wherein the battery separator comprises a porous layer that is fibrous.
47 . A battery separator or method as in any preceding claim, wherein the battery separator comprises a porous layer that is a non-woven fiber web.
48 . A battery separator or method as in any preceding claim, wherein the non-woven fiber web is a wet laid non-woven fiber web, or a non-wet laid non-woven fiber web.
49 . A battery separator or method as in any preceding claim, wherein the battery separator comprises a porous layer that is an extruded layer, a sintered layer, a woven layer, a knitted layer, a braided layer, and/or a membrane.
50 . A battery separator or method as in any preceding claim, wherein a thickness of the porous layer is greater than or equal to 0.05 mm and less than or equal to 6 mm.
51 . A battery separator or method as in any preceding claim, wherein a volume porosity of the porous layer is greater than or equal to 0% and less than or equal to 98%.
52 . A battery separator or method as in any preceding claim, wherein the battery separator further comprises a glass mat, a pasting paper, and/or a fabric layer.
53 . A battery separator or method as in any preceding claim, wherein an electrical resistance of the porous layer is greater than or equal to 5 mΩ·cm 2 and less than or equal to 800 mΩ·cm 2 .
54 . A battery separator or method as in any preceding claim, wherein the battery separator comprises a conductive additive.
55 . A battery separator or method as in any preceding claim, wherein the battery separator comprises two or more conductive additives.
56 . A battery separator or method as in any preceding claim, wherein the conductive additive(s) comprise carbon, carbon nanotubes, and/or metallic particles.
57 . A battery separator or method as in any preceding claim, wherein the battery separator comprises a conductive coating.
58 . A battery separator or method as in any preceding claim, wherein the conductive coating was formed by vapor deposition.
59 . A battery separator or method as in any preceding claim, wherein the conductive coating comprises a metallic foil.
60 . A battery separator or method as in any preceding claim, wherein the battery separator comprises a sulfation-reducing additive.
61 . A battery separator or method as in any preceding claim, wherein the battery separator comprises two or more sulfation-reducing additives.
62 . A battery separator or method as in any preceding claim, wherein the sulfation-reducing additive(s) comprise a sulfate salt.
63 . A battery separator or method as in any preceding claim, wherein the sulfate salt comprises a monovalent cation.
64 . A battery separator or method as in any preceding claim, wherein the sulfate salt comprises a divalent cation.
65 . A battery separator or method as in any preceding claim, wherein the sulfate salt comprises sodium sulfate, magnesium sulfate, and/or barium sulfate.
66 . A battery separator or method as in any preceding claim, wherein the battery separator comprises an antimony-suppression additive.
67 . A battery separator or method as in any preceding claim, wherein the battery separator comprises two or more antimony-suppression additives.
68 . A battery separator or method as in any preceding claim, wherein the antimony-suppressing additive(s) comprise a fluorocarbon, a vinyl aldehyde, a ketone, an alkyl phosphonate, and/or natural rubber.
69 . A battery separator or method as in any preceding claim, wherein the battery separator comprises a water loss-reducing additive.
70 . A battery separator or method as in any preceding claim, wherein the battery separator comprises two or more water loss-reducing additives.
71 . A battery separator or method as in any preceding claim, wherein the water loss-reducing additive(s) comprise a sulfate and/or benzylideneacetone.
72 . A battery separator or method as in any preceding claim, wherein the sulfate comprises zinc sulfate and/or alkyl ammonium hydrogen sulfate.
73 . A battery separator or method as in any preceding claim, wherein the battery separator is positioned in a battery.
74 . A battery as in claim 73 , wherein the battery is a lead-acid battery.
75 . A battery as in claim 73 or 74 , wherein the battery is a flooded battery, a gel battery, an extended flooded battery, and/or a VRLA battery.