Pelletization of a polymer stabilizer mixture
The invention relates to a method for manufacturing a pellet in a pellet mill, which method comprises the steps of (A) pressing a mixture for compaction by a roller through a nozzle to obtain a strand, and (B) comminuting the strand to obtain the pellet, wherein the mixture for compaction comprises (i) 87 to 97 wt. % of a polymer stabilizer mixture polymer stabilizer mixture, which comprises the polymer stabilizers (i-1) 21 to 29 wt. % of tris(2,4-ditert-butylphenyl) phosphite (CAS-No. 31570-04-4), (i-2) 21 to 29 wt. % of tetrakis-[3-(3,5-ditert-butyl-4-hydroxy-phenyl)-propionyloxymethyl]methane (CAS-No. 6683-19-8), (i-3) 8 to 12 wt. % of a C16-C18 fatty acid calcium salt, (i-4) 36 to 44 wt. % of a calcium oxide, and wt. % of the polymer stabilizers (i-1), (i-2), (i-3) and (i-4) are based on the weight of the polymer stabilizer mixture, and (ii) 3 to 13 wt. % of a processing aid, which is a propylene-ethylene copolymer and which possesses a melting enthalpy below 100 J/g at 101.32 kPa. The pellet is useful for a dust-free handling of its polymer stabilizer mixture at a manufacturing of a stabilized polymer. Furthermore, a method for stabilizing a polymer, which is a polyolefin, a polystyrene or a mixture thereof, is disclosed, which comprises the dosing of the pellet to the polymer.
1 . A method for manufacturing a pellet in a pellet mill, which comprises a roller and a die with a nozzle, which method comprises the steps of
(A) pressing a mixture for compaction by the roller through the nozzle to obtain a strand, and
(B) comminuting the strand to obtain the pellet,
wherein the mixture for compaction comprises the components
(i) 87 to 97 wt. % of a polymer stabilizer mixture, which comprises the polymer stabilizers
(i-1) 21 to 29wt. % of tris (2,4-ditert-butylphenyl) phosphite (CAS-No. 31570-04-4),
(i-2) 21 to 29 wt. % of tetrakis-[3-(3,5-ditert-butyl-4-hydroxy-phenyl)-propionyloxymethyl] methane (CAS-No. 6683-19-8),
(i-3) 8 to 12 wt. % of a C16-C18 fatty acid calcium salt,
(i-4) 36 to 44 wt. % of a calcium oxide, and wt. % of the polymer stabilizers (i-1), (i-2), (i-3) and (i-4) are based on the weight of the polymer stabilizer mixture, and
(ii) 3 to 13 wt. % of a processing aid, which is a propylene-ethylene copolymer and which possesses a melting enthalpy below 100 J/g at 101.32 kPa, wherein the melting enthalpy is determined by a differential scanning calorimetry according to EN ISO 11357-3,
and wt. % of the components (i) and (ii) are based on the weight of the mixture for compaction.
2 . The method according to claim 1 , wherein the processing aid possesses a weight average molecular weight above 10000 Da and below 80000 Da, and wherein the weight average molecular weight of the processing aid is determined by gel permeation chromatography (GPC).
3 . The method according to claim 1 , wherein the processing aid possesses a melting peak temperature above 50° C. and below 85° C., wherein the melting peak temperature is determined by a differential scanning calorimetry according to EN ISO 11357-3.
4 . The method according to claim 1 , wherein the polymer stabilizer mixture contains (i-3) 8 to 12 wt. % of a C16-C18 fatty acid calcium salt and 80 to 100 parts by weight of the C16-C18 fatty acid calcium salt is calcium stearate or calcium palmitate and parts by weight are based on the overall amount of C16-C18 fatty acid calcium salt in the polymer stabilizer mixture, which is 100 parts by weight.
5 . The method according to claim 1 , wherein the calcium oxide is in the form of a powder and the powder is hydrophobized or untreated.
6 . The method according to claim 5 , wherein the powder is hydrophobized by treatment with a paraffin oil or a fatty acid.
7 . The method according to claim 1 , wherein the processing aid is a propylene-ethylene copolymer, which is a wax.
8 . The method according to claim 1 , wherein the mixture for compaction comprises
(i) 89 to 96 wt. % of the polymer stabilizer mixture, and
(ii) 4 to 11 wt. % of the processing aid.
9 . The method according to claim 1 , wherein the strand has a surface temperature above 45° C. and below 110° C., wherein the strand surface temperature is determined by measurement of its infrared irradiation.
10 . The method according to claim 1 , wherein the method comprises a step (pre-A) feeding the mixture for compaction into the pellet mill, wherein the mixture for compaction is in the form of a powder,
and the step (pre-A) occurs before the step (A).
11 . The method according to claim 1 , wherein the pellet mill is a ring die pellet mill, wherein the die has a geometric form of a ring with an inner side and an outer side and the nozzle represent a pass from the inner side to the outer side, or the pellet mill is a flat die pellet mill, wherein the die has a geometric form of a planar plate with an upper side and a lower side and the nozzle represents a pass from the upper side to the lower side.
12 . A pellet, which comprises the components
(i) 87 to 97 wt. % of a polymer stabilizer mixture, which comprises the polymer stabilizers
(i-1) 21 to 29 wt. % of tris (2,4-ditert-butylphenyl) phosphite (CAS-No. 31570-04-4),
(i-2) 21 to 29 wt. % of tetrakis-[3-(3,5-ditert-butyl-4-hydroxy-phenyl)-propionyl-oxymethyl] methane (CAS-No. 6683-19-8),
(i-3) 8 to 12 wt. % of a C16-C18 fatty acid calcium salt,
(i-4) 36 to 44 wt. % of a calcium oxide, and wt. % of the stabilizers (i-1), (i-2), (i-3) and (i-4) are based on the weight of the polymer stabilizer mixture, and
(ii) 3 to 13 wt. % of a processing aid, which is a propylene-ethylene copolymer and which possesses a melting enthalpy below 100 J/g at 101.32 kPa, wherein the melting enthalpy of the processing aid is determined by a differential scanning calorimetry according to EN ISO 11357-3,
and wt. % of the components (i) and (ii) are based on the weight of the pellet.
13 . The pellet according to claim 12 , which has a shape of a round rod and the round rod has a diameter of a circle, which is between 2 mm and 4 mm and has a length of 1 to 3 times of the diameter of a circle.
14 . A method for manufacturing of a stabilized polymer, which comprises the steps of
(AP) dosing a pellet as defined in claim 12 into a polymer to obtain a pellet-polymer mixture,
(BP) exposing the pellet-polymer mixture to a temperature in the range of 120 to 340° C. under mechanical stirring to obtain a stabilized polymer,
wherein the polymer is a polyolefin, a polystyrene or a mixture thereof.
15 . A mixture for compaction, which comprises the components
(i) 87 to 97 wt. % of a polymer stabilizer mixture in the physical form of a powder, which comprises the polymer stabilizers
(i-1) 21 to 29 wt. % of tris (2,4-ditert-butylphenyl) phosphite (CAS-No. 31570-04-4),
(i-2) 21 to 29 wt. % of tetrakis-[3-(3,5-ditert-butyl-4-hydroxy-phenyl)-propionyloxymethyl] methane (CAS-No. 6683-19-8),
(i-3) 8 to 12 wt. % of a C16-C18 fatty acid calcium salt,
(i-4) 36 to 44 wt. % of a calcium oxide, and wt. % of the polymer stabilizers (i-1), (i-2), (i-3) and (i-4) are based on the weight of the polymer stabilizer mixture, and
(ii) 3 to 13 wt. % of a processing aid in the physical form of a powder, which is a propylene-ethylene copolymer and which possesses a melting enthalpy below 100 J/g at 101.32 kPa, wherein the melting enthalpy of the processing aid is determined by a differential scanning calorimetry according to EN ISO 11357-3,
and wt. % of the components (i) and (ii) are based on the weight of the mixture for compaction.