IP Library › Granted Patent US 12,729,416
Granted Patent B2
US 12,729,416 · App. 18/278,916 · Granted Sep 8, 2026

Aluminum alloys and methods of making and use thereof

Inventors: Aihua Luo (Westerville, OH); Emre Cinkilic (Columbus, OH); Michael Moodispaw (Powell, OH)
Assignee: OHIO STATE INNOVATION FOUNDATION
C22C21/00
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Quick Facts
Patent No.
US 12,729,416
App. No.
18/278,916
Granted
Sep 8, 2026
Kind
B2
Abstract

Disclosed herein are aluminum alloys and methods of making and use thereof.

Claims (31)

1 . An aluminum alloy comprising:

from 0.3 to 1.5 wt % Fe;

from 0.2 to 16 wt % Ce;

from 0 to 2% Si; and

the balance comprising Al and optionally additional components;

wherein the ratio of Ce to Fe is 1.2 or more;

wherein the ratio of Ce to Fe being 1.2 or more suppresses formation of a Al 13 Fe 4 phase; and

wherein the aluminum alloy comprises a Al 10 FeCe 2 phase, which neutralizes the detrimental effect of Fe on the mechanical properties of the aluminum alloy.

2 . The aluminum alloy of claim 1 , wherein the aluminum alloy is substantially free of a Al 13 Fe 4 phase.

3 . The aluminum alloy of claim 1 , wherein the aluminum alloy comprises from 0.3 to 1 wt % Fe.

4 . The aluminum alloy of claim 1 , wherein the aluminum alloy comprises 0.2 to 9 wt % Ce.

5 . The aluminum alloy of claim 1 , wherein the aluminum alloy comprises from 0 to 0.5 wt % Si.

6 . The aluminum alloy of claim 1 , wherein the aluminum alloy is substantially free of Si.

7 . The aluminum alloy of claim 1 , wherein the aluminum alloy comprises from 0.3 to 1.5 wt % Fe; from 0.2 to 9 wt % Ce, from 0 to 2% Si; and the balance comprising Al and optionally additional components.

8 . The aluminum alloy of claim 1 , wherein the aluminum alloy comprises from 0.3 to 1 wt % Fe; from 0.2 to 2.5 wt % Ce; from 0 to 0.5% Si; and the balance comprising Al and optionally additional components.

9 . The aluminum alloy of claim 1 , wherein the aluminum alloy comprises 0.3 to 1 wt % Fe, 0.2 to 1.5 wt % Ce, and 0 to 0.5 wt % Si, and the balance comprising Al and optionally additional components.

10 . The aluminum alloy of claim 1 , wherein the AlCeSi phase is substantially absent from the aluminum alloy.

11 . The aluminum alloy of claim 1 , wherein the aluminum alloy further comprises Mn, Mg, Cu, Zn, or a combination thereof.

12 . The aluminum alloy of claim 1 , wherein the aluminum alloy further comprises from 0 to 1 wt % of one or more additional components.

13 . The aluminum alloy of claim 1 , wherein the aluminum alloy comprises from 0.3 to 1.5 wt % Fe; from 0.2 to 16 wt % Ce; from 0 to 2% Si; from 0 to 1 wt % Mn; from 0 to 1 wt % Mg; from 0 to 1 wt % Cu; from 0 to 1 wt % Zn; and the balance comprising Al.

14 . The aluminum alloy of claim 1 , wherein the aluminum alloy comprises from 0.3 to 1.5 wt % Fe; from 0.2 to 9 wt % Ce; from 0 to 2% Si; from 0 to 1 wt % Mn; from 0 to 1 wt % Mg; from 0 to 1 wt % Cu; from 0 to 1 wt % Zn; and the balance comprising Al.

15 . The aluminum alloy of claim 1 , wherein the aluminum alloy has:

a yield strength of from 55 MPa to 120 MPa;

an ultimate tensile strength of from 175 MPa to 250 MPa;

an elongation to failure of from 4% to 12%;

or a combination thereof.

16 . An object or article of manufacture comprising the aluminum alloy of claim 1 .

17 . A method of making the aluminum alloy of claim 1 , the method comprising:

heating a precursor aluminum alloy to a first temperature to melt the precursor aluminum alloy, thereby forming a molten precursor aluminum alloy; and

adding Ce to the molten precursor aluminum alloy;

thereby forming the aluminum alloy.

Assignments (2)
CONFIRMATORY LICENSE Recorded Sep 11, 2023
From: OHIO STATE UNIVERSITY
To: UNITED STATES DEPARTMENT OF ENERGY
Reel/Frame 064857/0517 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 25, 2023
From: LUO, AIHUA; CINKILIC, EMRE; MOODISPAW, MICHAEL
To: OHIO STATE INNOVATION FOUNDATION
Reel/Frame 064705/0032 →
Continuity (2)
Provisional Application 63154196 · Feb 26, 2021
Related Publication 20240060158A1 · Feb 22, 2024
References Cited (22)
US 3278300A · Koike · 1966 [cited by examiner]
US 3964935A · Wilks · 1976 [cited by applicant]
US 5306363A · Masumoto et al. · 1994 [cited by applicant]
US 6306342B2 · Koch et al. · 2001 [cited by applicant]
US 8337644B2 · Trenda et al. · 2012 [cited by applicant]
US 9963770B2 · Rios et al. · 2018 [cited by applicant]
US 10584403B2 · Rios et al. · 2020 [cited by applicant]
US 20180237893A1 · Rios et al. · 2018 [cited by applicant]
US 20190085431A1 · Rios et al. · 2019 [cited by applicant]
US 20220098706A1 · Luo et al. · 2022 [cited by applicant]
JP H01272739A · 1989 [cited by applicant]
WO WO2018044047A1 · 2018 [cited by examiner]
WO 2018119283A1 · 2018 [cited by applicant]
WO 2020180441A1 · 2020 [cited by applicant]
English Abstract and English Machine Translation of Kim et al. (WO 2018/044047 A1) (Mar. 8, 2018). [cited by examiner]
International Searching Authority (ISA/US). International Search Report and Written Opinion. PCT Application No. PCT/US2022/017815. Issued on May 16, 2022. 12 pages. [cited by applicant]
European Patent Office. Extended search report. Issued in EP Application No. 22760451.9. Jan. 17, 2025. 11 pages. [cited by applicant]
Ayer et al. (1988). Microstructural characterization of the dispersed phases in Al—Ce—Fe system. Metallurgical Transactions A, 19, 1645-1656. [cited by applicant]
Sims ZC et al. High performance aluminum-cerium alloys for high-temperature applications, Mater. Horiz. 2017, 4, 1070-1078. [cited by applicant]
Sims ZC et al. Cerium-Based, Intermetallic-Strengthened Aluminum Casting Alloy: High-Volume Co-product Development, JOM, 68(7), 1940-1947,2016. [cited by applicant]
Stromme ET et al. Ageless Aluminum-Cerium-Based Alloys in High-Volume Die Casting for Improved Energy Efficiency, JOM, 2018, 70(6), 866-871. [cited by applicant]
Weiss D et al. Casting Characteristics of High Cerium Content Aluminum Alloys, Light Metals, 2017, 205-211. [cited by applicant]