Catalyst composition comprising magnetic material adapted for inductive heating
The invention provides a catalyst composition, including a mixture of catalytically active particles and a magnetic material, such as superparamagnetic iron oxide nanoparticles, capable of inductive heating in response to an applied alternating electromagnetic field. The catalytically active particles will typically include a base metal, platinum group metal, oxide of base metal or platinum group metal, or combination thereof, and will be adapted for use in various catalytic systems, such as diesel oxidation catalysts, catalyzed soot filters, lean NOx traps, selective catalytic reduction catalysts, ammonia oxidation catalysts, or three-way catalysts. The invention also includes a system and method for heating a catalyst material, which includes a catalyst article that includes the catalyst composition and a conductor for receiving current and generating an alternating electromagnetic field in response thereto, the conductor positioned such that the generated alternating electromagnetic field is applied to at least a portion of the magnetic material.
1 . A catalyst composition, comprising catalytically active particles and a magnetic material, wherein:
the catalytically active particles comprise one or more catalytic metals impregnated or ion-exchanged in a porous support, wherein the porous support is a refractory metal oxide or a molecular sieve, and the one or more catalytic metals are selected from the group consisting of base metals, platinum group metals, oxides of base metals or platinum group metals, and combinations thereof;
the magnetic material is capable of inductive heating in response to an applied alternating electromagnetic field, wherein the magnetic material comprises a rare-earth containing particulate material comprising neodymium-iron-boron or samarium-cobalt particles, and the magnetic material has an average particle size of less than about 100 nm.
2 . The catalyst composition of claim 1 , wherein the magnetic material is superparamagnetic.
3 . The catalyst composition of claim 1 , wherein the magnetic material comprises superparamagnetic iron oxide nanoparticles.
4 . The catalyst composition of claim 1 , wherein the catalytically active particles are further adapted for use as a diesel oxidation catalyst (DOC), a catalyzed soot filter (CSF), a lean NOx trap (LNT), a selective catalytic reduction (SCR) catalyst, an ammonia oxidation (AMOx) catalyst, or a three-way catalyst (TWC).
5 . The catalyst composition of claim 1 , wherein the catalytically active particles are further adapted for use as a volatile organic hydrocarbon (VOC) oxidation catalyst or a room temperature hydrocarbon oxidation catalyst.
6 . The catalyst composition of claim 1 , wherein the molecular sieve is a zeolite.