METAMATERIAL-ENHANCED PHOTOCATALYTIC CONVERSION OF HYDROGEN SULFIDE

1 . A photoreactor system comprising:

a flow-through reaction space having at least one metamaterial-catalyst surface, the at least one metamaterial-catalyst surface comprising a metamaterial surface having a plurality of resonators patterned thereon and a plurality of photocatalyst particles located upon at least a portion of the resonators, within a gap between a first region and a second region of one or more resonators, or within a gap between adjacent resonators;

wherein the plurality of photocatalyst particles comprise at least one photocatalyst effective to convert hydrogen sulfide into elemental hydrogen and elemental sulfur upon exposure to electromagnetic radiation.

2 . The photoreactor system of claim 1 , wherein the flow-through reaction space is connected to a gas inlet for receiving a gas stream comprising hydrogen sulfide, a gas outlet for discharging elemental hydrogen, and a liquid outlet for discharging elemental sulfur.

3 . The photoreactor system of claim 1 , wherein the at least one metamaterial-catalyst surface receives electromagnetic radiation from a solar source, an artificial source, or any combination thereof.

4 . The photoreactor system of claim 3 , wherein the artificial source is present and located adjacent to the flow-through reaction space.

5 . The photoreactor system of claim 4 , wherein the artificial source comprises a light-emitting diode array.

6 . The photoreactor system of claim 4 , wherein the at least one metamaterial-catalyst surface is present upon a substrate that is at least partially transparent to solar radiation, such that the at least one metamaterial-catalyst surface receives a first input of electromagnetic radiation as solar radiation from a first face of the substrate and a second input of electromagnetic radiation from the artificial source.

7 . The photoreactor system of claim 4 , wherein the at least one metamaterial-catalyst surface is present upon a substrate that is opaque to solar radiation or is blocked from transmitting solar radiation to the plurality of resonators, such that the solar radiation is converted to heat and heating of the flow-through reaction space takes place when exposure to solar radiation occurs.

8 . The photoreactor system of claim 4 , wherein the at least one metamaterial-catalyst surface is present upon a first face of a substrate and a second plurality of resonators are located upon a second face of the substrate opposite the first face, the second plurality of resonators being capable of interacting with solar radiation, such that the solar radiation is converted to heat by the second plurality of resonators and heating of the flow-through reaction space takes place when exposure to solar radiation occurs.

9 . The photoreactor system of claim 4 , wherein the at least one metamaterial-catalyst surface is present upon a membrane resonator comprising a substrate having plurality of holes or slits defined therein, the membrane resonator dividing the flow-through reaction space into a first flow-through reaction space and a second flow-through reaction space.

10 . The photoreactor system of claim 4 , wherein the plurality of resonators are located upon a substrate that is substantially planar, and the flow-through reaction space or a portion thereof is linearly interposed between the substrate and the artificial source.

11 . The photoreactor system of claim 4 , wherein the plurality of resonators are located upon a substrate that is substantially non-planar and the artificial source is also substantially non-planar, and the flow-through reaction space or a portion thereof defines an annulus between the substrate and the artificial source.

12 . The photoreactor system of claim 1 , wherein the plurality of resonators comprise one or more of a split ring resonator, a dimer gap resonator, a Fano resonator, a metal-insulator-metal resonator, a nano-hole array resonator, or any combination thereof.

13 . A method comprising:

providing a gas stream comprising hydrogen sulfide;

interacting the gas stream in a flow-through reaction space with at least one metamaterial-catalyst surface, the at least one metamaterial-catalyst surface comprising a metamaterial surface having a plurality of resonators patterned thereon and a plurality of photocatalyst particles located upon at least a portion of the resonators, within a gap between a first region and a second region of one or more resonators, or within a gap between adjacent resonators;

wherein the plurality of photocatalyst particles comprise at least one photocatalyst effective to convert hydrogen sulfide into elemental hydrogen and elemental sulfur upon exposure to electromagnetic radiation;

exposing the at least one metamaterial-catalyst surface to electromagnetic radiation while interacting the at least one metamaterial-catalyst surface with the gas stream; and

obtaining elemental hydrogen and elemental sulfur after interacting the gas stream with the at least one metamaterial-catalyst surface.

14 . The method of claim 13 , wherein the electromagnetic radiation comprises ultraviolet electromagnetic radiation, visible electromagnetic radiation, infrared electromagnetic radiation, or any combination thereof.

15 . The method of claim 13 , wherein the electromagnetic radiation is received from a solar source, an artificial source, or any combination thereof.

16 . The method of claim 15 , wherein the artificial source is present and located adjacent to the flow-through reaction pathway, and at least a portion of the electromagnetic radiation is received from the artificial source.

17 . The method of claim 16 , wherein the artificial source is a light emitting diode array.

18 . The method of claim 13 , wherein the at least one metamaterial-catalyst surface is interacted with the gas stream at a temperature ranging from about 135° C. to about 155° C.

19 . A method comprising:

providing a feed stream comprising hydrogen sulfide;

interacting the feed stream in a flow-through reaction space with at least one metamaterial surface comprising a plurality of resonators patterned thereon;

exposing the at least one metamaterial surface to a plurality of photocatalyst particles while interacting the feed stream with the at least one metamaterial surface;

wherein the plurality of photocatalyst particles comprise at least one photocatalyst effective to convert hydrogen sulfide into elemental hydrogen and elemental sulfur upon exposure to electromagnetic radiation;

exposing the at least one metamaterial surface to electromagnetic radiation while interacting the at least one metamaterial surface with the feed stream; and

obtaining elemental hydrogen and elemental sulfur after interacting the feed stream with the at least one metamaterial surface.

20 . The method of claim 19 , wherein the feed stream comprises a gas stream or a liquid stream.

21 . The method of claim 20 , wherein the plurality of photocatalyst particles is introduced to the flow-through reaction space concurrently with the feed stream.

22 . The method of claim 19 , wherein the at least one metamaterial surface receives electromagnetic radiation from a solar source, an artificial source, or any combination thereof.

23 . The method of claim 22 , wherein the artificial source is present and located adjacent to the flow-through reaction pathway, and at least a portion of the electromagnetic radiation is received from the artificial source.