Ink composition, layer prepared therefrom, and display apparatus including the ink composition
Provided is an ink composition including: a scatterer; and a monomer, wherein the scatterer comprises a first scatterer and a second scatterer, the first scatterer is hydrophilic, and the second scatterer is hydrophobic.
1 . An ink composition comprising:
a scatterer; and
a monomer,
wherein the scatterer comprises a first scatterer and a second scatterer, and
the first scatterer is hydrophilic, and the second scatterer is hydrophobic,
wherein:
the first scatterer is a scatterer in which a first ligand-type compound or a first dispersant-type compound is coated on the scattering particle,
the first ligand-type compound:
comprises an amine group, but not a carboxyl group;
comprises not an amine group, but a carboxyl group; or
comprises both an amine group and a carboxyl group, wherein a difference between an amine value and an acid value is 5 mg KOH/g or more,
the first dispersant-type compound comprising a polymer chain comprising a polyacrylate-based polymer, a polyurethane-based polymer, and/or a polyethylene-based polymer,
the polymer chain:
comprises an amine group, but not a carboxyl group;
comprises not an amine group, but a carboxyl group; or
comprises both an amine group and a carboxyl group, wherein a difference between an amine value and an acid value is 5 mg KOH/g or more,
wherein the amine value is a converted mg value of KOH after neutralization titration of an amine group included in 1 g of the compound with HCl, and
the acid value is an mg value of KOH required for neutralization titration the carboxyl group included in 1 g of the compound with KOH.
2 . The ink composition of claim 1 , wherein the second scatterer is a scatterer in which a ligand-type compound or a dispersant-type compound is coated on a scattering particle.
3 . The ink composition of claim 2 , wherein the scattering particle comprises a metallic compound.
4 . The ink composition of claim 2 , wherein the scattering particle comprises Al 2 O 3 , SiO 2 , ZnO, ZrO 2 , BaTiO 3 , TiO 2 , Ta 2 O 5 , Ti 3 O 5 , ZnO—Al, Nb 2 O 3 , SnO, MgO, MgF 2 , or any combination thereof.
5 . The ink composition of claim 1 , wherein a total amount of the scatterer is in a range of about 1 wt % to about 70 wt %, based on 100 wt % of the total amount of the ink composition.
6 . The ink composition of claim 1 , wherein an amount of the first scatterer is in a range of about 0.1 wt % to about 5 wt %, and an amount of the second scatterer is in a range of about 7 wt % to about 60 wt %, based on 100 wt % of the total amount of the ink composition.
7 . The ink composition of claim 1 , wherein an amount of the second scatterer is in a range of about 0.1 wt % to about 5 wt %, and an amount of the first scatterer is in a range of about 7 wt % to about 60 wt %, based on 100 wt % of the total amount of the ink composition.
8 . The ink composition of claim 1 , further comprising a quantum dot.
9 . The ink composition of claim 8 , wherein the quantum dot comprises: a Group II-VI semiconductor compound; a Group III-V semiconductor compound; a Group III-VI semiconductor compound; a Group I-III-VI semiconductor compound; a Group IV-VI semiconductor compound; a Group IV element or compound; or any combination thereof.
10 . The ink composition of claim 9 , wherein the Group II-VI semiconductor compound comprises CdS, CdSe, CdTe, ZnS, ZnSe, ZnTe, ZnO, HgS, HgSe, HgTe, MgSe, MgS, CdSeS, CdSeTe, CdSTe, ZnSeS, ZnSeTe, ZnSTe, HgSeS, HgSeTe, HgSTe, CdZnS, CdZnSe, CdZnTe, CdHgS, CdHgSe, CdHgTe, HgZnS, HgZnSe, HgZnTe, MgZnSe, MgZnS, CdZnSeS, CdZnSeTe, CdZnSTe, CdHgSeS, CdHgSeTe, CdHgSTe, HgZnSeS, HgZnSeTe, HgZnSTe, or any combination thereof.
11 . The ink composition of claim 9 , wherein:
the Group III-V semiconductor compound comprises GaN, GaP, GaAs, GaSb, AlN, AlP, AlAs, AlSb, InN, InP, InAs, InSb, GaNP, GaNAs, GaNSb, GaPAs, GaPSb, AlNP, AlNAs, AlNSb, AlPAs, AlPSb, InGaP, InNP, InAlP, InNAs, InNSb, InPAs, InPSb, GaAlNP, GaAlNAs, GaAlNSb, GaAlPAs, GaAlPSb, GaInNP, GaInNAs, GaInNSb, GaInPAs, GaInPSb, InAlNP, InAlNAs, InAlNSb, InAlPAs, InAlPSb, or any combination thereof, and
the Group III-VI semiconductor compound comprises GaS, GaSe, GazSe 3 , GaTe, InS, InSe, In 2 S 3 , In 2 Se 3 , InTe, InGaS 3 , InGaSe 3 , or any combination thereof.
12 . The ink composition of claim 9 , wherein:
the Group I-III-VI semiconductor compound comprises AgInS, AgInS 2 , CuInS, CuInS 2 , CuGaO 2 , AgGaO 2 , AgAlO 2 , AgInGaS, or any combination thereof,
the Group IV-VI semiconductor compound comprises SnS, SnSe, SnTe, PbS, PbSe, PbTe, SnSeS, SnSeTe, SnSTe, PbSeS, PbSeTe, PbSTe, SnPbS, SnPbSe, SnPbTe, SnPbSSe, SnPbSeTe, SnPbSTe, or any combination thereof, and
the Group IV element or compound comprises Si, Ge, SiC, SiGe, or any combination thereof.
13 . A layer prepared by the ink composition of claim 1 .
14 . A display apparatus comprising:
a first substrate on which a light-emitting device is provided; and
a light controller on the first substrate and corresponding to the light-emitting device,
wherein the light controller comprises: a quantum dot layer and/or a scattering layer; a color filter layer; and a bank, and
the quantum dot layer and/or the scattering layer is a layer obtained by the ink composition of claim 1 .
15 . The display apparatus of claim 14 , wherein:
the quantum dot layer and/or the scattering layer is in contact with the bank,
a surface of the bank in contact with the quantum dot layer and/or the scattering layer is hydrophilic, and
in the quantum dot layer and/or the scattering layer, an amount of the first scatterer is in a range of about 0.1 wt % to about 5 wt %, and an amount of the second scatterer is in a range of about 7 wt % to about 60 wt %, based on 100 wt % of the total amount of the ink composition.
16 . The display apparatus of claim 14 , wherein:
the quantum dot layer and/or the scattering layer is in contact with the bank,
a surface of the bank in contact with the quantum dot layer and/or the scattering layer is hydrophobic, and
in the quantum dot layer and/or the scattering layer, an amount of the second scatterer is in a range of about 0.1 wt % to about 5 wt %, and an amount of the first scatterer is in a range of about 7 wt % to about 60 wt %, based on 100 wt % of the total amount of the ink composition.
17 . The display apparatus of claim 14 , wherein:
the light-emitting device comprises:
a first electrode; a second electrode facing the first electrode; and an interlayer between the first electrode and the second electrode and comprising an emission layer.
18 . The display apparatus of claim 17 , wherein:
the interlayer further comprises:
a hole transport region comprising a hole injection layer, a hole transport layer, an emission auxiliary layer, an electron blocking layer, or any combination thereof, and/or
an electron transport region comprising a hole blocking layer, an electron transport layer, an electron injection layer, or any combination thereof.
19 . An ink composition comprising:
a scatterer; and
a monomer,
wherein the scatterer comprises a first scatterer and a second scatterer, and
the first scatterer is hydrophilic, and the second scatterer is hydrophobic,
wherein:
the second scatterer is a scatterer in which a second ligand-type compound or a second dispersant-type compound is coated on the scattering particle,
the second ligand-type compound:
does not comprise an amine group and a carboxyl group; or
comprises both an amine group and a carboxyl group, wherein a difference between an amine value and an acid value is in a range of about 0 mg KOH/g to about 20 mg KOH/g,
the second dispersant-type compound comprises a polymer chain comprising a polyacrylate-based polymer, a polyurethane-based polymer, or a polyethylene-based polymer,
the polymer chain:
does not comprise an amine group and a carboxyl group; or
comprises both an amine group and a carboxyl group, wherein a difference between an amine value and an acid value is in a range of about 0 mg KOH/g to about 20 mg KOH/g,
wherein the amine value is a converted mg value of KOH after neutralization titration of an amine group included in 1 g of the compound with HCl, and
the acid value is an mg value of KOH required for neutralization titration the carboxyl group included in 1 g of the compound with KOH.