Potassium sodium niobate sputtering target and production method thereof
A potassium sodium niobate sputtering target having a relative density of 95% or higher. A method of producing a potassium sodium niobate sputtering target, including the steps of mixing a Nb 2 O 5 powder, a K 2 Co 3 powder, and a Na 2 Co 3 powder, pulverizing the mixed powder to achieve a grain size d 50 of 100 μm or less, and performing hot press sintering to the obtained pulverized powder in an inert gas or vacuum atmosphere under conditions of a temperature of 900° C. or higher and less than 1150° C., and a load of 150 to 400 kgf/cm 2 . A high density potassium sodium niobate sputtering target capable of industrially depositing potassium sodium niobate films via the sputtering method is provided.
1. A potassium sodium niobate sputtering target comprising, a relative density is 98% or higher, and a volume resistivity is exceeding 500 kΩcm, and a content ratio of potassium, sodium and niobium is Nb:K:Na=1.0:X:1−X, wherein X is 0.3≤X, in terms of atomic ratio, a flexural strength is 50 MPa or more, and an average crystal grain size is 1 to 20 μm.
2. A method of producing the potassium sodium niobate sputtering target according to claim 1 , wherein the method includes the steps of mixing a Nb 2 O 5 powder, a K 2 CO 3 powder, and a Na 2 CO 3 powder, pulverizing the mixed powder to achieve a grain size d 50 of 100 μm or less, performing hot press sintering to the obtained pulverized powder in an inert gas or vacuum atmosphere under conditions of a temperature of 900° C. or higher and less than 1150° C., and a load of 150 to 400 kgf/cm 2 , and the step of performing, after hot press sintering, heat treatment in an oxygen atmosphere or an air atmosphere at a temperature of 550° C. or higher and 1000° C. or less.