Structural supercapacitors with reinforced interfaces to increase multifunctional efficiency
View Patent ↗Embodiments of the presently disclosed technology provide improved structural supercapacitors that increase multi-functional efficiency (i.e., improve energy-storage and mechanical load-bearing capacity/performance). Structural supercapacitors of the present technology achieve such improvements in part by focusing on interfaces between structural electrodes and structural electrolytes. For example, the present technology can provide improved structural electrodes by coating carbon fiber-based structures with a uniquely stable conjugated redox polymer and a carbon-based compound. Such coating (at the interface between the structural electrode and a structural electrolyte) can improve and tensile strength for the structural electrode. The present technology can also provide improved structural electrolytes that leverage a “gradient” configuration for a structural electrolyte where composition of the structural electrolyte is tuned such that regions of the structural electrolyte immediately adjacent to structural electrodes incorporate a higher concentration of an ion-conducting polymer and salt than “middle” regions of the structural electrolyte.
1 . A structural supercapacitor comprising:
an electrode comprising a coating material coating a surface of the electrode that interfaces with a structural electrolyte, wherein the coating material comprises a conjugated redox polymer and a carbon-based compound; and
the structural electrolyte comprising an epoxy resin, an ion-conducting polymer, and a salt, wherein concentration of the salt in the structural electrolyte increases with increasing proximity to interfaces between the structural electrolyte and electrodes of the structural supercapacitor.
2 . The structural supercapacitor of claim 1 , wherein concentration of the ion-conducting polymer increases with increasing proximity to the interfaces between the structural electrolyte and the electrodes of the structural supercapacitor.
3 . The structural supercapacitor of claim 1 , wherein the conjugated redox polymer comprises a stable conjugated open shell redox polymer.
4 . The structural supercapacitor of claim 3 , wherein the stable conjugated open shell redox polymer comprises alternating bithiophene donors and thiophene substituted thiadiazoloquinoxaline acceptors.
5 . The structural supercapacitor of claim 3 , wherein the stable conjugated open shell redox polymer comprises poly-4,6,7,9-tetra(thiophen-2-yl)-[1,2,5]thiadiazolo[3,4-g]quinoxaline (poly-QxTh).
6 . The structural supercapacitor of claim 5 , wherein the carbon-based compound comprises reduced graphene oxide (rGO).
7 . The structural supercapacitor of claim 1 , wherein the electrode further comprises a core structure comprising a carbon fiber-based material.
8 . The structural supercapacitor of claim 1 , wherein the ion-conducting polymer comprises polyethylene oxide (PEO).
9 . The structural supercapacitor of claim 1 , further comprising a second structural electrolyte, wherein:
the coating material also coats a surface of the electrode that interfaces with the second structural electrolyte; and
the second structural electrolyte comprises the epoxy resin, the ion-conducting polymer, and the salt, wherein concentration of the salt within the second structural electrolyte increases with increasing proximity to interfaces between the second structural electrolyte and the electrodes of the structural supercapacitor.
10 . A structural electrode comprising:
a core structure; and
a coating material coating a surface of the structural electrode that interfaces with a structural electrolyte, wherein the coating material comprises a conjugated redox polymer and a carbon-based compound.
11 . The structural electrode of claim 10 , wherein the conjugated redox polymer comprises a stable conjugated open shell redox polymer.
12 . The structural electrode of claim 11 , wherein the stable conjugated open shell redox polymer comprises alternating bithiophene donors and thiophene substituted thiadiazoloquinoxaline acceptors.
13 . The structural electrode of claim 11 , wherein the stable conjugated open shell redox polymer comprises poly-4,6,7,9-tetra(thiophen-2-yl)-[1,2,5]thiadiazolo[3,4-g]quinoxaline (poly-QxTh).
14 . The structural electrode of claim 13 , wherein the carbon-based compound comprises reduced graphene oxide (rGO).
15 . The structural electrode of claim 14 , wherein a ratio of poly-QxTh to rGO in the coating material is between 3:1 and 1:1.
16 . The structural electrode of claim 10 , wherein the core structure comprises a carbon fiber-based material.
17 . A structural electrolyte comprising:
an epoxy resin;
an ion-conducting polymer; and
a salt;
wherein concentrations of the ion-conducting polymer and the salt in the structural electrolyte increase with increasing proximity to interfaces between the structural electrolyte and one or more electrodes.
18 . The structural electrolyte of claim 17 , wherein the concentrations of the ion-conducting polymer and the salt increase as gradients between a middle region of the structural electrolyte and the interfaces between the structural electrolyte and the one or more electrodes.
19 . The structural electrolyte of claim 17 , wherein:
concentration of the ion-conducting polymer in a middle region of the structural electrolyte is between 8% and 10% by weight; and
concentration of the salt in the middle region of the structural electrolyte is between 2% and 8% by weight.
20 . The structural electrolyte of claim 17 , wherein the ion-conducting polymer comprises polyethylene oxide (PEO).