IP Library Granted Patent US 12,414,387
Granted Patent B2
US 12,414,387 · App. 18/396,223 · Granted Sep 9, 2025

Photoconductive switch with diamond

Inventors: Joseph Devin Schneider (Danville, CA); Lars F. Voss (Livermore, CA); Noah Patrick Allen (Oakland, CA); Caitlin Anne Chapin (Fremont, CA); Laura Leos (Livermore, CA); Alexander Peter Povilus (Livermore, CA); Sara Harrison (Livermore, CA); John Berns Lancaster (Livermore, CA)
Assignee: Lawrence Livermore National Security, LLC
H01L31/09H01L31/022466H01L31/02327H01L31/0288
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Quick Facts
Patent No.
US 12,414,387
App. No.
18/396,223
Granted
Sep 9, 2025
Kind
B2
Abstract

Devices, methods and techniques related to photoconductive switches using diamond are disclosed. In one example aspect, a photoconductive apparatus includes a diamond layer positioned to receive a light. The diamond layer is doped with nitrogen. The apparatus also includes a first electrode coupled to the diamond layer to provide a first electrical contact for the diamond layer, and a second electrode coupled to the diamond layer to provide a second electrical contact for the diamond layer and configured to reflect the light back to the diamond layer. The first electrode and the second electrode are configured to establish an electric field across the diamond layer in response to receiving the light.

Claims (48)

1. A photoconductive device, comprising:

a first electrode configured as a first electrical contact;

a second electrode configured as a second electrical contact; and

a region comprising a doped diamond material positioned between the first electrode and the second electrode, wherein a center of the doped diamond material has a smaller thickness as compared to an edge of the doped diamond material, wherein:

the region comprising the doped diamond material is configured to receive light from a light source operable at a wavelength in a range from 300 nm to 450 nm,

the doped diamond material includes nitrogen as a dopant, and

the first electrode and the second electrode are configured to establish an electric field across the region comprising the doped diamond material such that the region becomes conductive in response to receiving the light from the light source.

2. The photoconductive device of claim 1 , wherein the first electrode is configured as a top electrode to allow the light to reach the region comprising the doped diamond material, and the second electrode is configured as a bottom electrode and includes a material that is reflective at a wavelength of the light that enters the doped diamond material and travels to the bottom electrode.

3. The photoconductive device of claim 1 , wherein the light from the light source is split into two paths, and wherein the region comprising the doped diamond material is configured to receive the two paths of the light from a first side of the doped diamond material and a second side of the doped diamond material respectively.

4. The photoconductive device of claim 1 , wherein the light comprises a blue light or an ultraviolet light.

5. The photoconductive device of claim 1 , wherein the doped diamond material is doped with nitrogen at a concentration level that ranges from 1×10 15 cm −3 to 1×1 20 cm −3 .

6. The photoconductive device of claim 1 , wherein at least one of the first electrode or the second electrode comprises an ultra-wide bandgap transparent material.

7. The photoconductive device of claim 6 , wherein the ultra-wide bandgap transparent material comprises gallium oxide.

8. The photoconductive device of claim 6 , wherein the ultra-wide bandgap transparent material is doped to be conductive.

9. The photoconductive device of claim 1 , wherein at least one of the first electrode or the second electrode comprises an open aperture that allows the light to enter the region comprising the doped diamond material.

10. The photoconductive device of claim 1 , further comprising:

an annulus of metal positioned outside of a region through which the light enters the region comprising the doped diamond material.

11. The photoconductive device of claim 1 , wherein at least one of the first electrode or the second electrode comprises an ultra-wide bandgap transparent material with a mirror configured to reflect the light.

12. The photoconductive device of claim 1 , comprising:

a patterned layer of material positioned on the doped diamond material, wherein the patterned layer is electrically conductive and optically transparent.

13. The photoconductive device of claim 12 , wherein the patterned layer comprises a metal grid.

14. A method for operating a photoconductive switch, comprising:

operating a light source capable of producing light at a wavelength between 300 to 450 nm;

directing the light to a diamond layer of the photoconductive switch by splitting the light into two paths, wherein the diamond layer is configured to receive the two paths of the light from a first side of the diamond layer and a second side of the diamond layer respectively, wherein the photoconductive switch further comprises a first electrode coupled to the diamond layer to provide a first electrical contact for the diamond layer and a second electrode coupled to the diamond layer to provide a second electrical contact for the diamond layer; and

changing the diamond layer from a non-conductive state to a conductive state in response to the light from the light source.

15. The method of claim 14 , wherein the light comprises a blue light or an ultraviolet light.

16. The method of claim 14 , wherein the diamond layer is doped with a nitrogen at a concentration level that ranges from 1×10 15 cm −3 to 1×1 20 cm −3 .

17. The method of claim 14 , wherein at least one of the first electrode or the second electrode comprises an ultra-wide bandgap material.

18. The method of claim 14 , wherein a center of the diamond layer has a smaller thickness as compared to an edge of the diamond layer.

19. The method of claim 14 , wherein the diamond layer comprises a patterned layer that is electrically conductive and optically transparent.

20. A photoconductive device, comprising:

a first electrode configured as a first electrical contact;

a second electrode configured as a second electrical contact; and

a region comprising a doped diamond material positioned between the first electrode and the second electrode, wherein:

the region comprising the doped diamond material is configured to receive light from a light source operable at a wavelength in a range from 300 nm to 450 nm,

the doped diamond material includes nitrogen as a dopant, and

the first electrode and the second electrode are configured to establish an electric field across the region comprising the doped diamond material such that the region becomes conductive in response to receiving the light from the light source,

wherein at least one of the first electrode or the second electrode comprises an ultra-wide bandgap transparent material that is doped to be conductive.

21. The photoconductive device of claim 20 , wherein the ultra-wide bandgap transparent material comprises gallium oxide.

22. A photoconductive device, comprising:

a first electrode configured as a first electrical contact;

a second electrode configured as a second electrical contact;

a region comprising a doped diamond material positioned between the first electrode and the second electrode; and

a patterned layer of material positioned on the doped diamond material, wherein the patterned layer is electrically conductive and optically transparent,

wherein the region comprising the doped diamond material is configured to receive light from a light source operable at a wavelength in a range from 300 nm to 450 nm,

wherein the doped diamond material includes nitrogen as a dopant, and

wherein the first electrode and the second electrode are configured to establish an electric field across the region comprising the doped diamond material such that the region becomes conductive in response to receiving the light from the light source.

23. The photoconductive device of claim 22 , wherein the patterned layer comprises a metal grid.

Assignments (3)
CORRECTIVE ASSIGNMENT TO CORRECT THE NAME OF INVENTOR LARS F. LARS TO LARS F. VOSS PREVIOUSLY RECORDED AT REEL: 70860 FRAME: 598. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT . Recorded Apr 21, 2025
From: VOSS, LARS F.; LEOS, LAURA; CHAPIN, CAITLIN ANNE; SCHNEIDER, JOSEPH DEVIN; POVILUS, ALEXANDER PETER; HARRISON, SARA; LANCASTER, JOHN BERNS; ALLEN, NOAH PATRICK
To: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
Reel/Frame 070904/0164 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 16, 2025
From: SCHNEIDER, JOSEPH DEVIN; LARS, LARS F.; LEOS, LAURA; CHAPIN, CAITLIN ANNE; POVILUS, ALEXANDER PETER; HARRISON, SARA; LANCASTER, JOHN BERNS; ALLEN, NOAH PATRICK
To: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
Reel/Frame 070860/0598 →
CONFIRMATORY LICENSE Recorded Jan 26, 2024
From: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
To: U.S. DEPARTMENT OF ENERGY
Reel/Frame 066255/0238 →
Continuity (2)
Provisional Application 63477946 · Dec 30, 2022
Related Publication 20240222541A1 · Jul 4, 2024
References Cited (5)
US 20080203397A1 · Amaratunga · 2008 [cited by examiner]
US 20180013028A1 · Nelson · 2018 [cited by examiner]
Beetz et al., “Nitrogen Laser Photoconductive Switching Of Semiconducting Diamond”, LEOS '92 Conference Proceedings, 1992, p. 154-155. (Year: 1992). [cited by examiner]
C. Masante et al, “Non-volatile photo-switch using a diamond pn junction,” Adv. Electron. Mater. 2022, 8, 2100542. [cited by applicant]
N Donato et al, “Diamond power devices: state of the art, modelling, figures of merit and future perspective,” J. Phys. D: Appl. Phys. 53 (2020) 093001. [cited by applicant]