REGENERATION OF POLYMERIC CYCLODEXTRIN ADSORBENTS
Methods for removing PFAS from cationic CDP adsorbents having adsorbed PFAS are provided. The method comprises contacting a volume of the cationic CDP adsorbent with a regeneration medium and separating the cationic CDP adsorbent from the regeneration medium.
1 . A method of removing PFAS from a cationic CDP adsorbent having adsorbed PFAS, comprising contacting a volume of the cationic CDP adsorbent with a regeneration medium comprising an alcohol, optionally water, and optionally at least one salt; and
separating the cationic CDP adsorbent from the regeneration medium,
whereby at least about 50% of the total adsorbed PFAS is removed from the cationic CDP adsorbent into the regeneration medium.
2 . The method of claim 1 , wherein the alcohol is selected from the group consisting of methanol, ethanol, and propanol.
3 . The method of claim 1 , wherein the regeneration medium further comprises water.
4 . The method of claim 2 , wherein the alcohol is ethanol.
5 . The method claim 3 , wherein the volumetric ratio of alcohol to water in the regeneration medium ranges from about 0.5:1 to about 10:0.
6 . The method of claim 1 , wherein the regeneration medium comprises a mixture of alcohol and water at a volumetric ratio of about 2:1.
7 . The method of claim 1 , wherein the regeneration medium further comprises a salt.
8 . The method of claim 7 , wherein the regeneration medium comprises a salt selected from the group consisting of alkali or alkaline earth metal or ammonium (NH 4 + ) chlorides, nitrates, sulfates, phosphates, formates, acetates, hydroxides, and combinations thereof.
9 . The method of claim 1 , wherein the regeneration medium comprises a salt selected from the group consisting of K 2 SO 4 , NaCl, LiCl, and KOH.
10 . The method of claim 7 , wherein the amount of salt in the regeneration medium ranges from about 0.01 wt. % to about 6 wt. %.
11 . The method of claim 10 , wherein the regeneration medium comprises about 2:1 (v/v) ethanol:water and about 0.5 g/L K 2 SO 4 .
12 . The method of claim 10 , wherein the regeneration medium comprises about 2:1 (v/v) ethanol:water and about 0.65 g/L NaCl.
13 . The method of claim 10 , wherein the regeneration medium comprises about 2:1 (v/v) ethanol:water and about 4 g/L LiCl.
14 . The method of claim 10 , wherein the regeneration medium comprises about 2:1 (v/v) ethanol:water and about 0.76 g/L KOH.
15 . The method of claim 10 , wherein the regeneration medium comprises 95% (v/v) ethanol:water and about 4 g/L LiCl.
16 . The method of claim 10 , wherein the regeneration medium comprises 95% (v/v) ethanol:water and about 0.76 g/L KOH.
17 . The method of claim 10 , wherein the regeneration medium comprises 95% (v/v) ethanol:water, and the regeneration medium is substantially free of a salt.
18 . The method of claim 1 , wherein the cationic CDP adsorbent is prepared by polymerizing β-cyclodextrin and a compound bearing a cationic functional group with:
(a) tetrafluoroterephthalonitrile; or
(b) toluene diisocyanate; or
(c) methylene diphenyl diisocyanate.
19 . The method of claim 18 , wherein the compound bearing a cationic functional group comprises a compound bearing a trimethylammonium group.
20 . The method of claim 19 , wherein the compound bearing a cationic functional group is choline chloride.
21 . The method of claim 1 , wherein said method is carried out at a temperature below the boiling point of the regeneration medium.
22 . The method of claim 1 , wherein the cationic CDP adsorbent is contained in a packed-bed vessel, and the regeneration medium flows from the bottom to the top of the packed-bed vessel.
23 . The method of claim 22 , wherein the regeneration medium has a flow rate at which the bed expansion rate ranges from about 30% to about 50%.
24 . The method of claim 1 , wherein the method is carried out in batch mode, and the contact period of the cationic CDP adsorbent having adsorbed PFAS with the regeneration medium ranges from about 10 minutes to about 24 hours.
25 . The method of claim 1 , wherein after the cationic CDP adsorbent is separated from the regeneration medium, the resulting regeneration medium containing PFAS removed from the cationic CDP adsorbent is further concentrated to increase the concentration of PFAS.
26 . The method of claim 25 , wherein the PFAS removed from the cationic CDP adsorbent is further concentrated using a method selected from the group consisting of membrane filtration, distillation, evaporation, and combinations thereof.
27 . The method of claim 25 , wherein the concentrated PFAS is in the form of a liquid.
28 . The method of claim 25 , wherein the concentrated PFAS is in the form of a solid.
29 . The method of claim 26 , wherein the concentrated PFAS is in the form of a liquid.
30 . The method of claim 26 , wherein the concentrated PFAS is in the form of a solid.