TWO-COMPONENT CURABLE COMPOSITIONS
Room temperature, two-component curable compositions and their uses are described. The curable compositions are alternative to isocyanate systems and are kinetically tunable to cure within seconds to months. The curable compositions are particularly useful as coatings, adhesives, sealants, and elastomers for consumer packages including food packages.
1 . A two-component curable composition comprising:
a) an oxirane or oxetane functionalized component and
b) a multifunctional acid derivative having a structure of (i)
wherein R′ and R″, independently are H or R′—═—R″ is an aromatic ring, and may further contain substitutions on the aromatic ring; m=0 or 1, n is a positive integer from 2 to 100, and X is a multifunctional radical backbone, and
wherein the multifunctional acid derivative is prepared from (1) a diacid precursor having the structure of (ii), which has a pKa1 of less than 3, or (2) the corresponding anhydride of the diacid (ii)
2 . The two-component curable composition of claim 1 , wherein the oxirane or oxetane functionalized component is selected from aliphatic or glycidyl epoxy resin.
3 . The two-component curable composition of claim 1 , wherein the oxirane or oxetane functionalized component has an epoxy functional group attached to a polymeric backbone selected from the group consisting of silicone, polybutadiene, 1,4-polyisoprenes, polyether, polyester, polyurethane, polycarbonate, polyacrylate, and mixtures thereof.
4 . The two-component curable composition of claim 1 ,
wherein the multifunctional acid derivative is selected from the group consisting of oxalic acid derivative, maleic acid derivative, fumaric acid derivative phthalic acid or trimellitic acid derivative.
5 . The two-component curable composition of claim 1 , further comprising a tackifier, plasticizer, catalyst, curing agent, solvent or additive.
6 . A two-component curable composition comprising:
a) an epoxidized oil prepared from a renewable triglyceride compound and
b) a multifunctional acid derivative having a structure of (i)
wherein R′ and R″, independently are H or R′—═—R″ is an aromatic ring, and may further contain substitutions on the aromatic ring; m=0 or 1, n is a positive integer from 2 to 100, and X is a multifunctional radical backbone, and
wherein the multifunctional acid derivative is prepared from (1) a diacid precursor having the structure of (ii), which has a pKa1 of less than 3, or (2) the corresponding anhydride of the diacid (ii)
7 . The two-component curable composition of claim 6 ,
wherein the renewable triglyceride compound is selected from the group consisting of oils from soybean, high oleic soybean, palm, rape, corn, cottonseed, linseed, linola, olive, rice, safflower, sesame, sunflower, and mixtures thereof.
8 . The two-component curable composition of claim 7 , wherein the renewable triglyceride compound is soybean oil, high oleic soybean oil, rape oil or palm oil.
9 . The two-component curable composition of claim 6 , wherein the multifunctional component is selected from the group consisting of oxalic acid, maleic acid, fumaric acid, phthalic acid, trimellitic acid, and corresponding derivatives.
10 . The two-component curable composition of claim 6 , further comprising a tackifier, plasticizer, catalyst, curing agent, solvent or additive.
11 . A two-component curable composition comprising:
a) oxirane or oxetane functionalized component and
b) di- or tri-carboxylic acid having a pKa 1 less than 3.0 and selected from the group consisting of oxalic acid, maleic acid, fumaric acid, phthalic acid, trimellitic acid, and derivatives thereof.
12 . The two-component curable composition of claim 11 ,
wherein the oxirane or oxetane functionalized component is selected from the group consisting of soybean, palm, rape, corn, cottonseed, linseed, linola, olive, rice, safflower, sesame, sunflower, and mixtures thereof.
13 . The two-component curable composition of claim 11 ,
wherein the oxirane or oxetane functionalized component is selected from aliphatic epoxy resin or glycidyl epoxy resin.
14 . The two-component curable composition of claim 11 , further comprising a tackifier, plasticizer, catalyst, curing agent, solvent or additive.
15 . The two-component curable composition of claim 11 , which is an adhesive, sealant, elastomer or coating.
16 . An article comprising the two-component curable composition of claim 11 .
17 . The article of claim 16 further comprising a substrate.
18 . The article of claim 17 which is a flexible packaging, laminate or film.