Liquid dispersion of quantum dot particles
Liquid dispersions of quantum dot particles include an acrylic medium having a boiling point in a range of from greater than or equal to 100° C. to less than or equal to 500° C., quantum dot particles dispersed in the acrylic medium, a photo-initiator, and a surface additive. The liquid dispersions of quantum dot particles are useful as stable liquid formulations that resist gelling for spin-coating and ink-jet printing of color conversion layers in the manufacture of LED and micro-LED panels for advanced displays. Methods of manufacturing light-emitting devices using the liquid dispersions of quantum dot particles are also disclosed.
1. A liquid dispersion of quantum dot particles comprising:
an acrylic medium having a boiling point in a range of from greater than or equal to 100° C. to less than or equal to 500° C., the acrylic medium comprising one or more of an acrylate monomer or an acrylamide monomer, the quantum dot particles dispersed in the acrylic medium;
a photo-initiator; and
a surface additive,
wherein the liquid dispersion of quantum dot particles comprises one or more of a red ink formulation, a green ink formulation, or a blue ink formulation, the red ink formulation including in a range of from 42 weight % to 73 weight % red quantum dot particles in 1,6-hexanediol diacrylate (HDDA), in a range of from 24 weight % to 54 weight % diethyl acrylamide (DEAA), in a range of from 2 weight % to 5 weight % photo-initiator, and in a range of from 0 weight % to 0.50 weight % surface additive, and
wherein the liquid dispersion of quantum dot particles comprises in a range of from 15 inorganic weight % to 25 inorganic weight % red quantum dot particles in the red ink formulation.
2. The liquid dispersion of quantum dot particles according to claim 1 , wherein the boiling point of the acrylic medium is in a range of from 180° C. to less than or equal to 500° C.
3. The liquid dispersion of quantum dot particles according to claim 2 , wherein the boiling point of the acrylic medium is in a range of from 180° C. to 250° C.
4. The liquid dispersion of quantum dot particles according to claim 1 , wherein the photo-initiator comprises one or more of diphenyl(2,4,6-trimethylbenzoyl)-phosphine oxide (TPO) or ethyl(2,4,6-trimethylbenzoyl)phenylphosphinate (TPO-L).
5. The liquid dispersion of quantum dot particles according to claim 1 , wherein the surface additive comprises a polyether-modified polydimethylsiloxane.
6. The liquid dispersion of quantum dot particles according to claim 1 , further comprising the green ink formulation, wherein the green ink formulation comprises in a range of from 57 weight % to 94 weight % green quantum dot particles in HDDA, in a range of from 2 weight % to 40 weight % HDDA, in a range of from 2 weight % to 5 weight % photo-initiator, and in a range of from 0 weight % to 0.50 weight % of a polyether-modified polydimethylsiloxane.
7. The liquid dispersion of quantum dot particles according to claim 6 , comprising in a range of from 20 inorganic weight % to 33 inorganic weight % green quantum dot particles in the green ink formulation.
8. The liquid dispersion of quantum dot particles according to claim 1 , further comprising the blue ink formulation, wherein the blue ink formulation comprises in a range of from 50 weight % to 98 weight % blue quantum dot particles in HDDA, in a range of from 2 weight % to 5 weight % photo-initiator, and in a range of from 0 weight % to 0.50 weight % of a polyether-modified polydimethylsiloxane.
9. The liquid dispersion of quantum dot particles according to claim 8 , comprising in a range of from 20 inorganic weight % to 40 inorganic weight % blue quantum dot particles in the blue ink formulation.
10. The liquid dispersion of quantum dot particles according to claim 1 , having a viscosity in a range of from 5 to 30 centipoise (cP) at a temperature in a range of from 20° C. to 25° C.
11. The liquid dispersion of quantum dot particles according to claim 1 , having a surface tension in a range of from 20 to 25 dynes per centimeter (dyne/cm).
12. A liquid dispersion of quantum dot particles comprising:
an acrylic medium having a boiling point in a range of from greater than or equal to 100° C. to less than or equal to 500° C., the acrylic medium comprising one or more of an acrylate monomer, a diacrylate monomer, or an acrylamide monomer, the quantum dot particles dispersed in the acrylic medium;
a photo-initiator;
a surface additive; and
at least one additional acrylic monomer, the at least one additional acrylic monomer comprising diethyl acrylamide (DEAA), isobornyl acrylate (IBOA), 1,4-butanediol diacrylate (BDA), nonanediol diacrylate (NDDA), trimethylolpropane triacrylate (TMPTA), or a mixture thereof.
13. The liquid dispersion of quantum dot particles according to claim 12 , wherein the acrylic medium has the same composition as the at least one additional acrylic monomer.
14. The liquid dispersion of quantum dot particles according to claim 12 , wherein the acrylic medium comprises 1,6-hexanediol diacrylate (HDDA).