Electrolyte membrane for lithium-air battery, method of manufacturing same and lithium-air battery comprising same
Disclosed are an electrolyte membrane for a lithium-air battery, a method of manufacturing the same, a cathode for a lithium-air battery, a method of manufacturing the same, and a lithium-air battery including the electrolyte membrane and the cathode. Particularly, the lithium-air battery includes i) an electrolyte membrane, which is manufactured using an inorganic melt admixture including two or more nitrogen-oxide compounds and thus may have a very low eutectic point, and ii) a cathode, which is manufactured by reducing a metal at a fast speed on a carbon material. As such, the lithium-air battery is capable of stably operating even at low temperatures and providing high power output.
1 . An electrolyte membrane for a lithium-air battery manufactured by a method, wherein the method comprises:
preparing an inorganic salt;
preparing an inorganic melt admixture by melting the inorganic salt;
immersing a separator in the inorganic melt admixture; and
drying the immersed separator,
wherein the separator has pores therein, and the inorganic melt admixture is incorporated into and attached to inner and outer portions of the separator,
wherein the inorganic salt comprises:
three types of the nitrogen-oxide compounds, four types of the nitrogen-oxide compounds, or five types of the nitrogen-oxide compounds,
wherein the three types of the nitrogen-oxide compounds comprise an amount of about 29 mol % to 35 mol % of lithium nitrate, an amount of about 51 mol % to 56 mol % of potassium nitrite and an amount of about 10 mol % to 15 mol % of cesium nitrate,
the four types of the nitrogen-oxide compounds comprise an amount of about 27 mol % to 31 mol % of lithium nitrate, an amount of about 38 mol % to 50 mol % of potassium nitrate, an amount of about 11 mol % to 20 mol % of sodium nitrate and an amount of about 10 mol % to 13 mol % of calcium nitrate, and
the five types of the nitrogen-oxide compounds comprise an amount of about 14 mol % to 17 mol % of lithium nitrate, an amount of about 29 mol % to 31 mol % of potassium nitrate, an amount of about 28 mol % to 32 mol % of cesium nitrate, an amount of about 9 mol % to 11 mol % of sodium nitrate and an amount of about 13 mol % to 18 mol % of calcium nitrate,
all the mol % based on the total mole of the nitrogen-oxide compounds,
wherein the inorganic salt has a eutectic point of about 100° C. or less.
2 . A lithium-air battery, comprising:
a cathode comprising a carbon material;
an anode disposed to face the cathode and comprising a lithium metal that receives and releases a lithium ion; and
the electrolyte membrane of claim 1 , interposed between the cathode and anode.
3 . The lithium-air battery of claim 2 , wherein the carbon material comprises one or more selected from the group consisting of natural graphite, artificial graphite, carbon nanotubes, reduced graphene oxide (rGO), carbon fiber, carbon black, Ketjen black, acetylene black, mesoporous carbon, graphite, Denka black, fullerene, and activated carbon.
4 . The electrolyte membrane for a lithium-air battery of claim 1 , wherein the inorganic salt comprises the five types of the nitrogen-oxide compounds, and
wherein the five types of the nitrogen-oxide compounds comprise an amount of about 14 mol % to 17 mol % of lithium nitrate, an amount of about 29 mol % to 31 mol % of potassium nitrate, an amount of about 28 mol % to 32 mol % of cesium nitrate, an amount of about 9 mol % to 11 mol % of sodium nitrate and an amount of about 13 mol % to 18 mol % of calcium nitrate.