IP Library Granted Patent US 12,293,997
Granted Patent B2
US 12,293,997 · App. 18/451,234 · Granted May 6, 2025

3D printable feedstock inks for signal control or computation

Inventors: Maxwell Murialdo (Westminster, CA); Yuliya Kanarska (Livermore, CA); Andrew J. Pascall (Livermore, CA)
Assignee: Lawrence Livermore National Security, LLC
H01L25/16H01L25/07H01L25/50H05K1/16H05K3/30
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 12,293,997
App. No.
18/451,234
Granted
May 6, 2025
Kind
B2
Abstract

The present disclosure relates to a method for forming an electrically conductive ink able to be deposited through a print nozzle during a 3D printing operation. The method may involves providing an electrically non-conductive flowable material adapted to be flowed through a print nozzle during a 3D printing operation. A predetermined quantity of chiplets may then be mixed into flowable material, in accordance with a predefined percolation threshold, to form a percolating chiplet network within the polymer as the ink is flowed through the print nozzle and deposited on a surface. The chiplets each form an engineered electronic component, and ones of the chiplets randomly connect, in accordance with the predefined percolation threshold, to form an electrically conductive circuit having a predetermined circuit characteristic.

Claims (62)

1. A method for forming an electrically conductive ink able to be deposited through a print nozzle during a 3D printing operation, comprising:

providing an electrically non-conductive flowable material adapted to be flowed through a print nozzle during a 3D printing operation;

mixing a predetermined quantity of chiplets, in accordance with a predefined percolation threshold, into the non-conductive flowable material to form a percolating chiplet network within the polymer as the ink is flowed through the print nozzle and deposited on a surface, wherein the chiplets each form an engineered electronic component, and ones of the chiplets randomly connect, in accordance with the predefined percolation threshold, to form an electrically conductive circuit having a predetermined circuit characteristic.

2. The method of claim 1 , wherein the percolating chiplet network formed by the chiplets implements a predetermined logic function.

3. The method of claim 2 , wherein the predetermined logic function comprises at least one of:

a diode logic function;

a silicon controlled rectifier logic function;

a Zener diode logic function; or

a thyristor logic function;

a transistor logic function.

4. The method of claim 3 , wherein the predetermined logic function comprises at least two of:

a diode logic function;

a silicon controlled rectifier logic function;

a Zener diode logic function; or

a thyristor logic function;

a transistor logic function.

5. The method of claim 1 , wherein the predetermined circuit characteristic forms an inductance.

6. The method of claim 1 , wherein the providing a non-conductive flowable material comprises providing a non-conductive flowable polymer.

7. The method of claim 1 , wherein the mixing a predetermined quantity of chiplets into the non-conductive flowable material comprises mixing a plurality of chiplets which each comprise a logic section, a first conductive portion forming a first conductive leg, and a second conductive portion forming a second conductive leg, with the predetermined circuit characteristic forming a logic portion, and the logic portion being located between the first and second conductive portions and in electrical communication with the first and second conductive portions.

8. The method of claim 1 , further comprising mixing in a predetermined plurality of nanoscale elements into the non-conductive flowable material along with the predetermined quantity of chiplets, the predetermined plurality of nanoscale elements aiding in forming the engineered electronic circuit.

9. The method of claim 1 , wherein the mixing in a predetermined plurality of chiplets comprises mixing in a predetermined plurality of chiplets each having a shape in accordance with at least one of:

a rectangular shape;

an oval shape;

an elliptical shape;

a frusto-conical shape;

a cylindrical shape; or

a pyramid shape.

10. The method of claim 1 , wherein the mixing in a predetermined plurality of chiplets comprises mixing in a plurality of microcoils.

11. The method of claim 10 , further comprising applying at least one of a current or a magnetic field after depositing the ink to effect a controlled curing process in which the microcoils aligned in a desired orientation within the electrically non-conductive material.

12. The method of claim 1 , further comprising mixing in at least one of a ferro fluid or a magnetorheological fluid into the non-conductive material along with the predetermined quantity of chiplets.

13. The method of claim 1 , wherein the mixing in a predetermined quantity of chiplets comprises mixing in a predetermined quantity of chiplets each having at least one of the following dimensional feature:

a length of about 200 microns; or

a width of about 20 microns; or

a thickness of about 20 microns.

14. The method of claim 1 , wherein the mixing in a predetermined quantity of chiplets comprises mixing in a predetermined quantity of chiplets having different dimensions.

15. The method of claim 1 , wherein the ink, once deposited on the surface, further includes at least one of the following properties:

being flexible;

having a shape memory property; or

having an inductive property.

16. A method for forming an electrically conductive ink able to be deposited through a print nozzle during a 3D printing operation, comprising:

providing an electrically non-conductive flowable polymer material adapted to be flowed through a print nozzle during a 3D printing operation;

mixing a predetermined quantity of chiplets, in accordance with a predefined percolation threshold, into the non-conductive flowable polymer to form a percolating chiplet network within the polymer as the ink is flowed through the print nozzle and deposited on a surface, wherein at least a subportion of the predetermined quantity of chiplets each form an engineered electronic component providing a logic function, and ones of the chiplets randomly connect, in accordance with the predefined percolation threshold, to form an electrically conductive circuit having a predetermined circuit characteristic.

17. The method of claim 16 , wherein mixing in a predetermined quantity of chiplets comprises mixing in chiplets of having two different types of predetermined logic functions.

18. The method of claim 16 , further comprising mixing in a quantity of at least one of a ferrofluid or a magnetorheological fluid into the electrically non-conductive polymer.

19. The method of claim 16 , further comprising mixing in a quantity of electrically conductive elements into the electrically non-conductive polymer along with the predetermined quantity of chiplets.

20. A method for forming an electrically conductive ink able to be deposited through a print nozzle during a 3D printing operation, comprising:

providing an electrically non-conductive flowable polymer material adapted to be flowed through a print nozzle during a 3D printing operation;

mixing a predetermined quantity of chiplets, in accordance with a predefined percolation threshold, into the non-conductive flowable polymer to form a percolating chiplet network within the polymer as the ink is flowed through the print nozzle and deposited on a surface, wherein at least a subportion of the predetermined quantity of chiplets each form an engineered electronic component providing a logic function, and ones of the chiplets randomly connect, in accordance with the predefined percolation threshold, to form an electrically conductive circuit having a predetermined circuit characteristic;

wherein at least a subquantity of the predetermined quantity of chiplets includes chiplets having at least one of:

a rectangular shape;

an oval shape;

an elliptical shape;

a frusto-conical shape;

a cylindrical shape;

a pyramid shape;

a coil shape; and

wherein the predetermined logic function includes at least one of:

a diode logic function;

a silicon controlled rectifier logic function;

a Zener diode logic function; or

a thyristor logic function;

a transistor logic function.

Assignments (1)
CONFIRMATORY LICENSE (SEE DOCUMENT FOR DETAILS) Recorded Oct 2, 2023
From: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
To: U.S. DEPARTMENT OF ENERGY
Reel/Frame 065101/0394 →
Continuity (3)
Division 17375788 · Jul 14, 2021
Division 16219188 · Dec 13, 2018
Related Publication 20240006390A1 · Jan 4, 2024
References Cited (17)
US 20160198576A1 · Lewis et al. · 2016 [cited by applicant]
Toffoli, T. and Margolus, N. Programmable matter: concepts and realization. Physica. D, Nonlinear phenomena, 47(1-2), 1991, pp. 263-272. [cited by applicant]
Shin, D.G., Kim, T.H. and Kim, D.E. Review of 4D printing materials and their properties. International Journal of Precision Engineering and Manufacturing-Green Technology, 4(3), 2017, pp. 349-357. [cited by applicant]
Kokkinis, D., Schaffner, M. and Studart, A.R. Multimaterial magnetically assisted 3D printing of composite materials. Nature communications, 6, 2015, p. 8643. [cited by applicant]
Momeni, F., Liu, X. and Ni, J. A review of 4D printing. Materials & design, 122, 2017, pp. 42-79. [cited by applicant]
Ge, Q., Dunn, C.K., Qi, H.J. and Dunn, M.L. Active origami by 4D printing. Smart Materials and Structures, 23(9), 2014, p. 094007. [cited by applicant]
Van Manen, T., Janbaz, S. and Zadpoor, A.A. Programming 2D/3D shape-shifting with hobbyist 3D printers. Materials horizons, 4(6), 2017, pp. 1064-1069. [cited by applicant]
Tibbits, S. 4D printing: multi-material shape change. Architectural Design, 84(1), 2014, pp. 116-121. [cited by applicant]
Wu, A.S., Small IV, W., Bryson, T.M., Cheng, E., Metz, T.R., Schulze, S.E., Duoss, E.B. and Wilson, T.S. 3D printed silicones with shape memory. Scientific reports, 7(1), 2017, p. 4664. [cited by applicant]
Ding, Z., Yuan, C., Peng, X., Wang, T., Qi, H.J. and Dunn, M.L. Direct 4D printing via active composite materials. Science advances, 3(4), 2017, p. e1602890. [cited by applicant]
Ota, H., Emaminejad, S., Gao, Y., Zhao, A., Wu, E., Challa, S., Chen, K., Fahad, H.M., Jha, A.K., Kiriya, D. and Gao, W. Application of 3D printing for smart objects with embedded electronic sensors and systems. Advance… [cited by applicant]
Iyer, V., Chan, J. and Gollakota, S. 3D printing wireless connected objects. ACM Transactions on Graphics (TOG), 36(6), 2017, p. 242. [cited by applicant]
Rodriguez, J.N., Zhu, C., Duoss, E.B., Wilson, T.S., Spadaccini, C.M. and Lewicki, J.P. Shape-morphing composites with designed micro-architectures. Scientific reports, 6, 2016, p. 27933. [cited by applicant]
Gao, Y., Li, H. and Liu, J. Directly writing resistor, inductor and capacitor to composite functional circuits: a super-simple way for alternative electronics. PLoS One, 8(8), 2013, p. e69761. [cited by applicant]
Saengchairat, N., Tran, T. and Chua, C.K. A review: Additive manufacturing for active electronic components. Virtual and Physical Prototyping, 12(1), 2017, pp. 31-46. [cited by applicant]
Poblete Ramírez, V., Álvarez, M.P. and Fuenzalida Escobar, V. Conductive Copper-PMMA Nanocomposites: Microstructure, Electrical Behavior, and Percolation Threshold as a Function of Metal Filler Concentration, 2009. [cited by applicant]
Yunus, D.E., Shi, W., Sohrabi, S. and Liu, Y. Shear induced alignment of short nanofibers in 3D printed polymer composites. Nanotechnology, 27(49), 2016, p. 495302. [cited by applicant]