Granted Patent B2

US 12,252,649 · App. 18/473,727 · Granted Mar 18, 2025

Inventors: Ataur Malik (Abqaiq, SA); Mohammed A. Asiri (Udhailiyah, SA); Saad Al-Driweesh (Udhailiyah, SA); Rajesh Kumar Saini (Cypress, TX); Mohammad Hamidul Haque (Katy, TX); Mohammed Sayed (Katy, TX)

Assignee: Saudi Arabian Oil Company

C09K8/805C09K8/64C09K8/703E21B43/267C09K2208/08C09K2208/10C09K2208/30

Abstract

Claims (22)

1. A system for hydraulic fracturing, comprising:

a source of fracturing fluid;

a pump operationally coupled to the source to provide the fracturing fluid through a wellbore into a subterranean formation to hydraulically fracture the subterranean formation to generate fractures in the subterranean formation, wherein the fracturing fluid conveys proppant into the fractures, wherein the proppant comprises resin coating comprising unfunctionalized organic resin and functionalized nanoparticles that adhere to the unfunctionalized organic resin, wherein nanoparticles are reacted with at least one of an alkoxysilane solution or a halosilane solution to form the functionalized nanoparticles comprising at least one of a fluorosilane moiety, a perfluorosilane moiety, or an alkylsilane moiety for incorporation into the resin coating, and

wherein a surface modifier is applied to the resin coating prior to inclusion of the proppant in the fracturing fluid, and the surface modifier comprising at least one of an alkyl fluorosilane, a fluorinated surfactant, a fluorinated polymer, or a fluorinated polymeric surfactant; and

a control system to intermittently adjust a characteristic of the fracturing fluid conveying the proppant to form pillars of proppant in the fractures.

2. The system of claim 1 , wherein to intermittently adjust the characteristic comprises to adjust the characteristic at a frequency comprising an interval in a range of 2 minutes to 100 minutes, and wherein the characteristic comprises rheology or proppant suspension, or both.

3. The system of claim 2 , wherein the rheology comprises viscosity.

4. The system of claim 1 , wherein the characteristic comprises concentration of a surfactant in the fracturing fluid.

5. The system of claim 1 , wherein the characteristic comprises concentration of microparticles or concentration of nanoparticles, or both, in the fracturing fluid.

6. The system of claim 1 , wherein the fracturing fluid is foam fracturing fluid, wherein the characteristic comprises concentration of a foaming surfactant in the foam fracturing fluid.

7. The system of claim 1 , wherein the fracturing fluid is foam fracturing fluid, wherein the characteristic comprises foam quality (FQ) of the foam fracturing fluid, and wherein to intermittently adjust the FQ comprises to adjust, in the foam fracturing fluid, at least one of an amount of gas, an amount of supercritical fluid, an amount of water, or an amount of brine to form the pillars of proppant in the fractures.

8. The system of claim 1 , wherein the fracturing fluid comprises viscoelastic surfactant (VES)-based fracturing fluid, wherein the characteristic comprises concentration of VES in the VES-based fracturing fluid.

9. The system of claim 1 , wherein the fracturing fluid comprises VES-based fracturing fluid, and wherein the characteristic comprises salinity of brine incorporated the VES-based fracturing fluid.

10. The system of claim 1 , wherein the fracturing fluid comprises VES-based fracturing fluid, and wherein the characteristic comprises a type of salt in the VES-based fracturing fluid.

11. The system of claim 1 , wherein the fracturing fluid comprises oil-based fracturing fluid, and wherein the characteristic comprises concentration of crosslinker metal ions in the oil-based fracturing fluid.

12. The system of claim 1 , wherein the fracturing fluid comprises emulsion fracturing fluid, and wherein the characteristic comprises at least one of concentration of an emulsifying surfactant in the emulsion fracturing fluid or ratio of water to oil in the emulsion fracturing fluid.

13. The system of claim 1 , wherein the proppant comprises sand, and wherein the resin coating is coated on an outer surface of the sand.

14. The system of claim 1 , wherein the resin coating comprises a resin nanocomposite coating comprising the nanoparticles as a nanoreinforcing agent uniformly distributed throughout the resin nanocomposite coating.

15. The system of claim 1 , wherein the functionalized nanoparticles comprise nanotubes, nanofibers, or nanoplatelets, or any combinations thereof.

16. The system of claim 1 , wherein the functionalized nanoparticles comprise first nanoparticles comprising graphene and second nanoparticles comprising carbon nanotubes.

17. The system of claim 1 , wherein the unfunctionalized organic resin comprises phenolic resin, epoxy resin, furan resin, polyurethane resin, polyurea resin, polyester, polyamideimide resin, polyamide resin, polyurea/polyurethane resin, urea-formaldehyde resin, melamine resin, silicone resin, vinyl ester resin, phenol-formaldehyde resin, novolac, or resole, or any combinations thereof.

18. The system of claim 1 , wherein the surface modifier is at least one selected from the group consisting of an alkyl fluorosilane solution, a fluorinated surfactant, a fluorinated polymer, and a fluorinated polymeric surfactant.

Assignments (4)

Continuity (2)

References Cited (65)