IP Library Granted Patent US 12,152,191
Granted Patent B1
US 12,152,191 · App. 18/488,694 · Granted Nov 26, 2024

Methods and compositions of low specific gravity eutectic composite particles

Inventors: Ashok Santra (The Woodlands, TX); Christelle Y. Mbuncha (Houston, TX); Arthur Herman Hale (Houston, TX)
Assignee: SAUDI ARABIAN OIL COMPANY
C09K8/467C04B14/34C04B18/022C04B28/02E21B33/138C04B2103/0071
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Quick Facts
Patent No.
US 12,152,191
App. No.
18/488,694
Granted
Nov 26, 2024
Kind
B1
Abstract

A eutectic composite may be utilized in oil and gas servicing. For example, a method of making such a composite may include: crosslinking a mixture including a polymer, a metaphosphate salt, and a plurality of eutectic alloy particles to yield a eutectic composite; and producing a plurality of eutectic composite particles from the eutectic composite. Furthermore, an example composition may include: a cement; water; and a plurality of eutectic composite particles including eutectic alloy particles dispersed in a polymer crosslinked with a metaphosphate salt.

Claims (8)

1. A method comprising:

introducing a cement slurry into a wellbore penetrating a subterranean formation, wherein the cement slurry comprises a cement, water, and a plurality of eutectic composite particles that comprise eutectic alloy particles dispersed in a polymer crosslinked with a metaphosphate salt; and

allowing the cement slurry to set to a concrete in a downhole zone of interest.

2. The method of claim 1 , wherein the downhole zone of interest is an annulus between a wellbore wall and a tubular therein, an annulus between two tubulars, a microannulus, or a combination thereof.

3. The method of claim 1 , wherein the metaphosphate salt comprises sodium hexametaphosphate, sodium trimetaphosphate, or a combination of sodium hexametaphosphate and sodium trimetaphosphate.

4. The method of claim 1 , wherein the eutectic alloy comprises a bismuth-tin alloy, a bismuth-lead alloy, a bismuth-tin-lead alloy, or any combination thereof.

5. The method of claim 1 , wherein the volume ratio of the polymer crosslinked with the metaphosphate salt to the eutectic alloy is about 3:7 to about 9:1.

6. The method of claim 1 , wherein the plurality of eutectic composite particles have a specific gravity of about 1 g/cm 3 to about 4 g/cm 3 .

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 12, 2024
From: SAUDI ARAMCO UPSTREAM TECHNOLOGY COMPANY
To: SAUDI ARABIAN OIL COMPANY
Reel/Frame 067972/0109 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 12, 2024
From: ARAMCO SERVICES COMPANY
To: SAUDI ARAMCO UPSTREAM TECHNOLOGY COMPANY
Reel/Frame 067972/0025 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 17, 2023
From: SANTRA, ASHOK; MBUNCHA, CHRISTELLE Y.; HALE, ARTHUR HERMAN
To: ARAMCO SERVICES COMPANY
Reel/Frame 065256/0594 →