ANISOTROPIC IRON NITRIDE PERMANENT MAGNETS
Disclosed herein is a permanent magnet comprising: a plurality of aligned iron nitride nanoparticles wherein the iron nitride nanoparticles include α″-Fe 16 N 2 phase domains; wherein a ratio of integrated intensities of an α″-Fe 16 N 2 (004) x-ray diffraction peak to an α″-α″-Fe 16 N 2 (202) x-ray diffraction peak for the aligned iron nitride nanoparticles is greater than at least 7%, wherein the diffraction vector is parallel to alignment direction, and wherein the iron nitride nanoparticles exhibit a squareness measured parallel to the alignment direction that is greater than a squareness measured perpendicular to the alignment direction.
1 . A method of forming an anisotropic permanent magnet, the method comprising:
annealing an iron-containing agglomerated powder in the presence of nitrogen to provide iron nitride nanoparticles;
dispersing the iron nitride nanoparticles in a fluid;
removing excess fluid;
combining the iron nitride nanoparticles with a binder composition to provide a nanoparticle binder mixture;
aligning the nanoparticle binder mixture with an external force, and
curing the nanoparticle binder mixture to form a permanent magnet.
2 . The method of claim 1 , wherein the iron nanoparticles have an intrinsic coercivity from 2,000 to 4,000 Oe.
3 . The method of claim 1 , wherein the iron nanoparticles have an intrinsic coercivity from 2,500 to 4,000 Oe.
4 . The method of claim 1 , wherein the iron nanoparticles have an intrinsic coercivity from 3,000 Oe to 4,000 Oe;
5 . The method of claim 1 , wherein the fluid is aqueous.
6 . The method of claim 1 , wherein the step of dispersing the iron nitride nanoparticles in a fluid includes: introducing the iron nitride nanoparticles to a mixture of water and one or more additives to provide an aqueous solution; and subjecting the aqueous solution to a process of ultrasonication and/or wet ball milling.
7 . The method of claim 6 , wherein the one or more additives comprises a dispersing agent, a stabilizer, a wetting agent, a surfactant, a viscosity modifier, a corrosion inhibitor, emulsifier or any combination thereof.
8 . The method of claim 1 , wherein the fluid is non-aqueous.
9 . The method of claim 1 , wherein after the step of removing excess fluid the iron nitride nanoparticles are dried by freeze drying, spray drying, debinding, solvent exchange, or any combination thereof.
10 . The method of claim 1 , wherein the external force is a magnetic field.
11 . A permanent magnet formed according to the method of claim 1 , wherein the permanent magnet exhibits a squareness measured in a parallel direction that is larger than a squareness observed in a perpendicular direction to the direction of alignment of the nanoparticles, and wherein the permanent magnetic exhibits an X-ray diffraction pattern having a relative intensity of an α″-Fe 16 N 2 (004) peak that is greater than the intensity of the most-intense α|-Fe 16 N 2 (202) peak in a diffraction pattern, where the diffraction vector is parallel to the alignment direction.
12 . A permanent magnet formed according to the method of claim 1 , wherein a ratio of integrated intensities of an α″-Fe 16 N 2 (004) x-ray diffraction peak to an α″-Fe 16 N 2 (202) x-ray diffraction peak for the iron nitride nanoparticles is greater than at least 7%, where the diffraction vector is parallel to alignment direction.