Ink jet ink composition, ink set, recording method, and recording apparatus
An ink jet ink composition is provided which contains water, a (meth)acrylic resin, and a wax emulsion and which is a water-based clear ink, and the (meth)acrylic resin described above satisfies predetermined requirements.
1 . An ink jet ink composition which contains water, a (meth)acrylic resin, and a wax emulsion and which is a water-based clear ink, the (meth)acrylic resin satisfying the following requirements 1 to 6,
wherein in the requirement 1, the (meth)acrylic resin includes 90 percent by mass or more of a (meth)acrylic acid-based monomer as a constituent component,
the (meth)acrylic resin is a diblock copolymer including a polymer block A and a polymer block B, 50 percent by mass or more of a monomer forming the (meth)acrylic resin is a (meth)acrylate having a plant material-derived alcohol as an ester residue,
the (meth)acrylate includes at least one selected from the group consisting of ethyl (meth)acrylate, tetrahydrofurfuryl (meth)acrylate, and isobornyl (meth)acrylate, and
the (meth)acrylic resin has a biomass degree of 20% or more,
in the requirement 2, the polymer block A of the (meth)acrylic resin is a substantially water-insoluble polymer block,
the polymer block A has a number average molecular weight of 5,000 to 30,000, and
the polymer block A has a molecular weight distribution of 1.0 to 1.6,
in the requirement 3, the polymer block B of the (meth)acrylic resin includes (meth)acrylic acid as a constituent component,
the polymer block B has a number average molecular weight of 1,000 to 10,000, and
the polymer block B has an acid value of 50 to 330 mgKOH/g,
in the requirement 4, the polymer block A and the polymer block B both have a glass transition temperature of 70° C. or more, in the requirement 5, the (meth)acrylic resin has a
number average molecular weight of 10,000 to 40,000, and the (meth)acrylic resin has an acid value of 25 to 100 mgKOH/g, and
in the requirement 6, the (meth)acrylic resin has a carboxy group neutralized with an alkali and is emulsified in water, and
the (meth)acrylic resin has a number average particle diameter of 10 to 300 nm measured by light scattering.
2 . The ink jet ink composition according to claim 1 ,
wherein the polymer block A and the polymer block B both include isobornyl (meth)acrylate as a constituent component.
3 . The ink jet ink composition according to claim 1 ,
wherein 80 percent by mass or more of the monomer forming the (meth)acrylic resin includes as a constituent component, at least one selected from the group consisting of ethyl (meth)acrylate, tetrahydrofurfuryl (meth)acrylate, and isobornyl (meth)acrylate.
4 . The ink jet ink composition according to claim 1 ,
wherein the ink jet ink composition includes a dry solid content having a biomass degree of 10 percent by mass or more.
5 . The ink jet ink composition according to claim 1 ,
wherein the ink jet ink composition has a surface tension of less than 30 mN/m at 25° C.
6 . The ink jet ink composition according to claim 1 ,
further containing a silicone-acrylic resin.
7 . The ink jet ink composition according to claim 1 ,
wherein a content of the (meth)acrylic resin with respect to a total mass of the ink jet ink composition is 0.5 to 15 percent by mass.
8 . The ink jet ink composition according to claim 1 ,
wherein a content of the wax emulsion with respect to a total mass of the ink jet ink composition is 0.3 to 3.0 percent by mass.
9 . An ink set comprising:
a clear ink; and
a color ink,
wherein the clear ink is the ink jet ink composition according to claim 1 .
10 . A recording method comprising:
an ejection step of ejecting the ink jet ink composition according to claim 1 to a recording medium by an ink jet method.
11 . The recording method according to claim 10 , further comprising:
an ejection step of ejecting a color ink to the recording medium by an ink jet method,
wherein the ink jet ink composition and the color ink are adhered to the recording medium so as to be overlapped with each other.
12 . The recording method according to claim 10 ,
wherein the recording method is a multi-pass type recording method or a one-pass type recording method.
13 . The recording method according to claim 10 ,
wherein the recording is performed using a long recording medium by a roll-to-roll method.
14 . The recording method according to claim 10 ,
wherein the recording medium is a low-absorbing recording medium or a non-absorbing recording medium.
15 . A recording apparatus comprising:
an ink jet head to eject the ink jet ink composition according to claim 1 to a recording medium.