Solid-state hybrid supercapacitor with nickel-cobalt-layered double hydroxide nanoflowers supported on jute stick-derived activated carbon nanosheets
An electrode including a substrate, a binding compound, and a composite. The composite includes jute-activated carbon and a nickel-cobalt-layered double hydroxide (NiCoLDH). Particles of the NiCoLDH are in the form of nanoflowers with an average size of 5-15 μm. The nanoflowers comprise nanosheets with an average thickness of 5-20 nm. The particles of the jute-activated carbon are in the form of interconnected nanosheets, which form a porous carbon framework. The porous carbon framework connects the nanoflowers, thereby forming an interconnected structure in the composite. A mixture of the composite and the binding compound is coated on the surface of the substrate. The electrode can be included in supercapacitors and power banks.
1 . An electrode, comprising:
a substrate;
a binding compound, and
a composite,
wherein the composite comprises:
jute activated carbon; and
a nickel-cobalt-layered double hydroxide (NiCoLDH),
wherein particles of the NiCoLDH are in a form of nanoflowers with an average size of 5-15 μm,
wherein the nanoflowers comprise nanosheets with an average thickness of 5-20 nm,
wherein particles of the jute activated carbon are in a form of interconnected nanosheets which form a porous carbon framework,
wherein the porous carbon framework connects the nanoflowers thereby forming an interconnected structure in the composite, and
wherein a mixture of the composite and the binding compound is coated on a surface of the substrate.
2 . The electrode of claim 1 , wherein the mixture comprises 70-95 wt. % of the composite, based on a total weight of the binding compound and the composite.
3 . The electrode of claim 1 , wherein the NiCoLDH comprises Co 2+ and Co 3+ .
4 . The electrode of claim 1 , wherein the NiCoLDH has a molar ratio of Ni to Co of 1:2 to 2:1.
5 . The electrode of claim 1 , wherein the nanosheets of the NiCoLDH have an average width of 50-500 nm and an average length of greater than 100 nm.
6 . The electrode of claim 1 , wherein the nanosheets of the jute activated carbon have an average thickness of from 7 to 15 nm and an average width of 50-200 nm.
7 . The electrode of claim 1 , wherein the porous carbon framework of the jute activated carbon comprises pores greater than 200 nm in size.
8 . The electrode of claim 1 , wherein a surface area of the jute activated carbon is greater than 2,000 m 2 /g.
9 . The electrode of claim 1 , wherein the jute activated carbon has a pore volume of from 0.5-1.5 cm 3 /g.
10 . The electrode of claim 1 , wherein the composite comprises 25-45 wt. % carbon, 15-35 wt. % oxygen, 10-30 wt. % cobalt, and 10-30 wt. % nickel, based on a total weight of the composite.
11 . A method of making the electrode of claim 1 , comprising:
pyrolyzing jute sticks at a temperature of 300-500° C. to form partially carbonized jute powder;
mixing the partially carbonized jute powder with a base and pyrolyzing at a temperature of 700-900° C. to form the jute activated carbon;
mixing a cobalt salt, a nickel salt, and cetrimonium bromide in a solvent to form a first solution;
heating the first solution and the jute activated carbon in an autoclave for 10-20 hours at a temperature of 150-250° C. to form the composite; and
coating the surface of the substrate with the mixture to form the electrode.
12 . A supercapacitor, comprising:
a negative electrode;
the electrode of claim 1 as a positive electrode; and
a solid-state electrolyte,
wherein the negative electrode comprises:
a second substrate;
the jute activated carbon; and
a binding compound,
wherein a second mixture of the jute activated carbon and the binding compound is coated on a surface of the second substrate,
wherein the positive and negative electrodes are disposed facing each other, and
wherein the solid-state electrolyte is present between the positive and negative electrodes to form the supercapacitor.
13 . The supercapacitor of claim 12 , wherein the substrate and the second substrate are made from at least one material selected from the group consisting of stainless steel, aluminum, nickel, copper, platinum, zinc, tungsten, and titanium.
14 . The supercapacitor of claim 12 , wherein the solid-state electrolyte comprises a base and a polymer.
15 . The supercapacitor of claim 12 , wherein the solid-state electrolyte comprises polyvinyl alcohol and potassium hydroxide.
16 . The supercapacitor of claim 12 , having a specific capacitance of 700-800 F/g at a current density of 0.5 A/g.
17 . The supercapacitor of claim 12 , having an energy density of 90-110 Wh/kg at a power density of 250 W/kg.
18 . The supercapacitor of claim 12 , having a capacitance retention of at least 85% after 10,000 charge-discharge cycles.
19 . A power bank, comprising:
2-10 of the supercapacitors of claim 12 connected in parallel and/or series.