ELECTROCHEMICAL CELL INCLUDING SOLUTION INFUSED LAYER
An electrochemical cell comprises a first electrode configured for a first electrochemical half reaction, a first electrolyte solution in contact with the first electrode, a second electrode configured for a second electrochemical half reaction, a second electrolyte solution in contact with the second electrode, a separator positioned between the first electrode and the second electrode, and a first porous layer in contact with the first electrode, wherein the first porous layer is infused with a first specified solution comprising a first reactant for the first electrochemical half reaction.
1 . An electrochemical cell comprising:
a first electrode configured for a first electrochemical half reaction;
a first electrolyte solution in contact with the first electrode;
a second electrode configured for a second electrochemical half reaction;
a second electrolyte solution in contact with the second electrode;
a separator positioned between the first electrode and the second electrode; and
a first porous layer in contact with the first electrode, wherein the first porous layer is infused with a first specified solution comprising a first reactant for the first electrochemical half reaction.
2 . The electrochemical cell of claim 1 , wherein the separator comprises an anion exchange membrane.
3 . The electrochemical cell of claim 1 , wherein the porous layer comprises at least one of: a paper layer, a felt layer, a fibrous woven layer, a fibrous non-woven layer, a porous polymer layer, and a foam layer.
4 . The electrochemical cell of claim 1 , wherein the first specified solution comprises the first electrolyte solution.
5 . The electrochemical cell of claim 1 , wherein the first porous layer is between the first electrode and the separator.
6 . The electrochemical cell of claim 5 , wherein the first porous layer is in contact with the separator.
7 . The electrochemical cell of claim 1 , further comprising a second porous layer in contact with the second electrode, wherein the second porous layer is infused with a second specified solution comprising a second reactant for the second electrochemical half reaction.
8 . The electrochemical cell of claim 6 , wherein the second specified solution comprises the second electrolyte solution.
9 . The electrochemical cell of claim 1 , further comprising a solution supply to resupply the first specified solution to the first porous layer.
10 . The electrochemical cell of claim 1 , wherein the first electrode is an anode of the electrochemical cell, the second electrode is a cathode of the electrochemical cell, the first electrochemical half reaction is an oxygen evolution reaction that produces oxygen gas (O 2 ), and the second electrochemical half reaction is a hydrogen evolution reaction that produces hydrogen gas (H 2 ).
11 . The electrochemical cell of claim 10 , wherein the first electrolyte solution has a first pH, the second electrolyte solution has a second pH, and the first pH is higher than the second pH.
12 . The electrochemical cell of claim 10 , further comprising a second porous layer in contact with the cathode, wherein the second porous layer is infused with a second specified solution comprising a second reactant for the hydrogen evolution reaction, and wherein the first reactant comprises hydroxide ions (OH − ) and the second reactant comprises water (H 2 O).
13 . A method of electrolysis, the method comprising:
providing an electrochemical cell comprising a separator having a first side and an opposing second side, a first electrode configured for a first electrochemical reaction positioned on the first side of the separator, a second electrode configured for a second electrochemical reaction positioned on the second side of the separator, and a first porous layer in contact with the first electrode;
infusing the first porous layer with a first electrolyte solution comprising a first reactant for the first electrochemical half reaction;
contacting the second electrode with a second electrolyte solution;
passing current between the first electrode and the second electrode; and
producing hydrogen gas (H 2 ) at one of the first electrode and the second electrode, and producing oxygen gas (O 2 ) at the other of the first electrode and the second electrode.
14 . The method of claim 13 , wherein the separator is an anion exchange membrane.
15 . The method of claim 13 , wherein the porous layer comprises at least one of: a paper layer, a felt layer, a fibrous woven layer, a fibrous non-woven layer, a porous polymer layer, and a foam layer.
16 . The method of claim 13 , wherein the first porous layer is between the first electrode and the separator.
17 . The method of claim 16 , wherein the first porous layer is in contact with the separator.
18 . The method of claim 13 , wherein the electrochemical cell further comprises a second porous layer in contact with the second electrode and wherein the second electrolyte solution comprises a second reactant for the second electrochemical half reaction, the method further comprising infusing the second porous layer with the second electrolyte solution.
19 . The method of claim 13 , wherein the second porous layer is between the second electrode and the separator.
20 . The method of claim 13 , further comprising resupplying the first specified solution to the first porous layer.
21 . The method of claim 13 , wherein the first electrode is an anode of the electrochemical cell, the second electrode is a cathode of the electrochemical cell, the first electrochemical half reaction is an oxygen evolution reaction that produces the oxygen gas (O 2 ), and the second electrochemical half reaction is a hydrogen evolution reaction that produces the hydrogen gas (H 2 ).
22 . The method of claim 21 , wherein the first electrolyte solution has a first pH, the second electrolyte solution has a second pH, and the first pH is higher than the second pH.
23 . The method of claim 21 , wherein the electrochemical cell further comprises a second porous layer in contact with the cathode, wherein the second porous layer is infused with the second electrolyte solution, wherein the second electrolyte solution comprises a second reactant for the hydrogen evolution reaction, and wherein the first reactant comprises hydroxide ions (OH − ) and the second reactant comprises water (H 2 O).