Propylene-ethylene copolymer compositions suitable for hot fill packaging of foodstuffs
A propylene-ethylene copolymer includes propylene as a primary monomer, an ethylene content (ET) of 3.0% to 5% by weight, a melt flow rate of from 20 to 45 g/10 min, a xylene soluble fraction (XS) of from 2.0% to 7.0% by weight, and an XS/ET ratio of less than or equal to 1.51.
1 . A propylene-ethylene copolymer comprising:
propylene as a primary monomer;
an ethylene content (ET) of 3.0% to 5% by weight;
a melt flow rate of from 20 to 45 g/10 min;
a xylene soluble fraction (XS) of from 2.0% to 7.0% by weight; and
a xylene soluble fraction to ethylene content ratio (XS/ET) of less than or equal to 1.49.
2 . The propylene-ethylene copolymer of claim 1 , wherein the ethylene content is from 3.0% to 4.2% by weight.
3 . The propylene-ethylene copolymer of claim 1 , wherein the melt flow rate is 20 to 40 g/10 min.
4 . The propylene-ethylene copolymer of claim 1 , wherein the xylene ratio XS/ET is from 0.90 to 1.4.
5 . The propylene-ethylene copolymer of claim 1 , wherein the ratio XS/ET is less than 1.30.
6 . The propylene-ethylene copolymer of claim 1 , wherein the ratio XS/ET is less than 1.00.
7 . The propylene-ethylene copolymer of claim 1 , wherein the xylene soluble fraction (XS) and the ethylene content (ET) are below a line defined by equation XS=2.1e 0.297 (ET) .
8 . The propylene-ethylene copolymer of claim 1 , wherein the xylene soluble fraction (XS) and the ethylene content (ET) are above a line defined by equation XS=1.4e 0.297 (ET) .
9 . The propylene-ethylene copolymer of claim 1 , wherein the copolymer is formed using a Ziegler-Natta catalyst and a dicyclopentyldimethoxysilane (DCPDMS) based donor.
10 . The propylene-ethylene copolymer of claim 1 , wherein the copolymer is formed using a Ziegler-Natta catalyst and a n-propyltrimethoxysilane (NPTMS) based donor.
11 . The propylene-ethylene copolymer of claim 1 , wherein the copolymer is produced without the use of metallocenes.
12 . The propylene-ethylene copolymer of claim 1 , wherein the copolymer has a molecular weight distribution (Mw/Mn) of greater than about 3.5.
13 . A polymer composition containing the propylene-ethylene copolymer of claim 1 , wherein the propylene-ethylene copolymer is present in the polymer composition in an amount greater than about 70% by weight.
14 . The polymer composition of claim 13 , further comprising a clarifying agent.
15 . The polymer composition of claim 14 , wherein the clarifying agent comprises a dibenzyl sorbitol.
16 . The polymer composition of claim 14 , wherein the clarifying agent comprises a nonitol.
17 . The polymer composition of claim 14 , wherein the polymer composition displays a haze at 40 mil of less than about 15% and wherein after thermal aging for 24 hours at 55° C., the haze decreases by no more than about 15%.
18 . An injection molded article comprising the propylene-ethylene copolymer of claim 1 .
19 . A hot fill packaging container comprising the propylene-ethylene copolymer of claim 1 .
20 . A propylene-ethylene copolymer comprising:
propylene as a primary monomer;
an ethylene content (ET) of about 3.0% to about 5% by weight;
a melt flow rate of from 20 to 45 g/10 min;
a xylene soluble fraction (XS) of from 2.0% to 7.0% by weight;
a molecular weight distribution greater than about 6.0 and
a xylene soluble fraction to ethylene content
a ratio (XS/ET) of less than or equal to 1.51.