METHOD FOR PRODUCING RESIN COMPOSITION FOR SECONDARY BATTERY ELECTRODES, METHOD FOR PRODUCING MIXTURE SLURRY FOR SECONDARY BATTERY ELECTRODES, METHOD FOR PRODUCING ELECTRODE FILM, AND METHOD FOR PRODUCING SECONDARY BATTERY
Provided is a method for producing a resin composition for secondary battery electrodes, the method comprising adding a binder resin to a carbon nanotube dispersion liquid which contains carbon nanotubes, a dispersing agent, and a nonaqueous dispersion medium and in which the product (X×Y) of the complex elastic modulus X(Pa) and the phase angle Y(°) at 25° C. and 1 Hz obtained by dynamic viscoelastic measurement is 30 to 1,700 and the phase angle is 3° to 90°.
1 . A method for producing a resin composition for secondary battery electrodes, comprising
adding a binder resin to a carbon nanotube dispersion solution containing carbon nanotubes, a dispersing agent, and a non-aqueous dispersion medium and having a product (X×Y) of a complex elastic modulus X(Pa) and a phase angle Y(°) at 25° C. and 1 Hz obtained by dynamic viscoelastic measurement that is 30 or more and 1,700 or less and a phase angle of 3° or more and 90° or less, without adding an active material.
2 . The method for producing a resin composition for secondary battery electrodes according to claim 1 ,
wherein the carbon nanotube dispersion solution has a complex elastic modulus at 25° C. and 1 Hz obtained by dynamic viscoelastic measurement that is 0.1 Pa or more and 200 Pa or less.
3 . The method for producing a resin composition for secondary battery electrodes according to claim 1 ,
wherein the resin composition for secondary battery electrodes has a complex elastic modulus at 25° C. and 1 Hz obtained by dynamic viscoelastic measurement that is 0.1 Pa or more and 300 Pa or less.
4 . The method for producing a resin composition for secondary battery electrodes according to claim 1 ,
wherein the resin composition for secondary battery electrodes has a phase angle at 25° C. and 1 Hz obtained by dynamic viscoelastic measurement that is 3° or more and 90° or less.
5 . The method for producing a resin composition for secondary battery electrodes according to claim 1 ,
wherein the binder resin in a powder form is added to the carbon nanotube dispersion solution.
6 . The method for producing a resin composition for secondary battery electrodes according to claim 1 ,
wherein the content of the carbon nanotubes contained in the carbon nanotube dispersion solution based on a total amount of the carbon nanotube dispersion solution is 0.5 mass % or more and 10 mass % or less.
7 . The method for producing a resin composition for secondary battery electrodes according to claim 1 ,
wherein the carbon nanotubes contained in the carbon nanotube dispersion solution include single-walled carbon nanotubes and multi-walled carbon nanotubes.
8 . The method for producing a resin composition for secondary battery electrodes according to claim 1 ,
wherein a mass proportion of the binder resin with respect to the carbon nanotubes contained in the carbon nanotube dispersion solution is 10 mass % or more and 300 mass % or less.
9 . The method for producing a resin composition for secondary battery electrodes according to claim 1 ,
wherein the carbon nanotubes contained in the carbon nanotube dispersion solution include one of single-walled carbon nanotubes and multi-walled carbon nanotubes,
the method comprises additionally adding, when one of single-walled carbon nanotubes and multi-walled carbon nanotubes is dispersed in the carbon nanotube dispersion solution, the other of single-walled carbon nanotubes and multi-walled carbon nanotubes before, after, at the same time, or a combination thereof as when a binder resin is added to the carbon nanotube dispersion solution.
10 . The method for producing a resin composition for secondary battery electrodes according to claim 9 ,
wherein a mass proportion of the binder resin based on a total amount of the carbon nanotubes contained in the resin composition is 10 mass % or more and 300 mass % or less.
11 . The method for producing a resin composition for secondary battery electrodes according to claim 1 ,
wherein the carbon nanotube dispersion solution further contains carbon black.
12 . The method for producing a resin composition for secondary battery electrodes according to claim 1 , comprising
additionally adding carbon black before, after, at the same time, or a combination thereof as when a binder resin is added to the carbon nanotube dispersion solution.
13 . A method for producing a mixture slurry for secondary battery electrodes, comprising:
producing a resin composition for secondary battery electrodes by the method according to claim 1 and adding an active material to the resin composition.
14 . The method for producing a mixture slurry for secondary battery electrodes according to claim 13 , comprising
additionally adding carbon black before, after, at the same time, or a combination thereof as when an active material is added to the resin composition.
15 . A method for producing an electrode film, comprising
producing a mixture slurry for secondary battery electrodes by the method according to claim 13 , and forming an electrode film by applying the mixture slurry.
16 . A method for producing a secondary battery, comprising
producing a mixture slurry for secondary battery electrodes by the method according to claim 13 , and forming an electrode film by applying the mixture slurry onto a current collector.