PREVENTION OF SOLID DEPOSITION ON INTERNAL STRUCTURES OF REACTORS
A reactor system for high temperature reactions of reactants includes at least one reactant containing carbon. The reactor includes a reactor, a liquid media disposed within the reactor, and a solid carbon reaction product. The liquid media does not react irreversibly with the reactant to form products, and the liquid media wets at least a portion of a surface within the reactor. The solid carbon reaction product does not contact at least the portion of the surface within the reactor where the liquid media wets the portion of the surface within the reactor.
1 .- 9 . (canceled)
10 . A bubble column reactor system comprising:
a reactor vessel;
a liquid media disposed within the reactor vessel;
an inlet disposed in a lower portion of the reactor, wherein the inlet is configured to introduce a feed gas comprising a reactant as bubbles within the liquid media, wherein the reactant comprising a compounds having carbon; and
a material disposed on at least a portion of a surface within the reactor vessel, wherein the material and the liquid media are selected so that the liquid media wets the material, wherein the material is an oxide or a carbide.
11 . The bubble column reactor system of claim 10 , further comprising:
a draft tube disposed within the reactor vessel, wherein the inlet is configured to introduce the feed gas as bubbles within an interior of the draft tube.
12 . The bubble column reactor system of claim 10 , further comprising:
a packing material disposed within the reactor vessel, wherein the inlet is configured to introduce the feed gas as bubbles passing through the packing.
13 . The bubble column reactor system of claim 12 , wherein at least the portion of the surface within the reactor vessel is formed on the packing material, and wherein the packing material comprises at least one of a tube, a sphere, a saddle, a ring, or a perforated plate.
14 . The bubble column reactor system of claim 10 , wherein at least the portion of the surface within the reactor vessel comprises a porous surface, and wherein the porous surface comprises a mesh, a woven material, a filament based material, a screen, a perforated plate, or a combination thereof.
15 . The bubble column reactor system of claim 10 , wherein the liquid media comprises a molten metal comprising Ag, Au, Sb, Sn, Bi, Ni, Cu, Fe, Pt, In, Pb, Pd, Co, Te, Rh and/or Ga, oxides thereof, and any mixture thereof.
16 . The bubble column reactor system of claim 10 , wherein the liquid media comprises a molten salt comprising one or more oxidized atoms (M) +m and corresponding reduced atoms (X) −1 , wherein M is at least one of K, Na, Mg, Ca, Mn, Zn, Fe, La, or Li, and wherein X is at least one of F, Cl, Br, I, OH, SO 3 , or NO 3 .
17 . (canceled)
18 . The bubble column reactor system of claim 10 , wherein the material comprises: a ceramic, Al 2 O 3 , SiO 2 , ZrO 3 , MgO, a metal, Ni, Fe, Co, molybdenum, silicon, niobium, tantalum, tungsten, rhenium, or graphite, oxides thereof, carbides thereof, or any combination thereof.
19 . The bubble column reactor system of claim 3 or 4 , whereby the reactor system is filled with a molten salt, molten metal, or a combination thereof comprising Na(I,Br,Cl,F), K(I,Br,Cl,F), Li(I,Br,Cl,F), Ag, Au, Sb, Sn, Bi, Ni, Cu, Fe, Ga, Pb, In, wherein the material comprises molybdenum, niobium, tantalum, tungsten, zirconium, aluminum, graphite, silicon, rhenium, thereof oxides, carbides thereof, or combinations thereof.
20 . A reaction process comprising:
contacting a reactant with a liquid reaction media in the presence of a solid surface, wherein the solid surface comprises an oxide or a carbide,
forming a solid reaction product based on the contacting;
wetting the solid surface with the liquid reaction media; and
preventing a formation of the solid reaction product on the solid surface based on wetting the solid surface with the liquid reaction media.
21 . The process of claim 20 , wherein the solid surface comprises a non-porous surface.
22 . The process of claim 20 , wherein the solid surface comprises a porous surface.
23 . The process of claim 22 , wherein the porous surface comprises a mesh, a woven material, a filament based material, a screen, a perforated plate, or a combination thereof.
24 . The process of claim 20 , wherein the reactant comprises a gas phase reactant, and wherein contacting the reactant with the liquid reaction media comprises guiding the gas phase reactant with the porous surface.
25 . The process of claim 20 , wherein the liquid reaction media comprises a molten metal comprising Ag, Au, Sb, Sn, Bi, Ni, Cu, Fe, Pt, In, Pb, Pd, Co, Te, Rh and/or Ga, oxides thereof, and any mixture thereof.
26 . The process of claim 20 , wherein the liquid reaction media comprises a molten salt comprising one or more oxidized atoms (M) +m and corresponding reduced atoms (X) −1 , wherein M is at least one of K, Na, Mg, Ca, Mn, Zn, Fe, La, or Li, and wherein X is at least one of F, Cl, Br, I, OH, SO 3 , or NO 3 .
27 . The process of claim 20 , wherein the solid surface is formed on at least one of a tube, a sphere, a saddle, a ring, a perforated plate, or an internal surface of a reactor vessel.
28 . The process of claim 10 , wherein forming the solid reaction product comprises maintaining the liquid reaction media in a molten state at a temperature above about 400° C. and below about 1500° C.
29 . The process of claim 20 , wherein the solid surface is prepared for wetting by chemical modification through a specific pre-treatment or exposure to a material present in the liquid, and wherein the pre-treatment comprises forming the oxide, the carbide, or other surface layer on the solid surface to improve wetting over the solid surface material.
30 . (canceled)
31 . The process of claim 20 , wherein the reactant comprises a gas, where the process further comprises:
introducing the reactant into the liquid reaction media to form bubbles;
guiding the bubbles within the liquid reaction media using a draft tube disposed within a reactor vessel, wherein the solid surface comprises at least a portion of the draft tube.
32 . The process of claim 31 , wherein the solid surface comprises ceramic, Al 2 O 3 , SiO 2 , ZrO 3 , MgO, a metal, Ni, Fe, Co, molybdenum, silicon, niobium, tantalum, tungsten, rhenium, or graphite, oxides thereof, carbides thereof, or any combination thereof.