SYSTEMS AND METHODS FOR SEPARATING GASES
The invention pertains to processes for separating water from air. The processes may employ using an LCST solution with or without subsequent reverse osmosis, nanofiltration, or ultrafiltration.
1 . A process comprising:
absorbing CO 2 into a first aqueous solution comprising a CO 2 -lean diammonium phosphate to form a second solution comprising a CO 2 -rich diammonium phosphate; and
adding at least a portion of an acidic ammonium salt to the second solution comprising a CO 2 -rich diammonium phosphate to form a third solution comprising CO 2 -rich diammonium phosphate and an acidic ammonium salt; and
desorbing at least a portion of CO 2 from the third solution comprising CO 2 -rich diammonium phosphate and the acidic ammonium salt to form a fourth solution comprising CO 2 -lean diammonium phosphate and the acidic ammonium salt; and
removing at least a portion of the acidic ammonium salt from the fourth solution comprising CO 2 -lean diammonium phosphate and the acidic ammonium salt to form a solution comprising CO 2 -lean diammonium phosphate.
2 . The process of claim 1 which further comprises employing the formed solution comprising CO 2 -lean diammonium phosphate in the absorbing step.
3 . The process of claim 1 wherein the acidic ammonium salt is selected from the group consisting of ammonium nitrate, or ammonium sulfate, or ammonium chloride, or a weak base-strong acid, or a cation-hydrogen or dihydrogen-anion or trihydrogen-anion salt, or an alkali hydrogen sulfate salt, or an ammonium-strong acid salt, or a common-ion salt, or any combination thereof.
4 . The process of claim 1 wherein said removing of at least a portion of the acidic ammonium salt comprises cooling precipitation.
5 . The process of claim 1 wherein said removing comprises nanofiltering.
6 . A process comprising:
absorbing an acid gas into a first aqueous solution comprising an acid gas—lean basic ammonium salt to form a second solution comprising an acid gas—rich basic ammonium salt; and
adding at least a portion of an acidic ammonium salt to the second solution to form a third solution comprising an acid gas-rich basic ammonium salt and acidic ammonium salt; and
desorbing at least a portion of an acid gas from the third solution to form a fourth solution comprising an acid gas-lean basic ammonium salt and an acidic ammonium salt; and
removing at least a portion of the acidic ammonium salt from the fourth solution to form a solution comprising an acid gas-lean basic ammonium salt.
7 . The process of claim 6 which further comprises employing the formed solution comprising an acid gas-lean basic ammonium salt in the absorbing step.
8 . The process of claim 6 wherein the acidic ammonium salt is selected from the group consisting of ammonium nitrate, or ammonium sulfate, or ammonium chloride, or a weak base-strong acid, or a cation-hydrogen or dihydrogen-anion or trihydrogen-anion salt, or an alkali hydrogen sulfate salt, or an ammonium-strong acid salt, or a common-ion salt, or any combination thereof.
9 . The process of claim 6 wherein the basic ammonium salt is selected from the group consisting of diammonium phosphate, or ammonium—phosphate, or ammonium carbonate, or ammonium bicarbonate, or any combination thereof.
10 . The process of claim 6 wherein said acid gas is selected from the group consisting of CO 2 , or H 2 S, or SO 2 , or HCN, or HF, or NO 2 , or any combination thereof.
11 . The process of claim 6 wherein said removing comprises cooled precipitating.
12 . The process of claim 6 wherein said removing comprises nanofiltering.
13 . The process of claim 6 wherein said desorbing is facilitated by a change in pressure.
14 . The process of claim 6 wherein said desorbing is facilitated by an increase in temperature.
15 . The process of claim 6 wherein said desorbing is facilitated by a decrease in pH, or an increase in concentration of the acidic ammonium salt, or a decrease in solubility of acid gas, or any combination thereof.
16 . A process comprising:
absorbing an acid gas into a first solution comprising an acid gas-lean diammonium phosphate to form a second solution comprising an acid gas-rich diammonium phosphate; and
desorbing at least a portion of an acid gas from the second solution comprising an acid gas-rich diammonium phosphate to form a solution comprising an acid gas-lean diammonium phosphate.
17 . The process of claim 16 which further comprises employing the formed solution comprising an acid gas-lean diammonium phosphate in the absorbing step.
18 . The process of claim 16 wherein said acid gas is selected from the group consisting of CO 2 , or H 2 S, or SO 2 , or HCN, or HF, or NO 2 , or any combination thereof.
19 . A process comprising:
absorbing an acid gas into a first solution comprising an acid gas-lean alkali phosphate to form a second solution comprising an acid gas-rich alkali phosphate; and
desorbing at least a portion of an acid gas from the second solution to form a solution comprising an acid gas-lean alkali phosphate.
20 . The process of claim 19 which further comprises employing the formed solution comprising an acid gas-lean alkali phosphate in the absorbing step.
21 . The process of claim 19 wherein the alkali in the alkali phosphate is selected from the group consisting of lithium, or sodium, or potassium, or rubidium, or caesium, or any combination thereof.
22 . The process of claim 19 wherein said acid gas is selected from the group consisting of CO 2 , or H 2 S, or SO 2 , or HCN, or HF, or NO 2 , or any combination thereof.