Cellulosic gels, films and composites including the gels, and methods of forming same
Disclosed are cellulose-based flexible aerogels and xerogels containing bacterial cellulose nanorods, ribbons, fibers, and the like, wherein the gels have tunable optical, heat transfer, and stiffness properties. Further disclosed are highly transparent and flexible cellulose nanofiber-polysiloxane composite aerogels featuring enhanced mechanical robustness, tunable optical anisotropy, and low thermal conductivity.
1. A transparent and flexible cellulose nanofiber-polysiloxane composite aerogel comprising:
cellulose nanofibers having a diameter between about 4 and about 10 nm,
wherein the transparent and flexible cellulose nanofiber-polysiloxane composite aerogel is formed using a polysiloxane precursor and a surface modifying agent comprising a compound comprising an amine functional group,
wherein the cellulose nanofibers are crosslinked via a polysiloxane network comprising a siloxane bond derived from the polysiloxane precursor, and
wherein the flexible cellulose nanofiber-polysiloxane composite aerogel is rollable and foldable.
2. The composite aerogel of claim 1 having a thickness from about 1 μm to about 10 cm.
3. The composite aerogel of claim 1 having an electromagnetic transmission of from about 25% to about 100% for light wavelengths between about 400 nm and about 700 nm.
4. The composite aerogel of claim 1 having a thermal conductivity of from about 10 −3 W/(m·K) to about 10 W/(m·K).
5. The composite aerogel of claim 1 , wherein the cellulose nanofibers are derived from bacterial cellulose.
6. The composite aerogel of claim 1 , wherein the cellulose nanofibers are functionalized with siloxane pendants derived from the surface modifying agent.
7. A film comprising the composite aerogel of claim 1 .