Electrode for membrane-electrode assembly and method of manufacturing same
View Patent ↗Disclosed are an electrode including a porous substrate, a membrane-electrode assembly for a fuel cell including the same and a method of manufacturing the same. In the method of manufacturing the membrane-electrode assembly, the amount of a catalyst that is loaded depending on the position is applied in a gradational manner, thus efficiently using the catalyst, thereby reducing costs owing to the use of a decreased amount of the metal catalyst. Further, the membrane-electrode assembly includes the electrode including a porous substrate, thus making it easy to select hot-pressing conditions and increasing processing efficiency. The porous substrate is hydrophobic and the pore size in the electrode is not decreased compared to conventional electrodes, thus reducing flooding and generating various operation regions. The electrode including the porous substrate can minimize electrode loss, thus improving electrode durability.
1 . A method of manufacturing an electrode for a membrane-electrode assembly, comprising:
preparing a porous substrate;
forming the porous substrate comprising a first region and a second region having different thicknesses when viewed in a cross-section in a thickness direction by pressing the porous substrate using a press die; and
incorporating an electrode slurry on the porous substrate,
wherein the porous substrate comprises one or more selected from the group consisting of polytetrafluoroethylene (PTFE), ethylene/tetrafluoroethylene (ETFE), tetrafluoroethylene-hexafluoropropylene copolymer (FEP), tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer PFA), polyimide, polyester, and polyethylene terephthalate (PET),
wherein the electrode slurry comprises a metal catalyst,
wherein a thickness of the first region is greater than a thickness of the second region,
wherein one surface of the porous substrate after the forming is flat and an opposite surface of the porous substrate after the forming is irregular depending on a shape of the first region and the second region,
wherein the thickness of the first region is 5 to 10 μum and the thickness of the second region is 2 to 5 μm, and
wherein, in incorporating the electrode slurry, a loaded amount (mg/cm 2 ) of the metal catalyst is applied in a gradational manner over the thickness of the first region.
2 . The method of claim 1 , wherein a connecting portion connects the first region and the second region at a right angle or obliquely.
3 . The method of claim 1 , wherein the press die comprises a protrusion having a shape complementary to a shape of the first region and the second region.
4 . The method of claim 1 , wherein in incorporating the electrode slurry, the loaded amount of the metal catalyst that is loaded in the electrode slurry incorporated into the first region is 0.5 to 1.0 mg/cm 2 , and the loaded amount of the metal catalyst that is loaded in the electrode slurry incorporated into the second region is 0.05 to 0.5 mg/cm 2 .