Basalt fiber for adsorbing toxic material
Basalt selectively adsorbs organic toxic materials, such as dioxins, furans, polychlorinated biphenyls (PCBs), bis(2-ethylhexyl)phthalate, arsenic, mercury, chromium, copper, nickel, zinc, cadmium, lead, and the like, from substances such as sediment, which contains water and the toxic materials.
1. A method for adsorbing toxic materials, the method comprising:
exposing a fluid to a filter for a first minimum duration, wherein the fluid comprises water and a toxic material comprising at least one of arsenic, mercury, chromium, copper, nickel, zinc, cadmium, or lead, and wherein the filter comprises a needlepunch mat comprising basalt fibers and having a thickness selected from about 6.5 mm, about 13 mm, or about 20 mm; and
adsorbing at least a portion of the toxic material by the basalt fibers.
2. The method of claim 1 , further comprising:
exposing the needlepunch mat to a NaOH aqueous solution having 10% NaOH before exposing the fluid to the filter.
3. The method of claim 2 , wherein exposing the needlepunch mat to the NaOH aqueous solution further comprises:
exposing the needlepunch mat to the NaOH aqueous solution under agitation.
4. The method of claim 2 , further comprising:
rinsing the needlepunch mat in deionized water to remove the NaOH aqueous solution after exposing the needlepunch mat to the NaOH aqueous solution; and
after rinsing the needlepunch mat, drying the needlepunch mat.
5. The method of claim 4 , wherein drying the needlepunch mat further comprises:
drying the needlepunch mat using forced air.
6. The method of claim 1 , wherein the toxic material comprises a sediment.
7. The method of claim 1 , wherein the toxic material further comprises at least one of a dioxin, a furan, a polychlorinated biphenyl (PCB), or an ethylhexylphthalate.
8. The method of claim 7 , wherein the ethylhexylphthalate is bis(2-ethylhexyl) phthalate.
9. The method of claim 1 , wherein exposing the the fluid to the filter further comprises at least one of:
spraying the needlepunch mat with the fluid;
exposing the needlepunch mat to the fluid in a counter flow direction; or
exposing the needlepunch mat to the fluid in a flow direction.
10. The method of claim 1 , wherein adsorbing at least a portion of the toxic material by the basalt fibers further comprises:
adsorbing a weight-to-weight ratio of the needlepunch mat to the toxic material of 200:1 to 1:3.
11. The method of claim 1 , wherein the first minimum duration is from three days to seven days.
12. The method of claim 1 , wherein the at least the portion of the toxic material adsorbed by the basalt fibers is at least 25% by weight of the toxic material in the fluid.
13. The method of claim 12 , wherein the at least the portion of the toxic material adsorbed by the basalt fibers is selectively adsorbed in the presence of a water-soluble material.
14. A method for adsorbing toxic materials, the method comprising:
chemically exposing a fluid mixture comprising an aqueous sediment to a filter comprising a needlepunch mat comprising basalt fibers, wherein the fluid mixture comprises a toxic material including at least one of arsenic, mercury, chromium, copper, nickel, zinc, cadmium, or lead; and
adsorbing at least a portion of the toxic material using the basalt fibers while the fluid mixture is exposed to the filter for a first minimum duration, wherein the needlepunch mat has a thickness selected from about 6.5 mm, about 13 mm, or about 20 mm.
15. The method of claim 14 , comprising:
treating the basalt fibers with a NaOH aqueous solution having 10% NaOH before chemically exposing the fluid mixture to the filter.
16. The method of claim 15 , wherein treating the basalt fibers with the NaOH aqueous solution further comprises:
treating the basalt fibers with the NaOH aqueous solution under agitation.
17. The method of claim 16 , further comprising:
after treating the basalt fibers to the NaOH aqueous solution, rinsing the needlepunch mat in deionized water to remove the NaOH aqueous solution from the needlepunch mat; and
after rinsing the needlepunch mat, drying the needlepunch mat.
18. The method of claim 17 , wherein drying the needlepunch mat further comprises:
drying the needlepunch mat in a forced air oven.
19. The method of claim 14 , wherein the toxic material further comprises at least one of a dioxin, a furan, a polychlorinated biphenyl (PCB), or an ethylhexylphthalate.
20. The method of claim 14 , wherein chemically exposing the fluid mixture to the filter further comprises at least one of:
spraying the needlepunch mat with the fluid mixture;
exposing the needlepunch mat to the fluid mixture in a counter-flow direction; or
exposing the needlepunch mat to the fluid mixture in a flow direction.
21. The method of claim 14 , wherein adsorbing at least a portion of the toxic material using the basalt fibers further comprises:
adsorbing a weight-to-weight ratio of the basalt fibers to the toxic material of 200:1 to 1:3, wherein the first minimum duration is from at least 24 hours to at least 7 days.
22. The method of claim 14 , wherein adsorbing at least a portion of the toxic material using the basalt fibers further comprises:
adsorbing at least 25% weight of the toxic material in the fluid mixture.
23. The method of claim 14 , wherein the fluid mixture further comprises a water-soluble material, and wherein the basalt fibers selectively adsorb the toxic material in presence of the water-soluble material.
24. A method for adsorbing toxic materials, the method comprising:
exposing an aqueous fluid to a filter, wherein the aqueous fluid comprises a toxic material including at least one of a dioxin, a furan, a polychlorinated biphenyl (PCB), an ethylhexylphthalate, arsenic, mercury, chromium, copper, nickel, zinc, cadmium, or lead;
wherein the filter comprises a needlepunch mat consisting of basalt fibers and having a thickness selected from about 6.5 mm, about 13 mm, or about 20 mm; and
after exposing the aqueous fluid to the filter, adsorbing at least a portion of the toxic material by the basalt fibers.