PYROLYSIS GAS TREATMENT USING ABSORBER-STRIPPER SYSTEM
Processes and facilities for recovering and purifying a pyrolysis gas formed by pyrolyzing waste plastic are provided. An absorber-stripper system may be used to treat the pyrolysis gas for use in one or more downstream chemical recycling processes, which can be used in forming a variety of recycled content products.
1 . A process for purifying pyrolysis gas (pygas), the process comprising:
(a) pyrolyzing waste plastic to thereby produce a pyrolysis effluent stream;
(b) separating at least a portion of the pyrolysis effluent stream to produce a pygas stream and a pyrolysis oil (pyoil) stream; and
(c) treating at least a portion of the pygas stream in an absorber-stripper system to produce a purified pygas stream.
2 . The process of claim 1 , wherein the absorber-stripper system comprises one or more absorber towers and one or more regeneration towers.
3 . The process of claim 2 , wherein the treating (c) comprises introducing the pygas stream to the one or more absorber towers and contacting the pygas with an absorber solvent.
4 . The process of claim 3 , wherein the absorber solvent comprises a component selected from the group consisting of amines, methanol, sodium hydroxide, sodium carbonate/bicarbonate, potassium hydroxide, potassium carbonate/bicarbonate, SELEXOL®, glycol ether, and combinations thereof.
5 . The process of claim 4 , wherein the absorber solvent comprises an amine selected from the group consisting of diethanolamine (DEA), monoethanolamine (MEA), methyldiethanolamine (MDEA), diisopropanolamine (DIPA), diglycolamine (DGA), piperazine, modifications, derivatives, and combinations thereof.
6 . The process of claim 3 , wherein the one or more regeneration towers comprise at least one reboiler operating at a temperature high enough to release the CO 2 from the absorber solvent and below the degradation temperature of the absorber solvent.
7 . The process of claim 6 , wherein the stripper column reboiler operates at a temperature of 105° C. to 130° C.
8 . The process of claim 1 , further comprising cooling the pyrolysis effluent stream to a temperature not more than 60° C. before the separating (b).
9 . The process of claim 1 , wherein after the treating (c), the purified pygas stream has a temperature of 1° to 40° greater than the temperature of the pygas stream before the treating (c).
10 . A chemical recycling process, the process comprising:
(a) pyrolyzing waste plastic to produce a recycled content pyrolysis gas (r-pygas) stream, wherein the r-pygas stream comprises a quantity of carbon dioxide (CO 2 );
(b) treating at least a portion of the r-pygas stream in an absorber-stripper system to remove at least a portion of the quantity of CO 2 from the r-pygas stream, thereby producing a CO 2 -depleted r-pygas stream; and
(c) introducing at least a portion of the CO 2 -depleted r-pygas stream into a separation process to thereby produce one or more recycled content chemical product(s) and co-product(s).
11 . The process of claim 10 , wherein the CO 2 -depleted r-pygas stream comprises not more than 1000 ppm CO 2 .
12 . The process of claim 10 , wherein the CO 2 -depleted r-pygas stream is depleted in sulfur and/or sulfur-containing compounds.
13 . The process of claim 10 , wherein the waste plastic comprises not more than 10 percent by weight polyesters.
14 . The process of claim 10 , wherein the waste plastic comprises at least 80 percent by weight polyolefins.
15 . The process of claim 10 , wherein the recycled content chemical product(s) and co-product(s) comprise one or more olefins, alkanes, aromatics, hydrogen (H 2 ), paraffins, gasoline, and/or C5+ hydrocarbons.
16 . The process of claim 10 , wherein the recycled content chemical product(s) and co-product(s) comprise r-ethylene, r-propylene, r-butylene, r-benzene, r-toluene, r-xylenes, and/or r-styrene.
17 . A process for recovering heat from a pyrolysis effluent stream, the process comprising:
(a) pyrolyzing waste plastic to thereby produce the pyrolysis effluent stream;
(b) cooling and at least partially condensing at least a portion of the pyrolysis effluent stream via indirect heat exchange with:
(i) a heat transfer medium (HTM), thereby warming the HTM; and/or
(ii) a stripper column reboiler;
(c) feeding at least a portion of the cooled and at least partially condensed pyrolysis effluent stream to a separator to thereby produce a pyrolysis gas (pygas) stream and a pyrolysis oil (pyoil) stream;
(d) treating at least a portion of the pygas stream in an absorber-stripper system to thereby produce a purified pygas stream; and
(e) optionally, using at least a portion of the warmed HTM to provide heating to one or more of:
(i) a rich solvent stream within the absorber-stripper system;
(ii) a liquefication process; and/or
(iii) a pyrolysis feedstock preheating process.
18 . The process of claim 17 , wherein the pyrolysis effluent stream has a temperature of 500° C. to 800° C. after the pyrolyzing (a).
19 . The process of claim 17 , wherein the heat transfer medium (HTM) comprises water/steam, oils, siloxanes, molten metal, molten salt, and/or combinations thereof.
20 . The process of claim 19 , wherein the HTM comprises an oil selected from the group consisting of synthetic oil, refined oil, or a combination thereof.