Film extrusion composition and associated extruded film, metallized film, and capacitor
A film extrusion composition includes specific amounts of a heat-resistant copolycarbonate, a slip agent, and a particulate crosslinked polymethylsilsesquioxane having particles of a specific size. An extruded film prepared from the film extrusion composition exhibits a beneficial balance of telescoping, blocking, and dielectric properties. The extruded film is useful for forming electrostatic film capacitors.
1 . A film extrusion composition comprising, based on the total weight of the film extrusion composition:
50 to 99.35 weight percent of a copolycarbonate comprising, based on 100 mole percent total carbonate units in the copolycarbonate,
20 to 60 mole percent of first carbonate units having the structure
wherein R 1 is a C 6 -C 16 divalent aromatic group;
40 to 80 mole percent of second carbonate units having the structure
wherein R 2 is a C 17 -C 40 divalent aromatic group having the structure
wherein R f and R g are each independently at each occurrence C 1 -C 12 alkyl, C 1 -C 12 alkoxyl, or C 2 -C 12 alkenyl; each R h is hydrogen or two occurrence of R h combine with the carbon atom to which they are attached to form a carbonyl group; each occurrence of R i is independently C 1 -C 6 alkyl; R j is hydrogen, C 1 -C 6 alkyl, or phenyl optionally substituted with 1, 2, 3, 4, or 5 C 1 -C 6 alkyl groups; R k is independently at each occurrence C 1 -C 3 alkyl or phenyl, preferably methyl; X b is C 6 -C 12 arylene, C 4 -C 18 cycloalkylene, C 4 -C 18 cycloalkylidene, or —C(R m )(R n )— wherein R m is hydrogen, C 1 -C 12 alkyl, or C 6 -C 12 aryl, and R n is C 6 -C 10 alkyl, C 6 -C 8 cycloalkyl, or C 6 -C 12 aryl, or X b is -(Q a ) x -G-(Q b ) y -, wherein Q a and Q b are each independently C 1 -C 3 alkylene, G is C 3 -C 10 cycloalkylene, x is zero or 1, and y is zero or 1; and j, m, and n are each independently zero, 1, 2, 3, or 4; and
0 mole percent of third carbonate units, each third carbonate unit comprising a divalent carbonate group and a divalent polysiloxane group, the divalent polysiloxane group comprising 5 to 60 diorganosiloxane units having the structure
wherein each occurrence of R 3 is independently a C 1 -C 13 hydrocarbyl group;
0.1 to 6 weight percent of a slip agent selected from the group consisting of pentaerythritol tetrastearate, dipentaerythritol hexastearate, glycerol tristearate, high density polyethylenes, polymethylpentenes, poly(carbonate-siloxane) s, and combinations thereof; and
0.55 to 0.8 weight percent of a particulate crosslinked polymethylsilsesquioxane having a number-based mean equivalent spherical diameter of 0.5 to 4 micrometers determined by electrical sensing zone method according to ISO 13319-1:2021.
2 . The film extrusion composition of claim 1 , wherein a ratio, t p 60/(total number of particles), is 0.1 to 0.5 percent, wherein t p 60 is the load/length ratio at 60 percent, expressed in units of percent, calculated according to JIS B0601 (1994) using the formula
t
p
6
0
=
(
(
L
1
+
L
2
+
L
3
+
…
L
n
)
/
L
)
×
100
wherein (L 1 +L 2 +L 3 + . . . L n ) is the sum of cut portion lengths measured along a measurement length, L, at a cut line level of 60% of the separation between the highest peak height (corresponding to 0%) and the lowest trough bottom (corresponding to 100%); and wherein the total number of particles is the number of the crosslinked polymethylsilsesquioxane particles in one nanogram of extruded film, calculated from the weight of crosslinked polymethylsilsesquioxane particles in one nanogram of film extrusion composition, the density of the particles, and the number-based mean equivalent spherical diameter of the particles.
3 . The film extrusion composition of claim 1 , wherein the particulate crosslinked polymethylsilsesquioxane comprises, based on the total weight of the film extrusion composition, 0.55 to 0.7 weight percent of particles having a number-based mean equivalent spherical diameter of 1.5 to 2.5 micrometers.
4 . The film extrusion composition of claim 1 , wherein the particulate crosslinked polymethylsilsesquioxane comprises, based on the total weight of the film extrusion composition, 0.2 to 0.6 weight percent of first particles having a number-based mean equivalent spherical diameter of 0.5 to 1 micrometers, and 0.2 to 0.6 weight percent of second particles having a number-based mean equivalent spherical diameter of 1.5 to 3 micrometers.
5 . The film extrusion composition of claim 1 , wherein the particulate crosslinked polymethylsilsesquioxane comprises, based on the total weight of the film extrusion composition, 0.2 to 0.6 weight percent of first particles having a number-based mean equivalent spherical diameter of 1.5 to 2.4 micrometers, and 0.2 to 0.6 weight percent of second particles having a number-based mean equivalent spherical diameter of 2.5 to 4 micrometers.
6 . The film extrusion composition of claim 1 , wherein the slip agent is selected from the group consisting of
pentaerythritol tetrastearate;
a poly(carbonate-siloxane) block copolymer comprising, based on the weight of the poly(carbonate-siloxane) block copolymer, 70 to 90 weight percent of bisphenol A carbonate units and 10 to 30 weight percent of dimethylsiloxane units, based on the weight of the poly(carbonate-siloxane) block copolymer; and
a combination of pentaerythritol tetrastearate and the poly(carbonate-siloxane) block copolymer.
7 . The film extrusion composition of claim 1 ,
wherein the film extrusion composition comprises
90 to 99.25 weight percent of the copolycarbonate,
0.2 to 5 weight percent of the slip agent, and
0.55 to 0.7 weight percent of the particulate crosslinked polymethylsilsesquioxane; and
wherein the copolycarbonate comprises
50 to 75 mole percent of 3,3,5-trimethylcyclohexanonebisphenol carbonate units, and
25 to 50 mole percent of bisphenol A carbonate units.
8 . The film extrusion composition of claim 7 , wherein the particulate crosslinked polymethylsilsesquioxane comprises, based on the total weight of the film extrusion composition, 0.55 to 0.7 weight percent of particles having a number-based mean equivalent spherical diameter of 1.5 to 2.5 micrometers.
9 . An extruded film comprising the film extrusion composition of claim 1 .
10 . The extruded film of claim 9 ,
wherein the film extrusion composition comprises
90 to 99.25 weight percent of the copolycarbonate,
0.2 to 5 weight percent of the slip agent, and
0.55 to 0.7 weight percent of the particulate crosslinked polymethylsilsesquioxane; and
wherein the copolycarbonate comprises
50 to 75 mole percent of 3,3,5-trimethylcyclohexanonebisphenol carbonate units, and
25 to 50 mole percent of bisphenol A carbonate units.
11 . The extruded film of claim 10 , wherein the particulate crosslinked polymethylsilsesquioxane comprises, based on the total weight of the film extrusion composition, 0.55 to 0.7 weight percent of particles having a number-based mean equivalent spherical diameter of 1.5 to 2.5 micrometers.
12 . A capacitor comprising:
an extruded film comprising the film extrusion composition of claim 1 ; and
an electrically conductive metal layer in contact with the extruded film.
13 . The capacitor of claim 12 ,
wherein the film extrusion composition comprises
90 to 99.25 weight percent of the copolycarbonate,
0.2 to 5 weight percent of the slip agent, and
0.55 to 0.7 weight percent of the particulate crosslinked polymethylsilsesquioxane; and
wherein the copolycarbonate comprises
50 to 75 mole percent of 3,3,5-trimethylcyclohexanonebisphenol carbonate units, and
25 to 50 mole percent of bisphenol A carbonate units.
14 . The capacitor of claim 13 , wherein the particulate crosslinked polymethylsilsesquioxane comprises, based on the total weight of the film extrusion composition, 0.55 to 0.7 weight percent of particles having a number-based mean equivalent spherical diameter of 1.5 to 2.5 micrometers.
15 . A metallized film comprising:
an extruded film comprising the film extrusion composition of claim 1 ; and
an electrically conductive metal layer in contact with the extruded film.