Foamed Isocyanate-Based Polymer
There is described a foamed isocyanate-based polymer derived from a reaction mixture comprising: an isocyanate; a polyol composition comprising a first prescribed amount of polymer particles dispersed in a base polyol; a second prescribed amount of biomass-based carbonaceous particulate material; and a blowing agent. In one embodiement, the foamed isocyanate-based polymer having an Indentation Force Deflection when measured pursuant to ASTM D3574-11 which is within about 15% as that of a reference foam produced by omitting the biomass-based carbonaceous particulate material from the reaction mixture and increasing the amount of polymer particles in the polymer polyol composition to equal the sum of the first prescribed amount and the second prescribed amount. In another embodiment, the foamed polymer has a cellular matrix comprising a plurality of interconnected struts, the biomass-based carbonaceous particulate material conferring to the cellular matrix a load efficiency of at least about 5 Newtons/weight % of biomass-based carbonaceous particulate material. A process to produce the foamed isocyanate-based polymer is also described. A polyol-based dispersion to produce the foamed isocyanate-based polymer is also described. It has been discovered that a relatively expensive petroleum-based copolymer polyol can be fully substituted by a relative inexpensive bio-based (amorphous carbon) dispersion with no significant compromise in important physical properties in the resulting polyurethane foam.
1 . A foamed isocyanate-based polymer derived from a reaction mixture comprising:
an isocyanate;
a polyol composition comprising a first prescribed amount of polymer particles dispersed in a base polyol;
a second prescribed amount of biomass-based carbonaceous particulate material having an organic carbon content in the range of from about 85% to about 98% when measured by dry combustion using ASTM D4373; and
a blowing agent;
the foamed isocyanate-based polymer having an Indentation Force Deflection when measured pursuant to ASTM D3574-11 which is within about 15% as that of a reference foam produced by omitting the biomass-based carbonaceous particulate material from the reaction mixture and increasing the amount of polymer particles in the polymer polyol composition to equal the sum of the first prescribed amount and the second prescribed amount.
2 . The foamed isocyanate-based polymer defined in claim 1 , wherein the biomass-based carbonaceous particulate material has a D50 particle size in the range of from about 0.2 μm to about 6 μm.
3 . The foamed isocyanate-based polymer defined in claim 1 , wherein the biomass-based carbonaceous particulate material comprises hydrogen to carbon molar ratio in the range of from about 0.10 to about 0.85 when measured by dry combustion using ASTM D4373.
4 . The foamed isocyanate-based polymer defined in claim 1 , wherein the biomass-based carbonaceous particulate material has a surface area of from about 10 to about 4000 m2/g when measured by a BET method.
5 . The foamed isocyanate-based polymer defined in claim 1 , wherein the biomass-based carbonaceous particulate material has a percentage of modern carbon (pMC) greater than about 85% when measured pursuant to ASTM D6866.
6 . The foamed isocyanate-based polymer defined in claim 1 , wherein the biomass-based carbonaceous particulate material is selected from the group consisting of coniferous and deciduous wood, nut shells, bamboo, rice hulls, grasses, corn stover, plant matter, seeds, paper, cardboard, manure, other agricultural residues, biorefinery residues, sorghum, dried algae, coffee beans, coffee grounds, grounds, sugar cane bagasse and any mixture of two or more of these.
7 . The foamed isocyanate-based polymer defined in claim 1 , wherein the biomass-based carbonaceous particulate material has a D50 particle size in the range of from about 0.5 μm to about 6 μm.
8 . The foamed isocyanate-based polymer defined in claim 1 , wherein the foamed isocyanate based polymer is molded.
9 . A foamed isocyanate-based polymer derived from:
an isocyanate; and
a polyol composition optionally comprising polymer particles dispersed in a base polyol;
a biomass-based carbonaceous particulate material having an organic carbon content in the range of from about 85% to about 98% when measured by dry combustion using ASTM D4373;
the foamed polymer having a cellular matrix comprising a plurality of interconnected struts, the biomass-based carbonaceous particulate material conferring to the cellular matrix a load efficiency of at least about 5 Newtons/weight % of biomass-based carbonaceous particulate material.
10 . The foamed isocyanate-based polymer defined in claim 9 , wherein the first prescribed amount is zero such that the base polyol composition is the base polyol.
11 . The foamed isocyanate-based polymer defined in claim 9 , wherein the biomass-based carbonaceous particulate material has a D50 particle size in the range of from about 0.2 μm to about 6 μm.
12 . The foamed isocyanate-based polymer defined in claim 1 , wherein the foamed isocyanate-based polymer has an Indentation Force Deflection when measured pursuant to ASTM D3574-11 which is within about 15% as that of a reference foam produced by substituting an amount polymer particles in the base polyol that is equal to the amount of the biomass-based carbonaceous particulate material in the reaction mixture.
13 . The foamed isocyanate-based polymer defined in claim 9 , wherein the biomass-based carbonaceous particulate material comprises hydrogen to carbon molar ratio in the range of from about 0.10 to about 0.85 when measured by dry combustion using ASTM D4373.
14 . The foamed isocyanate-based polymer defined in claim 9 , wherein the biomass-based carbonaceous particulate material has a surface area of from about 10 to about 4000 m2/g when measured by a BET method.
15 . The foamed isocyanate-based polymer defined in claim 9 , wherein the biomass-based carbonaceous particulate material has a percentage of modern carbon (pMC) greater than about 85% when measured pursuant to ASTM D6866.
16 . The foamed isocyanate-based polymer defined in claim 9 , wherein the biomass-based carbonaceous particulate material is selected from the group consisting of coniferous and deciduous wood, nut shells, bamboo, rice hulls, grasses, corn stover, plant matter, seeds, paper, cardboard, manure, other agricultural residues, biorefinery residues, sorghum, dried algae, coffee beans, coffee grounds, grounds, sugar cane bagasse and any mixture of two or more of these.
17 . The foamed isocyanate-based polymer defined in claim 9 , wherein the biomass-based carbonaceous particulate material has a D50 particle size in the range of from about 0.5 μm to about 6 μm.
18 . The foamed isocyanate-based polymer defined in claim 9 , wherein the foamed isocyanate based polymer is molded.
19 . A polyol-based dispersion comprsing:
(a) a first prescribed amount of a biomass-based carbonaceous particulate material polymer particles having an organic carbon content in the range of from about 85% to about 98% when measured by dry combustion using ASTM D4373; and
(b) a polyol;
wherein the dispersion optionally comprises a second prescribed amount of polymer particles.
20 . The foamed isocyanate-based polymer defined in claim 19 . wherein the biomass-based carbonaceous particulate material has a D50 particle size in the range of from about 0.2 μm to about 6 μm.