RECOVERY OF CARBON DIOXIDE FROM METHANE COMBUSTION AND ETHYLENE OXIDE PRODUCTION TO PRODUCE RECYCLE CONTENT SYNGAS
It has been discovered that recycle content CO 2 streams produced in a chemical recycling facility involving waste plastic pyrolysis can be converted into recycle content syngas (r-syngas), which can be used for various applications. More particularly, recycle content CO 2 streams generated from a pyrolysis facility, a cracking facility, and/or an ethylene oxide facility may be recovered and converted into r-syngas. Moreover, recycle content methane, produced directly or indirectly from waste plastics, may also be used to produce flue gas streams, which provide additional recycle content CO 2 streams to produce additional recycle content syngas. Thus, methods for producing a useful recycle content product (i.e., r-syngas) from conventional waste streams that are typically exhausted (i.e., CO 2 streams) are provided herein.
1 . A chemical recycling process comprising:
(a) oxidizing at least a portion of a recycle content ethylene in an oxidation reactor to form a recycle content ethylene oxide stream and a recycle content CO 2 stream;
(b) feeding at least a portion of the recycle content CO 2 stream to a POX gasifier; and
(c) gasifying at least a portion of the recycle content CO 2 stream in the POX gasifier to thereby form a recycle content syngas.
2 . The process according to claim 1 , further comprising melting at least a portion of a solid waste plastic in at least one liquification system to form a liquefied waste plastic, pyrolyzing at least a portion of the liquefied waste plastic in at least one pyrolysis reactor to form a pyrolysis effluent comprising a recycle content pyrolysis gas, a recycle content pyrolysis oil, and a recycle content pyrolysis residue, and cracking at least a portion of the recycle content pyrolysis gas, the recycle content pyrolysis oil, and/or the recycle content pyrolysis residue in at least one cracker furnace to form a cracked product comprising a recycle content methane stream and the recycle content ethylene stream.
3 . The process according to claim 2 , further comprising bypassing the cracker furnace and introducing at least a portion of the pyrolysis gas directly into a compression system downstream of the cracker furnace.
4 . The process according to claim 3 , wherein the liquification system, the pyrolysis reactor, and/or the cracker furnace comprise a combustion device comprising one or more burners, further comprising combusting at least a portion of the recycle content methane stream in the combustion device to thereby form a flue gas stream comprising recycle content CO 2 .
5 . The process according to claim 4 , further comprising gasifying at least a portion of the flue gas stream to form additional recycle content syngas.
6 . The process according to claim 1 , further comprising introducing a molecular oxygen stream into the oxidation reactor and in the presence of a heterogeneous catalyst, and a temperature in the range of 200 to 300° C. or 220 to 280° C.
7 . The process according to claim 1 , further comprising separating the recycle content ethylene oxide stream and the recycle content CO 2 stream in a first absorber system comprising at least one absorber column and at least one stripper column, and further comprising, prior to the gasifying of step (c), purifying at least a portion of the recycle content CO 2 stream in a second absorber system comprising at least one absorber column and at least one stripper column.
8 . The process according to claim 1 , wherein the gasifying occurs at:
(i) a temperature of at least 1100° C., and
(ii) a pressure of at least 200 psig.
9 . The process according to claim 1 , wherein at least a portion of the recycle content ethylene and/or the recycle content methane is produced by a cracking process that includes cracking recycle content pyrolysis oil.
10 . The process according to claim 9 , wherein at least a portion of the recycle content pyrolysis oil is produced via pyrolysis of waste plastic.
11 . The process according to claim 1 , wherein at least a portion of the recycle content CO 2 is produced by combusting methane, wherein the methane is produced by cracking recycle content pyrolysis oil.
12 . A chemical recycling process comprising:
(a) generating a CO 2 stream by—
i) oxidizing ethylene to form ethylene oxide and CO 2 , and
ii) combusting methane to form flue gas comprising CO 2 ; and
(b) gasifying at least a portion of the CO 2 stream in a POX gasifier to thereby form a syngas.
13 . The process according to claim 12 , wherein the CO 2 stream is a recycle content CO 2 stream.
14 . The process according to claim 12 , wherein at least a portion of the ethylene is a recycle content ethylene that is produced by a cracking process that includes cracking recycle content pyrolysis oil.
15 . The process according to claim 12 , wherein at least a portion of the methane is a recycle content methane that is produced by a cracking process that includes cracking recycle content pyrolysis oil.
16 . The process according to claim 12 , wherein the CO 2 stream comprises at least 50 mole percent of recycle content CO 2 , based on the total molar content of the CO 2 stream.
17 . The process according to claim 12 , wherein the CO 2 stream comprises at least 0.1 mole percent and not more than 10 mole percent of water, based on the total molar content of the CO 2 stream.
18 . The process according to claim 12 , wherein at least a portion of the ethylene is produced by a cracking process that includes cracking recycle content naphtha, recycle content diesel, or recycle content ethane or recycle content propane.
19 . The process according to claim 12 , wherein the POX gasifier comprises a side injector for feeding a gaseous feedstock into the POX gasifier.
20 . The process according to claim 12 , wherein the POX gasifier does not contain any pyrolysis reaction zones.