POLISHING COMPOSITION FOR SEMICONDUCTOR PROCESS AND POLISHING METHOD OF SUBSTRATE USING THE SAME
A polishing composition for a semiconductor process includes abrasive particles and a surfactant. A volume of foam measured immediately after stirring 3L of the polishing composition at 25° C. at a speed of 1,000 rpm for 30 minutes and letting it stand for 10 minutes is 50 mL or less. When applied to a Chemical Mechanical Planarization (CMP) process, this composition improves polishing process convenience and provides a polished surface with a reduced frequency of defects.
1 . A polishing composition for a semiconductor process, the polishing composition comprising:
abrasive particles; and
a surfactant;
wherein a volume of foam measured immediately after stirring 3 L of the polishing composition at 25° C. at a speed of 1,000 rpm for 30 minutes and standing for 10 minutes is 50 mL or less.
2 . The polishing composition of claim 1 , wherein a viscosity of the polishing composition ranges from 0.7 cP to 1.5 cP at 25° C.
3 . The polishing composition of claim 1 , wherein a dynamic surface tension at a bubble lifetime of 10 seconds ranges from 25 mN/m to 70 mN/m.
4 . The polishing composition of claim 1 , wherein the surfactant comprises a nonionic surfactant, and
wherein the nonionic surfactant comprises a first nonionic surfactant having a Hydrophilic-Lipophilic Balance (HLB) value of 10 or more.
5 . The polishing composition of claim 1 , wherein the surfactant comprises a nonionic surfactant, and
wherein the nonionic surfactant comprises a second nonionic surfactant having a Hydrophilic-Lipophilic Balance (HLB) value of 8 or less.
6 . The polishing composition of claim 1 , wherein the surfactant comprises a polymeric surfactant, and
wherein the polymeric surfactant has a weight average molecular weight of 150 g/mol to 3,000 g/mol.
7 . The polishing composition of claim 1 , further comprising an antifoaming agent,
wherein the antifoaming agent comprises a water-soluble polymer.
8 . The polishing composition of claim 7 , wherein a weight average molecular weight of the antifoaming agent ranges from 200 g/mol to 2,000 g/mol.
9 . The polishing composition for of claim 7 , wherein the antifoaming agent comprises a polyglycerin-based compound.
10 . The polishing composition of claim 1 , wherein a pH of the polishing composition ranges from 2 to 5.
11 . The polishing composition of claim 1 , wherein a surface of the abrasive particles has a positive charge.
12 . A method of manufacturing a substrate, the method comprising:
polishing a substrate by applying a polishing composition for a semiconductor process as a slurry,
wherein the polishing composition comprises abrasive particles and a surfactant, and
wherein a volume of foam measured immediately after stirring 3 L of the polishing composition at 25° C. at a speed of 1,000 rpm for 30 minutes and standing for 10 minutes is 50 mL or less.