Multi-Functional Barrier Coating for Molded Fiber Containers
Coating compositions are disclosed that can be applied to at least a food-facing surface of a molded fiber container to make the coated container suitable for applications involving long term storage of a dry or frozen food item combined with short term contact with the food item in a liquid or moist state. The coating compositions include carboxylated polyvinyl alcohol copolymer and a crosslinking resin that is epichlorohydrin-based and/or azetidinium-functionalized. The compositions can also include clay particles or other suitable fillers. After crosslinking and drying, the compositions form a thermoset barrier coating in which the polyvinyl alcohol is bonded to the crosslinker by a plurality of function groups including ester functional groups.
1 . An article, comprising:
a molded fiber container adapted for holding food, the container having a container wall having a first surface for facing the food; and
a thermoset polymer coating layer applied to the first surface;
wherein the coating layer includes a polyvinyl alcohol bonded to a crosslinker by a plurality of functional groups including ester functional groups.
2 . The article of claim 1 , further comprising:
clay particles dispersed throughout the coating layer.
3 . The article of claim 2 , wherein the coating layer consists essentially of the polyvinyl alcohol bonded to the crosslinker, and the particles.
4 . The article of claim 2 , wherein the article exhibits a moisture vapor transmission rate (MVTR) of no more than 77 (g/m 2 )/day.
5 . The article of claim 2 , wherein the plurality of functional groups also include ether functional groups.
6 . The article of claim 2 , wherein the coating layer has a coat weight of at least 5 g/m 2 .