Plugging material, preparation method therefor, and use thereof
A plugging material is prepared from the following raw materials in terms of mass fractions, which include: 1 to 3.6 parts of PETA-modified bisphenol A epoxy resin, 1.5 to 2.4 parts of addition product of m-phenylenediamine and methacrylic acid, 0.12 to 0.17 parts of nanosilica dispersion liquid, with the remainder being water, such that the sum of the mass fractions of the aforementioned raw materials totals 100 parts. The preparation method includes: pouring a water phase mixture into a continuously stirred oil-phase mixture to form a gel-forming liquid through continued stirring; transferring the gel-forming liquid to be mixed with dibenzoyl peroxide, and stirring and reacting at a temperature of 50° C. to 120° C. to obtain the plugging material. The plugging material is resistant to high temperatures and high salinity, and exhibits strong plugging performance.
1. A plugging material, which is prepared from the following raw materials in terms of mass fractions, which comprise: 1 to 3.6 parts of pentaerythritol tetraacrylate (PETA)-modified bisphenol A epoxy resin, 1.5 to 2.4 parts of an addition product of m-phenylenediamine and methacrylic acid, 0.12 to 0.17 parts of nanosilica dispersion liquid, with the remainder being water, such that the sum of the mass fractions of the aforementioned raw materials totals 100 parts.
2. The plugging material according to claim 1 , the PETA-modified bisphenol A epoxy resin is prepared through the following steps: mixing bisphenol A epoxy resin, PETA, and a first catalyst to obtain a mixture, and stirring the mixture under a temperature of 40 to 50° C. to obtain the PETA-modified bisphenol A epoxy resin.
3. The plugging material according to claim 2 , the PETA-modified bisphenol A epoxy resin is obtained by reacting under nitrogen protection at a temperature of 40° C. to 50° C., with a stirring speed of 100 r/min to 200 r/min, for a duration of 2 h to 4 h.
4. The plugging material according to claim 2 , the mass ratio of the bisphenol A epoxy resin to the PETA is 1:0.25 to 1:0.3.
5. The plugging material according to claim 4 , the first catalyst is triphenylphosphine, with an addition amount of 0.1% to 2% of the total mass of the bisphenol A epoxy resin and the PETA.
6. The plugging material according to claim 1 , the addition product of m-phenylenediamine and methacrylic acid is prepared through the following steps:
mixing m-phenylenediamine, methacrylic acid, and a second catalyst to obtain a mixture, and stirring the mixture under a temperature of 25° C. to 60° C. to obtain the addition product of m-phenylenediamine and methacrylic acid.
7. The plugging material according to claim 6 , the mass ratio of the m-phenylenediamine to the methacrylic acid is 1:0.8 to 1:1.6.
8. The plugging material according to claim 7 , the second catalyst is potassium carbonate, with an addition amount of 1% to 5% of the total mass of the m-phenylenediamine and the methacrylic acid.
9. A preparing method for a plugging material, wherein the plugging material is prepared from the following raw materials in terms of mass fractions, which comprise: 1 to 3.6 parts of pentaerythritol tetraacrylate (PETA)-modified bisphenol A epoxy resin, 1.5 to 2.4 parts of an addition product of m-phenylenediamine and methacrylic acid, 0.12 to 0.17 parts of nanosilica dispersion liquid, with the remainder being water, such that the sum of the mass fractions of the aforementioned raw materials totals 100 parts;
the preparing method comprises the following steps:
step S1: preparation of oil phase and water phase: mixing PETA-modified bisphenol A epoxy resin and the addition product of m-phenylenediamine and methacrylic acid to form an oil phase mixture; and mixing nanosilica dispersion liquid with water to obtain a water phase mixture;
step S2: emulsification process: pouring the water phase mixture into the continuously stirred oil phase mixture and continue stirring to form a gel-forming liquid;
step S3: curing process: transferring the gel-forming liquid and mixing the gel-forming liquid with dibenzoyl peroxide; stirring and reacting at a temperature of 50° C. to 120° C. to obtain the plugging material.
10. The preparing method for plugging material according to claim 9 , in step S2, the duration of continued stirring is 20 to 30 minutes.
11. The preparing method for plugging material according to claim 10 , in step S3, the stirring and reaction time at a temperature of 50° C. to 120° C. is 4 hours to 12 hours.