CARBON DIOXIDE SEQUESTRATION WITH MAGNESIUM HYDROXIDE AND REGENERATION OF MAGNESIUM HYDROXIDE
Embodiments of the present disclosure are directed to systems and methods of removing carbon dioxide from a gaseous stream using magnesium hydroxide and then regenerating the magnesium hydroxide. In some embodiments, the systems and methods can further comprise using the waste heat from one or more gas streams to provide some or all of the heat needed to drive the reactions. In some embodiments, magnesium chloride is primarily in the form of magnesium chloride dihydrate and is fed to a decomposition reactor to generate magnesium hydroxychloride, which is in turn fed to a second decomposition reactor to generate magnesium hydroxide.
1 - 43 . (canceled)
44 . A method of regenerating Mg(OH) 2 in a process that reduces the amount of CO 2 contained in a gas stream, comprising:
(a) reacting a MgCl 2 containing material with steam in a first decomposition reactor to form step (a) products comprising Mg(OH) Cl and HCl, where the MgCl 2 containing material comprises a water to MgCl 2 ratio of less than about 2.5:1;
(b) reacting the Mg(OH) Cl with steam in a second decomposition reactor to form step (b) products comprising HCl and magnesium-containing products comprising mostly Mg(OH) 2 ;
(c) reacting the Mg(OH) 2 with CO 2 in a first absorption reactor to form MgCO 3 and H 2 O;
(d) reacting the MgCO 3 with CaCl 2 in a second absorption reactor to form step (d) products comprising MgCl 2 and CaCO 3 .
45 . The method of claim 44 , wherein the step (a) products comprises greater than 90% by weight Mg(OH) Cl.
46 . The method of claim 44 , further comprising passing a gaseous outflow comprising HCl and steam from the second decomposition reactor to the first decomposition reactor.
47 . The method of claim 44 , wherein the magnesium chloride-containing material of step (a) comprises magnesium chloride dihydrate.
48 . The method of claim 44 , wherein a first decomposition reactor operation temperature ranges from 250° C. to 400° C.
49 . The method of claim 44 , wherein a second decomposition reactor operation temperature ranges from 380° C. to 500° C.
50 . The method of claim 44 , wherein the step (d) products are in a liquid phase and a solid phase, the liquid phase comprising an aqueous solution of at least 50% by weight of magnesium chloride.
51 . The method of claim 50 , wherein a solid phase step (d) product comprises calcium carbonate.
52 . The method of claim 50 , wherein a molar ratio of water to MgCl 2 in the step (d) products is 5 or less.
53 . The method of claim 50 , wherein a molar ratio of water to MgCl 2 in the step (d) products is less than 4.5 to 1.
54 . The method of claim 50 , further comprising separating at least a portion of the calcium carbonate formed in step (d) from the liquid phase in a solid liquid separator.
55 . The method of claim 50 , further comprising removing a portion of water from the liquid phase in a dryer to provide a product having a molar ratio of water to magnesium chloride of about 2 to 1.
56 . The method of claim 55 , wherein the dryer is configured to form magnesium chloride dihydrate.
57 . The method of claim 56 , further comprising employing the formed magnesium chloride dihydrate as the magnesium chloride-containing material of step (a).
58 . The method of claim 44 , further comprising transferring heat from the gas stream to a first recycling heating fluid and transferring heat from the first recycling heating fluid to the first decomposition reactor.
59 . The method of claim 44 , further comprising transferring heat from the gas stream to a second recycling heating fluid and transferring heat from the second recycling heating fluid to the second decomposition reactor.
60 . The method of claim 50 , further comprising transferring heat from the gas stream to a third recycling heating fluid and transferring heat from the third recycling heating fluid to the step (d) products to facilitate removal of water.