COMPOSITIONS AND METHODS FOR TREATING AND RECLAIMING PAINT FLUSH WASTE
Methods and compositions useful for cleaning the lines used during manufacturing processes are disclosed. In certain embodiments, the methods and compositions may be particularly useful in the manufacture of colored paints or coatings or in the use of colored paints or coatings, for example, in the manufacture of finished automobiles.
1 . A method for switching paint formulations in a manufacturing process from a first color formulation to a second color formulation, said first color formulation comprising at least one suspended inorganic paint component and at least one dissolved organic paint component, the method comprising the acts of:
flushing lines containing the first color formulation with a first composition to provide a second composition wherein said second composition comprises the suspended inorganic paint component and the dissolved organic paint component;
adjusting the pH of the waste stream to floc the inorganic paint component and precipitate the organic paint component to provide a composition comprising a liquid portion and paint solids;
separating the paint solids from the liquid portion of the second composition to provide a solid portion; and
introducing a second color component into the lines of the manufacturing process;
wherein the organic paint component includes acrylics, acrylic enamels, and/or urethanes;
and wherein the inorganic paint component includes metal compounds.
2 . The method of claim 1 , wherein a base is used to floc the inorganic paint component and precipitate the organic paint component.
3 . The method of claim 2 , wherein the base is a strong base.
4 . The method of claim 3 , wherein the strong base is selected from the group consisting of lithium hydroxide, sodium hydroxide, potassium hydroxide, magnesium hydroxide, calcium hydroxide, or lime.
5 . The method of claim 2 , wherein an acid is used to floc the inorganic paint component and precipitate the organic paint component.
6 . The method of claim 5 , wherein the acid is a strong acid.
7 . The method of claim 6 , wherein the strong acid is sulfuric acid, phosphoric acid, nitric acid, hydrochloric acid, or methane sulfonic acid.
8 . The method of claim 1 , wherein the act of separating the paint solids from the liquid portion of the second composition to provide a solid portion comprises filtration or centrifugation.
9 . The method of claim 8 , wherein a filter aid is used to aid in filtration.
10 . The method of claim 8 , wherein the filtration comprises centrifugal filtration, gravity filtration, vacuum filtration, cold filtration, hot filtration, multi-layer filtration, mechanical filtration, surface filtration, depth filtration, or using a plate and frame filter press.
11 . The method of claim 9 , wherein said filter aid is diatomaceous earth, diatomite, perlite, or cellulose.
12 . The method of claim 1 , wherein an oxidizer is used in breaking the emulsion of said second composition.
13 . The method of claim 12 , wherein the oxidizer is bleach, hypochlorite, chloramine, a permanganate, ozone, or hydrogen peroxide.
14 . The method of claim 1 , wherein CO 2 is used to adjust the pH of the liquid portion of the second composition after filtration.
15 . A method for treating a waste stream from flushing systems, the method comprising the acts of:
providing a waste stream wherein said waste stream comprises at least one suspended inorganic paint component and at least one dissolved organic paint component;
adjusting the pH of the waste stream to floc the inorganic paint component and precipitate the organic paint component to provide a waste stream comprising a liquid portion and paint solids; and
separating the paint solids from the liquid portion of the waste stream;
wherein the organic paint component includes acrylics, acrylic enamels, and/or urethanes;
and wherein the inorganic paint component includes metal compounds.
16 . The method of claim 1 wherein the inorganic paint component comprises barium.
17 . The method of claim 15 , wherein the inorganic paint component comprises barium.