SYSTEMS AND METHODS FOR HIGH ENERGY DENSITY HEAT TRANSFER
The application pertains to, for example, novel processes and systems for heat transfer, refrigeration, energy storage, and various cooling and heating processes. Such processes may include cooling or mixing various liquid-liquid phase transition liquids to release and/or energy. Additionally or alternatively, such processes may include charging and/or discharging thermal storage reservoirs with layered liquids of various temperatures.
1 . A process for heat transfer comprising:
cooling a liquid-liquid phase transition liquid comprising two liquid phases below an exothermic liquid-liquid phase transition temperature range to form a liquid-liquid phase transition liquid comprising one liquid phase; and
cooling said one liquid phase below a temperature of a solid-liquid phase change to form a composition comprising a solid-liquid slurry.
2 . The process of claim 1 wherein the liquid-liquid phase transition liquid further comprises a solid-liquid phase change material.
3 . The process of claim 2 wherein the solid-liquid phase change material is soluble in at least one liquid phase of the liquid-liquid phase transition liquid.
4 . The process of claim 2 wherein the solid-liquid phase change material is insoluble in the liquid-liquid phase transition liquid while at a liquid state.
5 . The process of claim 3 wherein the solid-liquid phase change material comprises water.
6 . The process of claim 4 wherein the solid-liquid phase change material comprises a paraffin, a hydrophobic polymer, or a combination thereof.
7 . The process of claim 4 wherein said liquid-liquid phase transition liquid comprising one liquid phase is in a multi-liquid phase mixture with the solid-liquid phase change material.
8 . The process of claim 1 wherein the temperature of the solid-liquid phase change (1) is within the liquid-liquid phase transition temperature range, or (2) is adjacent to the liquid-liquid phase transition temperature range, or (3) is significantly different from the liquid-liquid phase transition temperature range.
9 . The process of claim 1 which further comprises adjusting the liquid-liquid phase transition temperature range by changing a concentration of a reagent in the liquid-liquid phase transition liquid.
10 . The process of claim 1 further comprising separating at least a portion of the solid-liquid slurry from the liquid-liquid phase transition liquid.
11 . The process of claim 1 further comprising adding a solid-liquid phase change material to the liquid-liquid phase transition liquid.
12 . The process of claim 2 further comprising adjusting the solid-liquid phase change material in response to a change in heat capacity.
13 . The process of claim 2 further comprising replacing at least a portion of the solid-liquid phase change material with a second solid-liquid phase change material having a different freezing point.
14 . The process of claim 13 wherein the replacing is in response to a change in an operating temperature.
15 . The process of claim 1 wherein the specific heat capacity of the solid-liquid slurry is greater than the specific heat capacity of a water-ice slurry at the temperature of the solid-liquid phase change.