PURIFICATION AND PROCESSING OF HYDROCARBON PRODUCTS
Exemplary methods and systems for improved purification and processing of hydrocarbon products are provided.
1 . A method comprising:
subjecting syngas to a Fischer Tropsch reaction to produce a Fischer Tropsch effluent;
separating the Fischer Tropsch effluent in a gas-liquid-liquid separator into a hydrocarbon liquid stream and a full non-liquid tail gas stream comprising unconverted syngas;
passing the hydrocarbon liquid stream and the full non-liquid tail gas stream to a plurality of reactors comprising a hydrogenation reactor to produce a hydrogenation effluent, wherein alkenes in the hydrocarbon liquid stream are converted into alkanes in the hydrogenation reactor; and
obtaining a fuel stream from the hydrogenation effluent.
2 . The method of claim 1 , wherein the alkene content in the hydrocarbon liquid stream is lowered via the conversion of the alkenes to alkanes.
3 . The method of claim 1 , wherein the alkene content in the hydrocarbon liquid stream is lowered to less than 1% via hydro-treating of the full non-liquid gas to convert alkenes to alkanes.
4 . The method of claim 1 , the alkene conversion being based on temperature and space velocity requirements in a presence of the full non-liquid tail gas stream.
5 . The method of claim 1 , wherein the fuel stream comprises a diesel fuel stream.
6 . The method of claim 1 , further comprising:
sending the full non-liquid tail gas stream directly from the gas-liquid-liquid separator to the hydrogenation reactor without a compositional gas separation.
7 . A system comprising:
a Fischer Tropsch reactor configured to produce a Fischer Tropsch effluent from a syngas;
a gas-liquid-liquid separator configured to separate the Fischer Tropsch effluent into a hydrocarbon liquid stream and a full non-liquid tail gas stream comprising unconverted syngas; and
a plurality of reactors comprising a hydrogenation reactor configured to receive the hydrocarbon liquid stream and the full non-liquid tail gas stream and produce a hydrogenation effluent, wherein alkenes in the hydrocarbon liquid stream are converted into alkanes in the hydrogenation reactor.
8 . The system of claim 7 , wherein the alkene content in the hydrocarbon liquid stream is lowered via the conversion of the alkenes to alkanes.
9 . The system of claim 7 , wherein the alkene content in the hydrocarbon liquid stream is lowered to less than 1% via hydro-treating of the full non-liquid gas to convert alkenes to alkanes.
10 . The system of claim 7 , the alkene conversion being based on temperature and space velocity requirements in a presence of the full non-liquid tail gas stream.
11 . The system of claim 7 , further comprising a diesel separator configured to generate a diesel fuel from the hydrogenation effluent.
12 . The system of claim 7 , wherein the full non-liquid tail gas stream is sent directly from the gas-liquid-liquid separator to the hydrogenation reactor without a compositional gas separation.