ELECTROLYTE INCLUDING ELECTROLYTE SOLVENT, FLUOROETHER, AND BIS(FLUOROSULFONYL) SALT, AND LITHIUM METAL ELECTROCHEMICAL CELLS INCLUDING THE SAME
Systems, devices, and methods described herein relate to electrolyte formulations and the incorporation thereof into batteries. In some aspects, an electrolyte composition can comprise between about 10 wt % and about 42 wt % of an electrolyte solvent, between about 13 wt % and about 59 wt % of a fluoroether. In some embodiments, the electrolyte solvent can make up between about 26 wt % and about 39 wt % of the composition. In some embodiments, the fluoroether can make up between about 18 wt % and about 36 wt % of the composition. In some embodiments, the composition can include between about 0.5 wt % and about 1.5 wt % of a first additive. In some embodiments, the composition can include between about 0.5 wt % and about 5 wt % of a second additive.
1 . A composition, comprising:
about 32 wt % to about 51 wt % of a first electrolyte solvent;
about 10 wt % to about 36 wt % of a halogenated ether;
about 12 wt % to about 45 wt % of a salt; and
about 4 wt % to about 26 wt % of a second electrolyte solvent, the second electrolyte solvent different from the first electrolyte solvent.
2 . The composition of claim 1 , wherein the halogenated ether includes a fluoroether (FE).
3 . The composition of claim 1 , wherein the first electrolyte solvent includes at least one of:
1,2-dimethoxyethane, bis-(2-fluoro-ethyl)-ether, 1,2-diethoxyethane, bis(2-methoxyethyl) ether, triethylene glycol dimethyl ether, tetraethylene glycol dimethyl ether, diethyl ether, dipropyl ether, 1,2-dipropoxyethane, dibutoxyethane, 1,2-diethoxypropane, dimethyl carbonate, 1,3-dioxolane, 1,4-dioxolane, ethyl methyl carbonate, diethyl carbonate, dimethyl sulfoxide, ethyl vinyl sulfone, tetramethylene sulfone, ethyl methyl sulfone, ethylene carbonate, vinylene carbonate, 4-vinyl-1,3-dioxolan-2-one, dimethyl sulfone, methyl butyrate, ethyl propionate, trimethyl phosphate, triethyl phosphate, gamma-butyrolactone, 4-methylene-1,3-dioxolan-2-one, methylene ethylene carbonate, 4,5-dimethylene-1,3-dioxolan-2-one, allyl ether, triallyl amine, triallyl cyanurate, triallyl isocyanurate, water, carbonate, fluorobutane, tetrahydropyran, ethyl acetate, ethyl butyrate, methyl acetate, methyl butyrate, methyl propionate, methyl pentafluoropropionate, propyl acetate, 2,2,2,-trifluoroethyl acetate, 2,2,2,-trifluoroethyl butyrate, or fluoroethylene carbonate.
4 . The composition of claim 1 , wherein the second electrolyte solvent includes at least one of:
1,2-dimethoxyethane, bis-(2-fluoro-ethyl)-ether, 1,2-diethoxyethane, bis(2-methoxyethyl) ether, triethylene glycol dimethyl ether, tetraethylene glycol dimethyl ether, diethyl ether, dipropyl ether, 1,2-dipropoxyethane, dibutoxyethane, 1,2-diethoxypropane, dimethyl carbonate, 1,3-dioxolane, 1,4-dioxolane, ethyl methyl carbonate, diethyl carbonate, dimethyl sulfoxide, ethyl vinyl sulfone, tetramethylene sulfone, ethyl methyl sulfone, ethylene carbonate, tetrahydropyran, 4-vinyl-1,3-dioxolan-2-one, dimethyl sulfone, methyl butyrate, ethyl propionate, trimethyl phosphate, triethyl phosphate, gamma-butyrolactone, 4-methylene-1,3-dioxolan-2-one, methylene ethylene carbonate, 4,5-dimethylene-1,3-dioxolan-2-one, allyl ether, triallyl amine, triallyl cyanurate, triallyl isocyanurate, water, carbonate, dimethyl carbonate, 1,3-dioxolane, ethyl methyl carbonate, diethyl carbonate, vinylene carbonate, ethyl acetate, ethyl butyrate, methyl acetate, methyl butyrate, methyl propionate, methyl pentafluoropropionate, propyl acetate, 2,2,2,-trifluoroethyl acetate, 2,2,2,-trifluoroethyl butyrate, or fluoroethylene carbonate.
5 . The composition of claim 1 , wherein the halogenated ether includes a compound having the following structure:
where n 1 and n 2 each have values between 1 and 5, X=F, Br, Cl, or I, and n=1-5 per molecule.
6 . The composition of claim 1 , further comprising:
about 0.5 wt % to about 1.5 wt % of a first additive.
7 . The composition of claim 6 , wherein the first additive includes at least one of:
lithium bis(fluorosulfonyl)imide (F 2 LiNO 4 S 2 ), lithium bis(trifluoromethylsulfonyl)imide (LiC 2 F 6 NO 4 S 2 ), lithium bis(oxalato)borate, lithium hexafluorophosphate (LiPF 6 ), lithium hexafluoroarsenate (LiAsF 6 ), lithium bis(trifluoromethane) sulfonimide (LiN(SO 2 CF 3 ) 2 ), lithium trifluoromethanesulfonate (LiCF 3 SO 3 ), lithium perchlorate (LiClO 4 ), lithium difluoro oxalato borate (LiBF 2 (C 2 O 4 )), lithium iodide (LiI), lithium bromide (LiBr), lithium chloride (LiCl), lithium hydroxide (LiOH), lithium nitrate (LiNO 3 ), lithium 2-trifluoromethyl-4,5-dicyanoimidazole (LiTDI), lithium sulfate (Li 2 SO 4 ), lithium tetrafluoroborate (LiBF 4 ), or lithium difluorophosphate (LiPO 2 F 2 ).
8 . The composition of claim 1 , wherein the composition has a conductivity of at least about 7 mS/cm.
9 . The composition of claim 1 , wherein the halogenated ether includes a compound having the following structure:
where n 1 and n 2 can each have values between 0 and 5, X=F, Br, Cl, or I, n=1-4 per molecule.
10 . A composition, comprising:
about 10 wt % to about 56 wt % of a first electrolyte solvent;
a second electrolyte solvent different from the first electrolyte solvent;
a third electrolyte solvent different from the first electrolyte solvent and the second electrolyte solvent, the third electrolyte solvent including a halogenated ether;
about 10 wt % to about 30 wt % of a first salt including hexafluorophosphate (PF 6 ) ions; and
a second salt different from the first salt.
11 . The composition of claim 10 , wherein the composition includes between about 4 wt % to about 19 wt % of the second salt.
12 . The composition of claim 10 , wherein the first electrolyte solvent includes at least one of:
1,2-dimethoxyethane, bis-(2-fluoro-ethyl)-ether, 1,2-diethoxyethane, bis(2-methoxyethyl) ether, triethylene glycol dimethyl ether, tetraethylene glycol dimethyl ether, diethyl ether, dipropyl ether, 1,2-dipropoxyethane, dibutoxyethane, 1,2-diethoxypropane, dimethyl carbonate, 1,3-dioxolane, 1,4-dioxolane, ethyl methyl carbonate, diethyl carbonate, dimethyl sulfoxide, ethyl vinyl sulfone, tetramethylene sulfone, ethyl methyl sulfone, ethylene carbonate, vinylene carbonate, 4-vinyl-1,3-dioxolan-2-one, dimethyl sulfone, methyl butyrate, ethyl propionate, trimethyl phosphate, triethyl phosphate, gamma-butyrolactone, 4-methylene-1,3-dioxolan-2-one, methylene ethylene carbonate, 4,5-dimethylene-1,3-dioxolan-2-one, allyl ether, triallyl amine, triallyl cyanurate, triallyl isocyanurate, water, carbonate, fluorobutane, tetrahydropyran, ethyl acetate, ethyl butyrate, methyl acetate, methyl butyrate, methyl propionate, methyl pentafluoropropionate, propyl acetate, 2,2,2,-trifluoroethyl acetate, 2,2,2,-trifluoroethyl butyrate, or fluoroethylene carbonate.
13 . The composition of claim 10 , wherein the second electrolyte solvent includes at least one of:
1,2-dimethoxyethane, bis-(2-fluoro-ethyl)-ether, 1,2-diethoxyethane, bis(2-methoxyethyl) ether, triethylene glycol dimethyl ether, tetraethylene glycol dimethyl ether, diethyl ether, dipropyl ether, 1,2-dipropoxyethane, dibutoxyethane, 1,2-diethoxypropane, dimethyl carbonate, 1,3-dioxolane, 1,4-dioxolane, ethyl methyl carbonate, diethyl carbonate, dimethyl sulfoxide, ethyl vinyl sulfone, tetramethylene sulfone, ethyl methyl sulfone, ethylene carbonate, vinylene carbonate, 4-vinyl-1,3-dioxolan-2-one, dimethyl sulfone, methyl butyrate, ethyl propionate, trimethyl phosphate, triethyl phosphate, gamma-butyrolactone, 4-methylene-1,3-dioxolan-2-one, methylene ethylene carbonate, 4,5-dimethylene-1,3-dioxolan-2-one, allyl ether, triallyl amine, triallyl cyanurate, triallyl isocyanurate, water, carbonate, fluorobutane, tetrahydropyran, ethyl acetate, ethyl butyrate, methyl acetate, methyl butyrate, methyl propionate, methyl pentafluoropropionate, propyl acetate, 2,2,2,-trifluoroethyl acetate, 2,2,2,-trifluoroethyl butyrate, or fluoroethylene carbonate.
14 . The composition of claim 10 , wherein the composition includes about 10 wt % to about 25 wt % of the second electrolyte solvent.
15 . The composition of claim 10 , wherein the second salt includes bis(fluorosulfonyl)imide ions.
16 . The composition of claim 10 , further comprising:
about 0.5 wt % to about 1.5 wt % of a first additive.
17 . The composition of claim 16 , wherein the first additive includes at least one of:
tris-(trimethylsilyl) phosphate (TMSP), trimethoxy(3,3,3-trifluoropropyl)silane (TTS), triisobutyl phosphate, tributyl phosphate, trioctyl phosphate, triethyl phosphate, tris(2-ethylhexyl)phosphate, triphenyl phosphate, pentafluorophenyltriethoxysilane (TPS), amphiphilic nonionic fluorosurfactants with hydrophilic part of ethylene glycol chains and hydrophobic part of fluoroalkyl chains, boric acid tris(trimethylsilyl) ester (TMSB), tris-(pentafluorophenyl)silane (TPFPS), 1,10-sulfonyldiimidazole (SDM), trioxane, lithium difluorophosphate, prop-1-ene-1,3-sultone, 1,4-butane sultone, fluoropropane sultone, propargyl methanesulfonate, 1,3-propanediolcyclic, 1,3,2-benzodioxathiole 2,2-dioxide, dihydro-1,3,2-dioxathiolo [1,3,2] dioxathiole-2,2,5,5 tetraoxide, ethylene sulfite, vinyl ethylene sulfite, propylene sulfite, butylene sulfite, dimethyl sulfite, 1,3-propane sultone, methylene methanedisulfonate, sulfolane, di(methylsulfonyl)methane (DMSM), methyl 2,2-dilfuoro-2-(fluorosulfonyl) acetate (MDFA), p-toluenesulfonyl isocyanate (PTSI), phenyl trans-styryl sulfone, N,N,N,N-tetraethyl sulfamide, 3-sulfopropionic anhydride, diphenyl disulfide, 1,3,2-dioxathiolane 2,2-dioxide (DTD), lithium difluoro oxalato borate, lithium nitrate, (pentafluorophenyl) diphenylphosphine (PFPDPP), cetyltrimethylammonium bromide (CTAB), sodium dodecyl sulfate (SDS), polyethylene-glycol (PEG-8000), and thiourea (TU), benzotriazole (BTA), thiourea (CH 4 N 2 S), sodium dodecyl benzene sulfonate (SDBS), LiTFSI, poly(vinyl alcohol) (PVA), polyethylene glycol (PEG), or carboxymethyl cellulose (CMC).
18 . The composition of claim 17 , further comprising:
about 0.5 wt % to about 5 wt % of a second additive, the second additive being different from the first additive.
19 . The composition of claim 18 , wherein the second additive includes at least one of:
tris-(trimethylsilyl) phosphate (TMSP), trimethoxy(3,3,3-trifluoropropyl)silane (TTS), triisobutyl phosphate, tributyl phosphate, trioctyl phosphate, triethyl phosphate, tris(2-ethylhexyl)phosphate, triphenyl phosphate, pentafluorophenyltriethoxysilane (TPS), amphiphilic nonionic fluorosurfactants with hydrophilic part of ethylene glycol chains and hydrophobic part of fluoroalkyl chains, boric acid tris (trimethylsilyl) ester (TMSB), tris-(pentafluorophenyl)silane (TPFPS), 1,10-sulfonyldiimidazole (SDM), trioxane, lithium difluorophosphate, prop-1-ene-1,3-sultone, 1,4-butane sultone, fluoropropane sultone, propargyl methanesulfonate, 1,3-propanediolcyclic, 1,3,2-benzodioxathiole 2,2-dioxide, dihydro-1,3,2-dioxathiolo [1,3,2] dioxathiole-2,2,5,5 tetraoxide, ethylene sulfite, vinyl ethylene sulfite, propylene sulfite, butylene sulfite, dimethyl sulfite, 1,3-propane sultone, methylene methanedisulfonate, sulfolane, di(methylsulfonyl)methane (DMSM), methyl 2,2-dilfuoro-2-(fluorosulfonyl) acetate (MDFA), p-toluenesulfonyl isocyanate (PTSI), phenyl trans-styryl sulfone, N,N,N,N-tetraethyl sulfamide, 3-sulfopropionic anhydride, diphenyl disulfide, 1,3,2-dioxathiolane 2,2-dioxide (DTD), lithium difluoro oxalato borate, lithium nitrate, (pentafluorophenyl)diphenylphosphine (PFPDPP), cetyltrimethylammonium bromide (CTAB), sodium dodecyl sulfate (SDS), polyethylene-glycol (PEG-8000), and thiourea (TU), benzotriazole (BTA), thiourea (CH 4 N 2 S),sodium dodecyl benzene sulfonate (SDBS), LiTFSI, poly(vinyl alcohol) (PVA), polyethylene glycol (PEG), or carboxymethyl cellulose (CMC).
20 . The composition of claim 10 , wherein the halogenated ether includes a fluoroether (FE).
21 . An electrochemical cell, comprising:
an anode disposed on an anode current collector;
a cathode disposed on a cathode current collector;
a separator disposed between the anode and the cathode; and
an electrolyte, the electrolyte comprising:
a first electrolyte solvent;
a second electrolyte solvent, the second electrolyte solvent different from the first electrolyte solvent, the second electrolyte solvent including a halogenated ether;
about 10 wt % to about 30 wt % of a first salt including hexafluorophosphate (PF 6 ) ions;
and
about 4 wt % to about 19 wt % of a second salt including bis(fluorosulfonyl)imide ions.
22 . The electrochemical cell of claim 21 , wherein the electrolyte includes about 10 wt % to about 25 wt % of the first salt.
23 . The electrochemical cell of claim 21 , wherein the electrolyte includes about 4 wt % to about 10 wt % of the second salt.
24 . The electrochemical cell of claim 21 , wherein the electrolyte includes about 10 wt % to about 56 wt % of the first electrolyte solvent.
25 . The electrochemical cell of claim 21 , wherein the electrolyte includes about 40 wt % to about 56 wt % of the first electrolyte solvent.
26 . The electrochemical cell of claim 21 , wherein the anode includes at least one of carbon, graphite, hard carbon, activated carbon, silicon, SiO, Sn, SnS, SnS 2 , Sn 3 P 4 , Sb, SbS, Bi, P, TiO 2 , antimony, tin, aluminum, silver, copper, ZnO, Cu 2 O, or LTO.
27 . The electrochemical cell of claim 21 , wherein the anode includes lithium metal.
28 . The electrochemical cell of claim 21 , wherein the cathode includes at least one of:
LFP, conductive carbon particles, or high-nickel layered oxide (NMC 811 ).
29 . The electrochemical cell of claim 21 , wherein the halogenated ether includes a compound having the following structure:
where n 1 and n 2 each have values between 1 and 5, X=F, Br, Cl, or I, and n=1-5 per molecule.
30 . The electrochemical cell of claim 21 , wherein the halogenated ether does not include a hydrofluoroether.