Antimicrobial Coatings
Described are coatings for medical devices and methods of forming same.
1 . A coating, comprising:
a base coat comprising a copolymer of tetrahydrofurfuryl acrylate and a monomer comprising a functional group amenable to further derivatization, including a plurality of reactive moieties; and
a top coat comprising at least one antimicrobial compound, a polymer, or a combination thereof;
wherein the top coat comprises a copolymer reaction product of a mixture comprising methacryloyloxyethyl phosphorylcholine and 4-hydroxybutyl acrylate, and
wherein the top coat comprises a decorated top coat formed from a reaction product of a mixture comprising the copolymer reaction product and 2-isocyanatoethyl acrylate.
2 . The coating of claim 1 , wherein the top coat comprises a top coat macromer formed from a reaction product of a mixture comprising the decorated top coat, benzophenone, and 1-hydroxycyclohexyl phenyl ketone.
3 . The coating of claim 1 , wherein the functional group comprises at least one of hydroxyl, amine, or carboxylic acid group.
4 . The coating of claim 1 , wherein the monomer comprises hydroxyethyl methacrylate, hydroxyethyl acrylate, hydroxypropyl acrylate, hydroxypropyl methacrylate, hydroxybutyl acrylate, hydroxybutyl methacrylate, N-(3-aminopropyl) methacrylamide, 2-aminoethyl methacrylate, 2-aminoethyl methacrylamide, acrylic acid, methacrylic acid, beta-carboxyethyl acrylate, or a combination thereof.
5 . The coating of claim 1 , wherein the base coat comprises a copolymer of tetrahydrofurfuryl acrylate and 4-hydroxybutyl acrylate.
6 . The coating of claim 5 , wherein the base coat comprises a reaction product of a mixture comprising the copolymer, benzophenone, and 1-hydroxycyclohexyl phenyl ketone.
7 . The coating of claim 1 , wherein said antimicrobial compound comprises an anti-microbial small molecule, protein, polysaccharide, glycosaminoglycan, or polymer derivatized with polymerizable groups.
8 . The coating formulation of claim 1 , wherein said antimicrobial compound comprises at least one of silver-containing polymers, antibiotics, antimicrobial peptides, zwitterionic polymers, nitric oxide releasing polymers, enzymes, extremely hydrophilic polymers, and extremely hydrophobic polymers.
9 . The coating of claim 1 , wherein the structure of the top coat is linear or branched.
10 . A medical device, comprising a surface including the coating of claim 1 .
11 . A medical device, comprising a surface including the coating of claim 2 .
12 . A medical device, comprising a surface including the coating of claim 3 .
13 . A medical device, comprising a surface including the coating of claim 4 .
14 . A medical device, comprising a surface including the coating of claim 5 .
15 . A medical device, comprising a surface including the coating of claim 6 .
16 . A medical device, comprising a surface including the coating of claim 7 .
17 . A medical device, comprising a surface including the coating of claim 8 .
18 . A medical device, comprising a surface including the coating of claim 9 .
19 . The medical device of claim 10 , wherein the medical device is a catheter.
20 . The medical device of claim 19 , wherein the catheter is a urinary catheter.