Pigment for safety applications
The invention relates to a multilayered interference pigment consisting of a transparent carrier material which is coated with alternating layers of colorless, non-absorbent metal oxides having a high and a low refractive index, the difference between the refractive indices being at least 0.1. The inventive pigment can be obtained by alternately coating the transparent carrier material with a metal oxide having a high refractive index and a metal oxide having a low refractive index according to the wet method, by hydrolysing the corresponding water-soluble, inorganic metal compounds, and separating, drying and optionally calcinating the obtained pigment.
1. A multilayer interference pigment for security applications, consisting of a transparent support material which is coated with alternating layers of colourless, non-absorbent metal oxides of high and low refractive index, with the difference between the refractive indices being at least 0.1, obtainable by alternate coating of the transparent support material with a metal oxide of high refractive index and a metal oxide of low refractive index by the wet process by hydrolysis of the corresponding, water-soluble, inorganic metal compounds, and separating off, drying and optionally calcining the resultant pigment, whereby said multilayer interference pigment exhibits a perceivable three-hue effect of two reflection colors and one transmission color.
2. An interference pigment according to claim 1 , in which the transparent support material is a phyllosilicate, platelet-shaped aluminium oxide, or glass or silicon dioxide platelets.
3. An interference pigment according to claim 1 , in which the colourless, non-absorbent metal oxide of high refractive index is titanium dioxide, zirconium oxide, zinc oxide, tin oxide or a mixture of these oxides.
4. An interference pigment according to claim 1 , in which the colourless, non-absorbent metal oxide of low refractive index is silicon dioxide, aluminium oxide, AlOOH, boron trioxide or a mixture of these oxides.
5. A process for the production of the interference pigment according to claim 1 , in which the transparent support material is suspended in water and coated alternately with a colourless, non-absorbent metal oxide of high refractive index and a colourless, non-absorbent metal oxide of low refractive index by addition and hydrolysis of the corresponding inorganic, water-soluble metal compounds, the pH necessary for the precipitation of the respective metal oxide being set and kept constant by simultaneous addition of acid or base, and the coated support material is subsequently separated off from the aqueous suspension, dried and optionally calcined.
6. A process for the production of the interference pigment according to claim 5 , in which the colourless, non-absorbent metal oxide of high refractive index is titanium dioxide, zirconium oxide, zinc oxide, tin oxide or a mixture of these oxides.
7. A process for the production of the interference pigment according to claim 5 , in which the colourless, non-absorbent metal oxide of low refractive index is silicon dioxide, aluminium oxide, AlOOH, boron trioxide or a mixture of these oxides.
8. In a forgery-resistant security application comprising paints, printing inks, plastics, or paper, the improvement wherein said paint, printing ink, plastic or paper further comprises a pigment according to claim 1 .
9. An interference pigment according to claim 1 , in which the transparent support material is a mica, talc or kaolin.
10. In a paint, printing ink, varnish, plastic, ceramic material, glass, cosmetic, or laser marking composition for paper or plastics, comprising a pigment, the improvement wherein the pigment is one according to claim 1 .
11. A multilayer interference pigment for security applications, comprising a transparent support material which is coated with at least three layers comprising titanium dioxide layer having a layer thickness of from 65–95 nm, a silicon dioxide layer having a layer thickness of from 160–240 nm and a further titanium dioxide layer having a layer thickness of from 50–70 nm.
12. An interference pigment according to claim 11 , in which the transparent support material is phyllosilicate, talc or kaolin, platelet-shaped aluminium oxide, or glass or silicon dioxide platelets.
13. An interference pigment according to claim 11 , which exhibits red and gold reflection colours and green transmission colour.
14. An interference pigment according to claim 13 , containing further layer sets of alternating low and high refractive index materials.
15. A process for the production of an interference pigment according to claim 12 , in which the transparent support material is suspended in water and coated alternately with a layer of titanium dioxide, a layer of silicon dioxide and a further layer of titanium dioxide by addition and hydrolysis of the corresponding inorganic, water-soluble metal compounds, the pH necessary for the precipitation of the respective metal oxide being set and kept constant by simultaneous addition of acid or base, and the coated support material is subsequently separated off from the aqueous suspension, dried and optionally calcined.
16. In a forgery-resistant security application comprising paints, printing inks, plastics, or paper, the improvement wherein said paint, printing ink, plastic or paper further comprises a pigment according to claim 11 .
17. In a paint, printing ink, varnish plastic, ceramic material, glass, cosmetic, laser marking composition for paper or plastics, comprising a pigment, the improvement wherein the pigment is one according to claim 11 .
18. An interference pigment according to claim 11 , in which the transparent support material is a mica, talc or kaolin.