Catalyst obtained by prepolymerization of polyolefin and olefin polymerization method using the same
The present invention provides a prepolymerized olefin polymerization catalyst and olefin polymerization method using the same. More particularly, the present invention provides a prepolymerized catalyst that is encapsulated with macromonomers produced by polymerizing olefin monomers with a vinyl-terminated polysiloxane compound in the presence of a solid titanium catalyst for olefin polymerization having been previously surface treated with silane compounds containing two or more vinyl groups, and a method for producing polyolefin having a high melt strength using the catalyst.
1. A prepolymerized olefin polymerization catalyst encapsulated with macromonomers wherein the prepolymerized catalyst is prepared by polymerization of an olefin monomer and a vinyl-terminated polysiloxane compound in the presence of a solid titanium olefin polymerization catalyst wherein the solid titanium catalyst is prepared by surface treating a compound comprising a magnesium compound, a titanium compound, and an electron donor with a silane compound having two or more vinyl groups.
2. The prepolymerized olefin polymerization catalyst of claim 1 , wherein the silane compound having two or more vinyl groups comprises divinyldimethylsilane, divinyldiphenylsilane, divinyldiethylsilane, divinyldiisobutylsilane, or divinyldihydridesilane.
3. The prepolymerized olefin polymerization catalyst of claim 1 , wherein the amount of the silane compound having two or more vinyl groups is 2–200 moles per mole of magnesium compound.
4. The prepolymerized olefin polymerization catalyst of claim 1 , wherein the compound comprising a magnesium compound, a titanium compound, and an electron donor is prepared by the method comprising:
(i) preparing a solution of the magnesium compound by dissolving the magnesium compound in the electron donor;
(ii) reacting the magnesium solution with a transition metal compound, a silicon compound, a tin compound, or a mixture thereof and thereby precipitating solid particles; and
(iii) reacting the precipitated solid particles with a titanium compound and an electron donor.
5. The prepolymerized olefin polymerization catalyst of claim 1 , wherein the olefin monomer used in the prepolymerization step comprises one or more monomers selected from the group consisting of ethylene, propylene, 1-butene, 1-hexene, and 1-octene.
6. The prepolymerized olefin polymerization catalyst of claim 1 , wherein the vinyl-terminated polysiloxane compound has the structure:
H 2 C═CH—SiR 2 —O—(SiR 2 —O) n —SiR 2 —CH═CH 2
(n=0–100, R=alkyl, alkoxy, hydrogen, or phenyl).
7. The prepolymerized olefin polymerization catalyst of claim 1 , wherein the macromonomers encapsulating the prepolymerized catalyst have a weight average molecular weight in the range of 500–100,000, and comprise 1–99% by weight olefin, 0.01–10% by weight vinyl-terminated polysiloxane compound, and 0.001–1% by weight silane material from the silane compound having two or more vinyl groups.
8. A method of olefin polymerization comprising contacting olefin with a catalyst system wherein the catalyst system comprises:
(i) a prepolymerized olefin polymerization catalyst encapsulated with macromonomers wherein the prepolymerized catalyst is prepared by polymerization of an olefin monomer and a vinyl-terminated polysiloxane compound in the presence of a solid titanium olefin polymerization catalyst wherein the solid titanium catalyst is prepared by surface treating a compound comprising a magnesium compound, a titanium compounds and an electron donor with a silane compound having two or more vinyl groups;
(ii) an organometallic compound comprising a metal of Group I or Group III of the Periodic Table; and
(iii) an external electron donor.
9. The method of olefin polymerization of claim 8 , wherein the organometallic compound comprises a trialkylaluminum compound.
10. The method of olefin polymerization of claim 8 , wherein the external electron donor comprises an alkoxy silane compound.
11. The method of olefin polymerization of claim 8 , wherein the silane compound having two or more vinyl groups comprises divinyldimethylsilane, divinyldiphenylsilane, divinyldiethylsilane, divinyldiisobutylsilane, or divinyldihydridesilane.
12. The method of olefin polymerization of claim 8 , wherein the amount of the silane compound having two or more vinyl groups is 2–200 moles per mole of magnesium compound.
13. The method of olefin polymerization of claim 8 , wherein the compound comprising a magnesium compound, a titanium compound, and an electron donor is prepared by the method comprising:
(i) preparing a solution of the magnesium compound by dissolving the magnesium compound in the electron donor;
(ii) reacting the magnesium solution with a transition metal compound, a silicon compound, a tin compound, or a mixture thereof and thereby precipitating solid particles; and
(iii) reacting the precipitated solid particles with a titanium compound and an electron donor.
14. The method of olefin polymerization of claim 8 , wherein the olefin monomer used in the prepolymerization step comprises one or more monomers selected from the group consisting of ethylene, propylene, 1-butene, 1-hexene, and 1-octene.
15. The method of olefin polymerization of claim 8 , wherein the vinyl-terminated polysiloxane compound has the structure:
H 2 C═CH—SiR 2 —O—(SiR 2 —O) n —SiR 2 —CH═CH 2
(n=0–100, R=alkyl, alkoxy, hydrogen, or phenyl).
16. The method of olefin polymerization of claim 8 , wherein the macromonomers encapsulating the prepolymerized catalyst have a weight average molecular weight in the range of 500–100,000, and comprise 1–99% by weight olefin, 0.01–10% by weight vinyl-terminated polysiloxane compound, and 0.001–1% by weight silane material from the silane compound having two or more vinyl groups.