Self-cooling containers for liquids
Disclosed are self-cooling containers for beverages and other liquids. Such containers comprise porous matrices as elements of the container bodies to effect the cooling of contained liquids by pervaporation. The liquid vapor can pass through the porous matrix directly to the environment or to a collector or trap comprising an absorbent material in contact with the container. Also disclosed are self-cooling containers incorporating insulative sleeves that reduce radiative warming of container surfaces yet permit sufficient pervaporative flux to cool containers residing within such sleeves.
1. A container for liquids comprising:
a container body comprising one or more walls;
wherein at least a portion of said one or more walls comprises a hydrophobic porous matrix that allows for the passage of vapor from a liquid within said container such that pervaporation or evaporation of said vapor cools said liquid within said container; and
a regenerable or disposable outer layer directly adjacent to at least portion of said container body, said layer comprising a desiccant or an absorbent material that absorbs moisture or other fluid resulting from said evaporation or pervaporation.
2. A container for liquids according to claim 1 wherein said porous matrix comprises a membrane.
3. A container for liquids according to claim 1 wherein said porous matrix comprises a porous sintered matrix.
4. A container for liquids according to claim 1 wherein said porous matrix is fabricated from a polymer selected from the group consisting of polyethylenes, polypropylenes, ethylene copolymers, polymethylpentenes, polybutylenes, and blends thereof.
5. A container for liquids according to claim 1 wherein said porous matrix is fabricated from a polymer selected from the group consisting of polytetrafluoroethylene, polyvinylfluoride, polyvinylidinefluoride, polyethylenetetrafluoroethylene, fluorinated ethylene propylene, polyperfluoroalkoxyethylene, polyvinylchloride, chlorinatedpolyvinylchloride, polyvinyldichloride and blends thereof.
6. A container for liquids according to claim 1 wherein said porous matrix is fabricated from a blend of a fluorinated additive with a non-fluorinated plastic resin.
7. A container for liquids according to claim 1 wherein said porous matrix is fabricated from a silicone polymer or fluorosilicone polymer.
8. A container for liquids according to claim 1 wherein said porous matrix has a thickness of 0.025 to 7.0 mm.
9. A container for liquids according to claim 1 wherein said porous matrix has a thickness of 0.05 to 3.0 mm.
10. A container for liquids according to claim 1 wherein said porous matrix has a pore size of 0.05 to 500 μm.
11. A container for liquids according to claim 1 wherein said porous matrix has pore size of 0.1 to 100 μm.
12. A container for liquids according to claim 1 wherein said porous matrix has percent porosity of 10 to 90%.
13. A container for liquids according to claim 1 wherein said porous matrix has percent porosity of 30 to 70%.
14. A container for liquids according to claim 1 wherein said portion of said one or more walls is 5 to 100% of the total wall area of said container.
15. A container for liquids according to claim 1 wherein said porous matrix is comprised of hollow or expanded particles which are fused or adhered together to reduce the thermal conductivity of said porous matrix.
16. A container for liquids according to claim 1 , wherein said hydrophobic porous matrix has a pleated structure.
17. A container for liquids comprising:
a container body comprising one or more walls;
wherein at least a portion of said one or more walls comprises a hydrophobic porous matrix that allows for the passage of vapor from a liquid within said container such that pervaporation or evaporation of said vapor cools said liquid within said container; and
an insulating sleeve surrounding at least a portion of said one or more walls.
18. A container for liquids according to claim 17 wherein said porous matrix comprises a membrane.
19. A container for liquids according to claim 17 wherein said porous matrix comprises a porous sintered matrix.
20. A container for liquids according to claim 17 wherein said porous matrix is fabricated from a polymer selected from the group consisting of polyethylenes, polypropylenes, ethylene copolymers, polymethylpentenes, polybutylenes, and blends thereof.
21. A container for liquids according to claim 17 wherein said porous matrix is fabricated from a polymer selected from the group consisting of polytetrafluoroethylene, polyvinylfluoride, polyvinylidinefluoride, polyethylenetetrafluoroethylene, fluorinated ethylene propylene, polyperfluoroalkoxyethylene, polyvinylchloride, chlorinatedpolyvinylchloride, polyvinyldichloride and blends thereof.
22. A container for liquids according to claim 17 wherein said porous matrix is fabricated from a blend of a fluorinated additive with a non-fluorinated plastic resin.
23. A container for liquids according to claim 17 wherein said porous matrix is fabricated from a silicone polymer or fluorosilicone polymer.
24. A container for liquids according to claim 17 wherein said porous matrix has a thickness of 0.025 to 7.0 mm.
25. A container for liquids according to claim 17 wherein said porous matrix has a thickness of 0.05 to 3.0 mm.
26. A container for liquids according to claim 17 wherein said porous matrix has a pore size of 0.05 to 500 μm.
27. A container for liquids according to claim 17 wherein said porous matrix has pore size of 0.1 to 100 μm.
28. A container for liquids according to claim 17 wherein said porous matrix has percent porosity of 10 to 90%.
29. A container for liquids according to claim 17 wherein said porous matrix has percent porosity of 30 to 70%.
30. A container for liquids according to claim 17 wherein said portion of said one or more walls is 5 to 100% of the total wall area of said container.
31. A container for liquids according to claim 17 wherein said porous matrix is comprised of hollow or expanded particles which are fused or adhered together to reduce the thermal conductivity of said porous matrix.
32. A container for liquids according to claim 17 wherein said porous matrix has a pleated structure.
33. A container for liquids according to claim 17 wherein said insulating sleeve comprises a porous insulative material.
34. A container for liquids according to claim 17 , wherein said porous insulative material is open-cell porous insulative material.
35. A container for liquids according to claim 17 , wherein said insulating sleeve is generally tubular and has one or more openings in the wall thereof, whereby the sleeve may be rotated about the container to selectively cover or expose portions of said porous matrix.
36. A container for liquids comprising:
a container body comprising one or more walls;
wherein at least a portion of said one or more walls comprises a porous matrix having a first surface and a second surface wherein said first surface is a hydrophobic surface and said second surface is a hydrophilic surface; and
wherein said porous matrix allows for the passage of vapor from a liquid within said container such that pervaporation or evaporation of said vapor cools said liquid within said container.
37. A container for liquids according to claim 36 wherein said porous matrix is oriented such that said hydrophilic surface faces the interior of the container.
38. A container for liquids according to claim 17 wherein said porous matrix comprises a porous hydrophilic membrane laminated to a porous hydrophobic membrane.
39. A container for liquids according to claim 17 wherein said second surface is rendered hydrophilic by a process selected from the group consisting of plasma etching, chemical etching, impregnation with wetting agents, and application of hydrophilic coatings.
40. A container for liquids according to claim 17 wherein said porous matrix has a thickness of 0.025 to 7.0 mm.
41. A container for liquids according to claim 17 wherein said porous matrix has a thickness of 0.05 to 3.0 mm.
42. A container for liquids according to claim 17 wherein said porous matrix has a pore size of 0.05 to 500 μm.
43. A container for liquids according to claim 17 wherein said porous matrix has pore size of 0.1 to 100 μm.
44. A container for liquids according to claim 17 wherein said porous matrix has percent porosity of 10 to 95%.
45. A container for liquids according to claim 17 wherein said porous matrix has percent porosity of 30 to 70%.
46. A container for liquids according to claim 17 , wherein said portion of said one or more walls is 5 to 100% of the total wall area of said container.
47. A container for liquids according to claim 17 wherein said porous matrix has a pleated structure.