IP Library Granted Patent US 7,202,283
Granted Patent B2
US 7,202,283 · App. 10/495,592 · Granted Apr 10, 2007

Method for dissolving saturated polyester solution for decomposing saturated polyester and method for decomposition using the same

Assignee: Hitachi Chemical Co., Ltd.
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Quick Facts
Patent No.
US 7,202,283
App. No.
10/495,592
Granted
Apr 10, 2007
Kind
B2
Abstract

The present invention provides a dissolution method for saturated polyester capable of recycling saturated polyester used in fibers, a film, a bottle and others with ease and a low cost, a solution decomposing saturated polyester and a decomposition method using the solution.

Claims (32)

1. A solution for decomposing saturated polyester containing an alkali and a monoalcohol as a solvent, and not containing a solvent other than the monoalcohol.

2. The solution according to claim 1 , wherein the saturated polyester is polyalkylene terephthalate.

3. The solution according to claim 1 , wherein the monoalcohol is a lower alcohol.

4. The solution according to 1 , wherein the monoalcohol is methanol.

5. A solution for decomposing saturated polyester containing a salt of a phosphorus-containing acid and a monoalcohol as a solvent.

6. The solution according to claim 5 , wherein the saturated polyester is polyalkylene terephthalate.

7. The solution according to claim 5 , wherein the salt of a phosphorus-containing acid is in the form of a hydrate thereof.

8. The solution according to claim 5 , wherein the salt of a phosphorus-containing acid is an alkali metal salt of a phosphorus-containing acid.

9. The solution according to claim 5 , wherein the salt of a phosphorus-containing acid is potassium phosphate or potassium phosphate hydrate.

10. The solution according to claim 5 , wherein the monoalcohol is a lower alcohol.

11. The solution according to claim 5 , wherein the monoalcohol is methanol.

12. The solution according to claim 5 , further containing, as a solvent other than a monoalcohol, at least one kind selected from the group consisting of an amide solvent, a ketone solvent, an ether solvent, an ester solvent and a hydrocarbon solvent.

13. A decomposition method for saturated polyester, comprising decomposing the saturated polyester in the presence of the solution according to claim 5 .

14. The decomposition method for saturated polyester according to claim 13 , wherein the saturated polyester is a polyalkylene terephthalate.

15. The decomposition method for saturated polyester according to claim 13 , wherein a temperature of the solution in the decomposition is equal to or higher than a freezing point thereof and equal to or lower than a boiling point thereof.

16. The decomposition method for saturated polyester according to claim 13 , wherein a temperature of the solution in the decomposition is equal to or less than 150° C.

17. The decomposition method for saturated polyester according to claim 13 , wherein the decomposition is implemented under ordinary pressure.

18. The decomposition method for saturated polyester according to claim 13 , wherein at least one kind of decomposition product of the saturated polyester is a dicarboxylic acid dialkyl ester.

19. The decomposition method for saturated polyester according to claim 13 , wherein at least one kind of decomposition product of the saturated polyester is a diol.

20. The decomposition method for saturated polyester according to claim 13 , wherein the decomposition product of the saturated polyester is obtained in one step chemical reaction.

21. A decomposition method for saturated polyester, comprising decomposing the saturated polyester in the presence of the solution according to claim 1 .

22. The decomposition method for saturated polyester according to claim 21 , wherein the saturated polyester is a polyalkylene terephthalate.

23. The decomposition method for saturated polyester according to claim 21 , wherein a temperature of the solution in the decomposition is equal to or higher than a freezing point thereof and equal to or lower than a boiling point thereof.

24. The decomposition method for saturated polyester according to claim 21 , wherein a temperature of the solution in the decomposition is equal to or less than 150° C.

25. The decomposition method for saturated polyester according to claim 21 , wherein the decomposition is implemented under ordinary pressure.

26. The decomposition method for saturated polyester according to claim 21 , wherein at least one kind of decomposition product of the saturated polyester is a dicarboxylic acid dialkyl ester.

27. The decomposition method for saturated polyester according to claim 21 , wherein at least one kind of decomposition product of the saturated polyester is a diol.

28. The decomposition method for saturated polyester according to claim 21 , wherein the decomposition product of the saturated polyester is obtained in one step chemical reaction.

29. The solution according to claim 1 , said solution further comprising said saturated polyester.

30. The solution according to claim 29 , wherein said saturated polyester is polyalkylene terephthalate.

31. The solution according to claim 5 , said solution further comprising said saturated polyester.

32. The solution according to claim 31 , wherein said saturated polyester is polyalkylene terephthalate.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 20, 2004
From: MASUDA, HISAYO; SHIBATA, KATSUJI; IZAWA, HIROYUKI; IWAMUARU, AYAKAO
To: HITACHI CHEMICAL CO., LTD.
Reel/Frame 015874/0732 →
Priority Claims (5)
JP 2001-351068 · Nov 16, 2001 · national
JP 2001-351073 · Nov 16, 2001 · national
JP 2001-351076 · Nov 16, 2001 · national
JP 2001-351081 · Nov 16, 2001 · national
JP 2001-351082 · Nov 16, 2001 · national
Continuity (1)
Related Publication 20050027023A1 · Feb 3, 2005