Aluminum alloy piping material for automotive tubes having excellent corrosion resistance and formability, and method of manufacturing same
View Patent ↗An aluminum alloy piping material for automotive tubes having excellent tube expansion formability by bulge forming at the tube end and superior corrosion resistance, which is suitably used for a tube connecting an automotive radiator and heater, or for a tube connecting an evaporator, condenser, and compressor. The aluminum alloy piping material is an annealed material of an aluminum alloy containing 0.3 to 1.5% of Mn, 0.20% or less of Cu, 0.10 to 0.20% of Ti, more than 0.20% but 0.60% or less of Fe, and 0.50% or less of Si with the balance being aluminum and unavoidable impurities, wherein the aluminum alloy piping material has an average crystal grain size of 100 μm or less, and Ti-based compounds having a grain size (circle equivalent diameter, hereinafter the same) of 10 μm or more do not exist as an aggregate of two or more serial compounds in a single crystal grain.
1. An aluminum alloy piping material for automotive tubes having excellent corrosion resistance and formability and which is an annealed material of an aluminum alloy comprising, in mass percent, 0.8 to 1.5% of Mn, 0.05% or less of Cu, 0.10 to 0.20% of Ti, 0.30% to 0.60% of Fe, and 0.50% or less of Si with the balance being aluminum and unavoidable impurities, wherein the aluminum alloy piping material has an average crystal grain size of 100 μm or less, and Ti-based compounds having a grain size of 10 μm or more do not exist as an aggregate of two or more serial compounds in a single crystal grain, wherein the aluminum alloy is hot-extruded and cold-drawn at a reduction ratio of 30% or more, the total reduction ratio of hot extrusion and cold drawing is 99% or more and the temperature increase rate during annealing is 200° C./h or more.
2. The aluminum alloy piping material according to claim 1 , wherein the aluminum alloy further comprises up to 0.4% of Mg.
3. The aluminum alloy piping material according to claim 1 , wherein the aluminum alloy further comprises at least one of 0.01 to 0.2% of Cr and 0.01 to 0.2% of Zr.
4. The aluminum alloy piping material according to claim 1 , wherein the aluminum alloy further comprises at least one of 0.01 to 0.1% of Zn, 0.001 to 0.05% of In, and 0.001 to 0.05% of Sn.
5. A method of manufacturing an aluminum alloy piping material for automotive tubes having excellent corrosion resistance and formability, the method comprising hot extruding a billet of the aluminum alloy according to claim 1 into an aluminum alloy tube, cold drawing the aluminum alloy tube, and annealing the cold-drawn product, wherein a reduction ratio of the cold drawing is 30% or more, a total reduction ratio of the hot extrusion and the cold drawing is 99% or more, and a temperature increase rate during the annealing is 200° C./h or more, the reduction ratio being expressed by {(cross-sectional area before forming—cross-sectional area after forming)/(cross-sectional area before forming)}×100%.
6. The aluminum alloy piping material according to claim 1 , wherein at least 0.22% Fe is present.
7. The aluminum alloy piping material according to claim 1 , wherein at least 0.30% Fe is present.